Geochemical comparison of the subvolcanic appinite suite of the British Caledonides and the durbachite suite of the Central European Hercynides: evidence for associated shoshonitic and Granitic Magmatism

Summary Subvolcanic pyroxenite-hornblendite-kentallenite-diorite-granodiorite masses of the appinite suite that are spatially and temporally associated with the much more voluminous granitic plutons of the British Caledonides have major element proportions and REE patterns indicative of shoshonitic affinities. Hornblendite-monzonite-syenogabbro-pyroxene melasyenite-durbachite-biotite-rich syenite-biotite-rich granite masses of the plutonic durbachite suite of the Bohemian Massif of the Central European Hercynides, that also are spatially and temporally associated with much more voluminous granitic plutons, have geochemical characteristics that generally correspond with those of the appinite suite. Compositionally both suites resemble lamprophyres emplaced during the latter parts of the respective episodes.Both the appinite and durbachite suites show independence of K/Rb and SiO₂ with the two suites having mainly different but somewhat overlapping K/Rb ratios. Other geochemical characters, as shown by fields and trends on K vs Rb, AFM and other plots, point to the durbachite suite representing generally more evolved products of shoshonitic magma than members of the appinite suite. However, there are different geochemical characteristics, including higher Cr/Ni ratios in the durbachite suite and Co present in lower proportions in the appinite suite. These differences are the result of different histories of freezing, remelting and partial separation and remixing of fractionation products and reflect the explosive subvolcanic vs plutonic regimes of the appinitic and durbachitic suites, respectively. Support for this petrogenesis is provided by mineral compositions and comparison of compositions of mineral phases and the rocks in which they occur.

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Ein geochemischer Vergleich der subvulkanischen Appinite der Britischen Kaledoniden und der Durbachite der Mitteleuropäischen Herzyniden: Hinweise für assoziierten shoshonitischen und granitischen Magmatismus

Zusammenfassung Subvulkanische Pyroxenit-Hornblendit-Kentallenit-Diorit-Granodioritmassen der Appinit-Gruppe, die räumlich und zeitlich mit den viel umfangreicheren Granitplutonen der Britischen Kaledoniden assoziiert sind, haben Hauptelementverteilungen und SEE Gehalte, die auf Beziehungen zu Shoshoniten hinweisen. Hornblendit-Monzonit-Syenogabbro-Pyroxen-Melasyenit-Durbachit-Biotit-reiche Syenite-Biotit-reiche Granitmassen der plutonischen Durbachitabfolge des Böhmischen Massivs der Mitteleuropäischen Herzyniden, die auch räumlich und zeitlich mit viel umfangreicheren Granitplutonen assoziiert sind, haben geochemische Charakteristika, die im allgemeinen mit denen der Appinit-Gruppe übereinstimmen. Beide Gruppen sind in ihrer Zusammensetzung Lamprophyren ähnlich, die in späteren Abschnitten der magmatischen Episoden Platz genommen haben.Sowohl in den Appinit-, wie in den Durchbachit-Abfolgen sind K/Rb und SiO₂ voneinander unabhängig, beide Gruppen haben aber verschiedene, wenn auch zum Teil einander überlappende K/Rb Verhältnisse. Andere geochemische Parameter, wie K vs Rb, AFM und andere, weisen darauf hin, daß die Durbachit-Abfolge im allgemeinen weiter entwickelte Produkte shoshonitischen Magmas darstellt, als die Mitglieder der Appinit-Gruppe. Es gibt jedoch verschiedene geochemische Charakteristika, wozu auch höhere Cr/Ni Verhältnisse in den Durbachiten und niedrige CoGehalte in den Appiniten gehren. Diese Unterschiede sind das Ergebnis verschiedener Abkhlung, Aufschmelzung und teilweiser Trennung- und Wiedermischung von Fraktionierungs-Produkten und weisen auf die explosiven subvulkanischen bzw. plutonischen Regimes der beiden Gruppen hin. Diese petrogenetische Interpretation wird durch Mineralzusammensetzungen und deren Vergleich mit den Muttergesteinen unterstützt.

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With 6 Figures     

Phase transformation studies on a synthetic hedenbergite up to 26 GPa at 1200° C

Phase transformations in a synthetic hedenbergite (CaFeSi₂O₆) have been observed with X-ray diffraction up to 26 GPa at 1200° C in a diamond anvil cell with a YAG laser heating system. Hedenbergite first decomposes into spinel, stishovite, and cubic perovskite phases at 16 GPa, and spinel further decomposes into wüstite and stishovite at 19 GPa. Between 19 GPa and 26 GPa, the phase assemblage is wüstite + stishovite+ perovskite. On decompression to 0.1 MPa, all the highpressure phases are retained except the cubic perovskite, which reverts to a retrogressive phase of CaSiO₃. A comparison of the results of this study with those from a previous study on a natural hedenbergite suggests that the garnet phase formed from natural hedenbergite is stabilized by manganese.     

Active tuned liquid column damper with propellers

The active control of a Tuned Liquid Column Damper (TLCD) with two propellers is presented. A single‐degree‐of‐freedom system with a passive or active TLCD is used as an example to set up the basic equation of motion. The Optimal Control Theory is applied to establish the control law and to calculate the control force generated by these two propellers installed inside the TLCD. A simple pendulum‐like model test is carried out to study the dynamic characteristics of the passive and active TLCDs and the effectiveness of the vibrational control. Comparison of the experimental result with the analytical one shows a good agreement. Finally, the analytical results of the seismic response are also included as an example for demonstration and application. Copyright © 2003 John Wiley & Sons, Ltd.     

The effect of Fe on the crystal structure of wadsleyite β-(Mg1 − x Fe x )2SiO4, 0.00≤x≤0.40

Single crystals of five wadsleyite compositions, β-(Mg,Fe)₂SiO₄ with Fe/(Fe+Mg)=0.00, 0.08, 0.16, 0.25 and 0.40, have been synthesized at high temperature and pressure in a uniaxial, split-sphere apparatus. Crystal structures of these samples, determined by x-ray diffraction techniques, reveal that iron is significantly ordered: Fe is depleted in the M2 octahedron, while it is enriched in M1 and M3. The most iron-rich synthetic sample, which falls well outside previous estimates of wadsleyite stability, raises questions regarding published Mg₂SiO₄-Fe₂SiO₄ phase diagrams at transition zone conditions.     

Identifying drivers for fishing pressure. A multidisciplinary study of trawl and sea snail fisheries in Samsun,Black Sea coast of Turkey

This study aims to investigate and model driving forces that lead to increased fishing pressure and an altered state of the environment in the coastal areas near Samsun on the Turkish Black Sea coast. We have applied a modified DPSIR model to structure our investigation and analysis and have investigated the drivers that generate fishing pressure in the Samsun fisheries. The overall health of the ecosystem is declining, and there is a consistent trend of deterioration in the condition of the three major species targeted by the trawl fisheries. Although introduced invasive species have brought significant changes to the Black Sea, it is clear that the state of the environment is significantly and negatively affected by the pressure exerted by fisheries. Fishing pressure has to a certain extent been redirected to pelagic trawling as bottom trawling has become less profitable and a rise in catch capacity has levelled off. This reduction is, however, offset by an increase in illegal trawling and dredging by a very rapidly growing sector of multi-purpose small boats, resulting in a considerable increase in the overall accumulated engine power of fishing boats in Samsun during 2000–2005. Fisheries in Samsun, in particular sea snail fisheries, have constituted a frontier of sorts open to the poorer populations of Samsun during the last 20 years, and, thereby, constitute one of the major drivers for fishing pressure. We identify eight drivers of importance for the period 2000–2005. Although the authorities can impact all or most of those drivers, most of them are beyond the scope of conventional ‘fisheries management’.     

利用单频双程波动方程计算初至走时及其振幅

通过在频率域双程波动方程模拟算法中加入一个复数频率（实部表示频率,虚部表示衰减因子）压制地震波初至走时之后的能量,从而把初至走时及其振幅的计算问题转换为单一频率波场中最大能量走时和振幅的拾取问题,然后利用单一频率域波场的相位项和振幅项分别计算初至走时及其振幅.本文还提出利用参数分析方法求取最优的复数频率,并给出数值计算例子,将本方法的计算结果与有限差分程函方程初至走时和最大能量走时振幅进行比较,结果表明,该方法具有适应于任意复杂介质和多炮多接收点走时和振幅的计算.     

Factors controlling groundwater chemistry in an agricultural area with complex topographic and land use patterns in mid‐western South Korea

Shallow and bedrock groundwater from granitic aquifers were investigated for the hydrogeochemistry of major and minor constituents in an agricultural area. Nitrate concentrations were observed up to 49 mg/l as NO₃‐N, with 22% of samples exceeding the drinking water standard, which could pose a significant threat because most residents rely on groundwater as their drinking water source. Principal component analysis revealed three principal components (PCs): (1) nitrate contamination, contributed by major cations, Cl^?, SO and NO , (2) reduction processes positively involving Fe, Mn and B, and negatively involving dissolved oxygen and NO and (3) natural mineralization, involving HCO and F^?. Cluster analysis, performed on the PC scores, resulted in seven sample groups, which were successfully identified by total depth, elevation and land use. The nitrate‐contaminated groups had mixed land uses, with locally concentrated residential areas. Uncontaminated groundwater groups were found in the natural environment, including high‐altitude spring water and bedrock groundwater with a higher degree of natural mineralization. Shallow groundwater groups in paddy fields in lowlands were affected by reducing environments, of which one group was characterized by high Fe, Mn and B, and negligible nitrate. Groundwater with intermediate nitrate and lower Cl^? and SO was found primarily in hilly terrains with orchards and vegetable gardens, indicating lower contaminant loadings than lowland areas. Higher concentrations of F^? and nitrate were observed in the nitrate‐contaminated water, which seemed unlikely to be explained by groundwater mixing. The strong acidity generated from nitrification may infiltrate deeper into the aquifer, induce accelerated weathering of bedrock and result in the coexistence of F^? and nitrate, which may be an evidence of intense nitrate loading, leading to soil acidification. Multivariate statistical analysis successfully delineated hydrochemical characteristics of groundwater attained by natural and anthropogenic processes in an agriculturally stressed area with complex topographic land use patterns. Copyright © 2009 John Wiley & Sons, Ltd.     

Experimental developments for studying static and seismic behavior of retaining walls with liquefiable backfills

The effects of earthquakes on cantilever retaining walls with liquefiable backfills were studied. The experimental techniques utilized in this study are discussed here. A series of centrifuge tests was conducted on aluminum, fixed-base, cantilever wall models retaining saturated, cohesionless backfills. Accelerations on the walls and in the backfill, static and excess pore pressures in the soil, and deflections and bending strains in the wall were measured. In addition, direct measurements of static and dynamic lateral earth pressures were made. In some tests, sand backfills were saturated with the substitute pore fluid metolose. Modeling of model type experiments were conducted. The experimental measurements were found internally consistent and repeatable. Both static and dynamic earth pressure measurements were determined to be reliable. It was also observed that for the test configuration adopted, a special boundary treatment such as the use of duxseal is optional. Static and seismic modeling of models were also successful, which indicated that the assumed scaling relations were essentially correct.     

Increased zooplankton PAH concentrations across hydrographic fronts in the East China Sea

The Changjiang has transported large quantities of polycyclic aromatic hydrocarbons (PAHs) to the East China Sea (ECS), but information of these pollutants in zooplankton is limited. To understand PAHs pollution in zooplankton in the ECS, total concentrations of PAHs in zooplankton from surface waters were measured. Values of PAHs ranged from 2 to 3500 ng m⁻³ in the ECS, with highest PAHs levels located at the salinity front between the Changjiang Diluted Water (CDW) and the mid-shelf waters. In contrast, concentrations of zooplankton PAHs in the mid-shelf and outer-shelf waters were significantly lower (2–23 ng m⁻³) than those in the CDW. These results demonstrate that PAHs are conspicuously accumulated in zooplankton at the salinity front between the CDW and the mid-shelf waters. These higher levels of PAHs in zooplankton at the salinity front may be further biomagnified in marine organisms of higher trophic levels through their feeding activities.