Late Pleistocene and Holocene terrestrial geomorphodynamics and soil formation in northeastern Germany: a review of geochronological data

ABSTRACT

This study is based on 616 geochronological ages from aeolian and colluvial sediments as well as paleosols, representing the largest database of geochronological data from northeastern Germany available to date. Cumulative probability density functions for radiocarbon data and kernel density estimates for luminescence data were created covering the last 15 ka. The data analysis aimed at the identification of changes and their drivers in geomorphodynamics and soil formation. The ages representing aeolian activity cluster in the Late Glacial, the Early Holocene, and the Late Holocene, where the first two clusters are assumed to result mostly from climatic impact with only a minor share of human impact triggering the mobilization of aeolian sediments. The third cluster is considered to result mainly from human impact. The Late Glacial to Early Holocene activity phase is interrupted by a phase of surface stability around 11.5–12.7 ka, which is indicated by the occurrence of initial soil formations of Finow and Usselo types. Colluvial sedimentation predominantly occurred during the last 7 ka and clearly accelerated since the last 1000 a. According to the ages of specific paleosol types, related soil-forming processes started already in the Late Glacial and were completed in the Holocene.     

Resolving frontal structures: on the payoff using a less diffusive but computationally more expensive advection scheme

This article presents some advantages using a shape-preserving total variation diminishing (TVD) advection scheme in an ecosystem model. The superbee flux-limiter has been used to the second-order Lax–Wendroff advection scheme to make it TVD. We performed simulations for three shelf sea regions with different characteristic time scales, namely, the North Sea, the Barents Sea, and the Baltic Sea. To explore the advantages, we also performed reference runs with the much simpler and computationally cheaper upwind advection scheme. Frontal structures are much better resolved with the TVD scheme. The bottom salinity in the Baltic Sea stays at realistic values throughout the 10-year simulation with the TVD scheme, while with the upwind scheme, it drifts towards lower values and the permanent haline stratification in the Baltic is almost completely eroded within one seasonal cycle. Only when applying TVD for both the vertical and horizontal advections the model succeeded to preserve haline stratification in the decadal simulation. Lower trophic level patterns are far better reproduced with the TVD scheme, and for the estimated cod larval survival, the advantages seem to be even stronger. Simulations using the TVD-derived prey fields identified distinct regions such as Dogger Bank to favor potential larvae survival (PLS), which did not appear as particularly favorable in the upstream simulations. The TVD scheme needs about 25 % more time on the central processing unit (CPU) in case of a pure hydrodynamic setup with only two scalar state variables (Barents Sea application). The additional CPU time cost increases for a coupled physical–biological model application with a large number of state variables. However, this is more than compensated by all the advantages found, and, hence, we conclude that it is worthwhile to use the TVD scheme in our ecosystem model.

     

A reindeer herder's perspective on caribou, weather and socio-economic change on the Seward Peninsula, Alaska

Non-climate variables shape vulnerability and adaptive capacity to climate change. Here, we describe how recent environmental and socio-economic developments have transformed reindeer herding and perceptions of weather on the Seward Peninsula, Alaska. The reindeer industry has shrunk considerably since the early 1990s, when the winter range of the Western Arctic Caribou Herd expanded, and over 17 000 reindeer mixed with migrating caribou and left the region. Socio-economic and environmental repercussions make the continuation of herding tenuous, and erode the ability of herders to cope with weather variability, among other perturbations. We present a case study of one herder's annual cycle, and juxtapose physical drivers of herding activities, including weather-station and herder observations of local weather variability, with socio-economic factors. There is an increased urgency to access and monitor reindeer with caribou present, but herding plans are constrained by lower economic returns and the need to spend more time in non-herding jobs. Although weather is a greater concern now for immediate herd access, standard weather data are largely irrelevant to the mechanics of herding, whereas variables pertaining to the timing of biotic events (e.g., synchrony of spring break-up and calving) and visibility are attributed to lost herding opportunities. Short-term responses to weather conditions stem from more long-term vulnerability associated with caribou presence, reduced herd size, difficulties affording snowmobile maintenance or crew assistance, and dwindling market opportunities. We emphasize the environmental and socio-economic interactions that affect vulnerability and adaptive capacity for modern herding.     

Simplification of a Sequential Extraction Scheme To Determine the Mobilisable Heavy Metal Pool in Soils

This investigation had the purpose of evaluating the reliability of a sequential extraction procedure according to Zeien and Brümmer (1989) which is performed routinely to analyse the distribution of heavy metals to different soil phases. Reliability was tested by two hypotheses. According to the first hypothesis an error propagation increased during a morefold extraction of heavy metals from a single soil sample to such an extend that it does not allow a statistical comparison of different analyses. This assumption was confirmed in an interlaboratory study of five participants applying the sequential extraction scheme on two different soils. The heavy metal amounts extracted by the different partners were of the same magnitude, but from the results no statistical correspondence at the 95% confidence level could be observed. The second hypothesis stated that also weak extraction agents were able to release metals from the more immobile soil fractions, especially if the amount of easily soluble metals was comparatively small. To answer this question the sequential extraction was modified by carrying out selected weak extraction steps several times. As expected the intensified extraction conditions caused a decrease of the element content within the more resistant phases. However, the additional release in the first four extraction steps of Pb, Mn, Fe, and Zn was only in the range of 5 to 10%. Furthermore, it was observed that a single EDTA extraction (step four within the sequential extraction scheme) was capable to extract the same amount of metals as the first four extraction steps of the original scheme at a variation of about 15%. From these results it was concluded that the EDTA step alone already represents a reliable pool of mobilisable metals. Thus it can be maintained that such a simple single EDTA extraction can be used to assess the environmental risk from heavy metal contaminated soils or to predict the potential heavy metal release of soil remediation processes.     

Biodegradation of NOM in Rapid Sand Filters for Removing Iron and Manganese

In order to examine the Corg flow in rapid sand filter columns for the elimination of iron and manganese, reduced groundwater was treated in a pilot plant consisting of a trickling filter column (TF I) followed by a wet type filter column (WF II) and a separate wet type filter column (WF sep). Additionally the effect of filtration on BOM was studied by measuring AOC and BDOC. The biological processes in TF I and WF sep led to an elimination of iron, ammonia, and manganese. Moreover, the filtration decreased the NOM content. 21% and 23% of the TOC were eliminated in TF I and in WF sep, respectively. WF II caused no significant Corg reduction. The calculation of the Corg flow in the filter columns showed that bacteria took part in the TOC elimination. From the TOC removed, about 24% was eliminated by metabolic activities of the bacterial population whereas 86% was adsorbed onto iron sludge. Similar results were obtained for the TF I column and for the WF sep column as well. The calculated Corg flow was confirmed by the BDOC measurements. The filtration process led to a BDOC decrease. TF I and WF sep reduced appoximately 35% of the biodegradable organic carbon. In contrast there was no significant elimination by WF II. The AOC results suggest that an AOC production and an AOC elimination process exist in rapid sand filters for groundwater treatment. In the trickling filter column significant AOC production was found, whereas in the wet type filter columns AOC elimination was predominating.     

Microfabric and rock properties of experimentally compressed silt-clay mixtures

Oedometric mechanical compaction tests were performed on brine-saturated synthetic samples consisting of silt-clay mixtures to study changes in microfabric and rock properties as a function of effective stress. The silt consisted of crushed quartz (∼100%) with grain size range between 4 and 40 μm, whereas the clay consisted of 81% kaolinite, 14% mica/illite and 5% microcline of grain size between 0.4 and 30 μm. Five sample pairs ranging in composition from pure silt to pure clay were compacted to 5 and 50 MPa effective stress respectively. SEM studies were carried out to investigate microfabric changes in the mechanically compacted silt-clay mixtures. The degree of alignment of the different minerals present (quartz, mica/illite and kaolinite) were computed by using an image analysis software. Experimental compaction have measured the changes in the rock properties such as porosity and velocity as a function of effective stress for different mixtures of clay and silt. Clay-rich samples showed a higher degree of mineral orientation and lower porosity compared to silt-dominated samples as a function of effective stress. Pure clay sample had 11% porosity at 50 MPa effective stress whereas the pure silt sample retained about 29% porosity at the same effective stress. The experiments showed that low porosity down to 11% is possible by mechanical compaction only. A systematic increase in strain was observed in the silt-clay mixtures with increasing clay content but the porosity values found for the 50:50 silt-clay mixture were lower than that of 25:75 silt-clay mixture. No preferential mineral orientation is expected before compaction owing to the high initial porosity suggesting that the final fabric is a direct result of the effective stress. Both P- and S-wave velocities increased in all silt-clay mixtures with increasing effective stress. The maximum P- and S-wave velocities were observed in the 25:75 silt-clay mixture whereas the minimum Vp and Vs were recorded in the pure silt mixture. At 50 MPa effective stress P- wave velocities as high as 3 km/s resulted from experimental mechanical compaction alone. The results show that fine-grained sediment porosity and velocity are dependent on microfabric, which in turn is a function of grain size distribution, particle shape, sediment composition and stress. At 5 MPa effective stress, quartz orientation increased as a function of the amount of clay indicating that clay facilitate rotation of angular quartz grains. Adding clay from 25% to 75% in the silt-clay mixtures at 50 MPa effective stress decreased the quartz alignment. The clay mineral orientation increased by increasing both the amount of clay and the effective stress, the mica/illite fabric alignment being systematically higher than that of kaolinite. Even small amount of silt (25%) added to pure clay reduced the degree of clay alignment significantly. This study demonstrates that experimental compaction of well characterized synthetic mudstones can be a useful tool to understand microfabric and rock properties of shallow natural mudstones where mechanical compaction is the dominant process.     

Role of effective permeability distribution in estimating overpressure using basin modelling

Overpressure generation is a function of the rates of sedimentation, compaction, fluid generation from kerogen and dehydration of minerals, and most importantly the lateral distribution of permeability within a basin as this controls lateral drainage. Sedimentary basins, however, are typically highly heterogeneous with respect to primary sedimentary facies, diagenesis and tectonic development. While fluid flow models based on idealised homogeneous basins may further our understanding of the processes that influence overpressure development, the results are very sensitive to the distribution of rock properties, particularly permeability. The absolute permeability of sedimentary rocks varies from more than 1 Darcy to less than 0.01 nanodarcy (nD) (10⁻¹¹ Darcy).     

Reflection and transmission by a vertically inhomogeneous planetary atmosphere

By appealing to the reciprocity principle simple expressions are derived for the plane albedo and the transmissivity of a vertically inhomogeneous, plane parallel atmosphere. The plane albedo is shown to equal the angular distribution of the reflected intensity for isotropie Illumination of unit intensity incident at the top of the atmosphere, while the transmissivity equals the angular distribution of the transmitted intensity for isotropie illumination of unit Intensity incident at the bottom of the atmosphere. Chandrasekhar's solution of the planetary problem (including a Lambert reflecting lower boundary) in terms of the solution to the standard problem (no reflecting ground) is extended to apply to an inhomogeneous atmosphere resting on a surface that reflects radiation anisotropically but with no dependence on the direction of incidence (anisotropic Lambert reflector). The computational aspects are discussed and a procedure for computing the planetary albedo and transmissivity Is outlined for a vertically inhomogeneous, anisotropically scattering atmosphere overlying a partially reflecting surface. Numerical verification and illustration are also provided and it is shown that the assumed vertical variation of the single scattering albedo strongly affects the plane albedo but only weakly the transmissivity.