Origin and age of ultramafic rocks and gabbros in the southern Puna of Argentina: an alleged Ordovician suture revisited

Ultramafic rocks and gabbros are exposed in the southern Puna (NW Argentina) in tectonic association with continental arc-related Ordovician (volcano) sedimentary successions and granitoids. The origin of this mafic rock suite has been debated for three decades as either representing an Ordovician terrane suture, primitive Ordovician arc-related rocks or relics of the pre-Ordovician basement in tectonic contact with the Ordovician retro-arc basin successions. We present the first U–Pb ages of primary and inherited zircon from gabbros of this mafic–ultramafic assemblage. LA-ICP-MS analyses on cores and rims of these zircon grains yielded a concordia age of 543.4 ± 7.2 Ma for the gabbroic rocks. Other analysed zircons have Mesoproterozoic, and Early Ediacaran core and rim ages indicating that the magmas also assimilated Meso- and Neoproterozoic crustal material prior to final crystallization. The mafic rocks witnessed higher metamorphic grade than associated Ordovician rocks, which are unmetamorphosed or only affected by anchimetamorphism. The gabbros are mostly tholeiitic and enriched in Zr, Th, as well as other incompatible elements and have εNd _t=540Ma ranging from 1.3 to 7.4 with most of the values between 5 and 7. ¹⁴⁷Sm/¹⁴⁴Nd ratios show evidence of weak crustal contamination. The mafic rocks do not reveal any affinity to mid-ocean ridge basalts in their geochemistry but point instead to an emplacement in an active plate margin arc environment. Chromites from ultramafic rocks show typical Ti, Al, Cr#, Fe³⁺ abundances found in magmatic arc rocks. The formation of the gabbros and the associated ultramafic rocks in the southern Argentine Puna is related to the evolution of the margin of the Pampia terrane, including the Puncoviscana basin, during the Late Neoproterozoic and earliest Cambrian. In contrast to previous interpretations, the rocks predate the Ordovician evolution of the Central proto-Andean active margin. Consequently, interpretations assuming these rocks to represent an oceanic terrane suture of Ordovician age have to be dismissed as much as all palaeotectonic models that define Ordovician terranes in the Central Andes based on assumption that the ultramafic rocks and gabbros exposed in the southern Puna mark plate boundaries.     

Application of Bayesian Generative Adversarial Networks to Geological Facies Modeling

Mathematical Geosciences - Geological facies modeling is a key component in exploration and characterization of subsurface reservoirs. While traditional geostatistical approaches are still commonly...     

Lithic fragments,glasses and chondrules from Luna 16 fines

Bulk compositions of igneous and microbreccia lithic fragments, glasses, and chondrules from Luna 16 fines as well as compositions of minerals in basaltic lithic fragments were determined with the electron microprobe. Igneous lithic fragments and glasses are divided into two groups, the anorthositic-noritic-troctolitic (hereafter referred to as ANT) and basaltic groups. Chondrules are always of ANT composition and microbreccia lithic fragments are divided into groups 1 and 2. The conclusions reached may be summarized as follows: (1) Luna 16 fines are more similar in composition to Apollo 11 than to Apollo 12 and 14 materials (e.g. Apollo 11 igneous lithic fragments and glasses fall into similar ANT and basaltic groups; abundant norites in Luna 16 and Apollo 11 are not KREEP as in Apollo 12 and 14; Luna 16 basaltic lithic fragments may represent high-K and low-K suites as is the case for Apollo 11; rare colorless to greenish, FeO-rich and TiO₂-poor glasses were found in both Apollo 11 and Luna 16; Luna 16 spinels are similar to Apollo 11 spinels but unlike those from Apollo 12). (2) No difference was noted in the composition of lithic fragments, glasses and chondrules from Luna 16 core tube layers A and D. (3) Microbreccia lithic fragments of group 1 originated locally by mixing of high proportions of basaltic with small proportions of ANT materials. (4) Glasses are the compositional analogs to the lithic fragments and not to the microbreccias; most glasses were produced directly from igneous rocks. (5) Glasses show partial loss of Na and K due to vaporization in the vitrification process. (6) Luna 16 chondrules have ANT but not basaltic composition. It is suggested that either liquid droplets of ANT composition are more apt to nucleate from the supercooled state; or basaltic droplets have largely been formed in small and ANT droplets in large impact events (in the latter case, probability for homogeneous and inhomogeneous nucleation is larger. (7) No evidence for ferric iron and water-bearing minerals was found. (8) Occurrence of a great variety of igneous rocks in Luna 16 samples (anorthosite, noritic anorthosite, anorthositic norite, olivine norite, troctolite, and basalt) confirm our earlier conclusion that large-scale melting or partial melting to considerable depth and extensive igneous differentiation must have occurred on the moon.     

On the relation between residual currents and the wind field in the German Bight

Summary The long-period part (T>25 h) of currents measured at close spacing in the German Bight in June 1968 is investigated. The north component of the bottom current is shown to be highly correlated with the east component of the wind in this area, the wind-generated changes of the mass-field giving rise to a quasi-geostrophic current near the bottom.This current responds without perceptible delay to the variations of wind fields with periods considerably longer than those of the seiches of the North Sea. The accelerations linked to such long periods are so small as to be negligable and the residual currents can be regarded as quasi-stationary.

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Über die Beziehung zwischen Reststrom und Windfeld in der Deutschen Bucht

Zusammenfassung Es werden engabständige Strommessungen in der Deutschen Bucht aus dem Juni 1968 in ihrem langperiodischen Teil (T>25 h) untersucht. Dabei ergibt sich, daß die Nordkomponente des Bodenstromes (v) stark korreliert mit der Ostkomponente des Windes (U) in diesem Gebiet. Die winderzeugten Veränderungen des Massenfeldes verursachen eine quasi-geostrophische Strömung am Boden.Diese Strömung reagiert ohne erkennbare Verzögerung auf solche Veränderungen des Windfeldes, die erheblich größere Perioden haben als die Eigenschwingungen der Nordsee. Die damit verbundenen Beschleunigungen sind sehr klein und so zu vernachlässigen; daher kann man die Restströmung auch als quasi-stationär ansehen.

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Sur la relation entre les courants résiduels et le champ du vent en baie Allemande

Résumé La partie à longue période (T>25 h) de courants measurés en des points rapprochés en baie Allemande en juin 1968 est étudiée. La composante Nord du courant de fond se révèle largement corrélée avec la composante Est du vent dans cette zone. Les modifications du champ de masse dues au vent donnent naissance à un courant quasi-géostrophique près du fond.Ce courant répond sans délai perceptible aux variations du champ du vent avec des périodes considérablement plus longues que celles des seiches de la mer du Nord. Les accélérations liées à de telles longues périodes sont si petites qu'elles peuvent être négligées et les courants peuvent être considérés comme quasi-stationnaires.

     

Morphometric analysis of the upper catchment of Kosi River using GIS techniques

Geographical Information System (GIS) have proved to be an efficient tool in the delineation of drainage pattern for water resources management and its planning. In this study, GIS and image processing techniques have been adopted for the identification of morphological features and analyzing the properties of the upper catchment of Kosi River. The basin area includes the high-altitude Himalayan Mountains, including Mount Everest and Kanchenjunga peaks. This basin is the main contributing area for devastating floods in 2008 in the Bihar state of India. The catchment can be divided into three sub-catchments, namely, Arun, Sunkosi, and Tamur. A morphometric analysis shows the nature of drainage in the upper catchment of Kosi River and some causes behind the high-intensity floods by comparing the properties of these three sub-catchments. It shows that the highest-order drains are present in both Arun and Sunkosi and the length of the first-order drains is very high (6,088 km) due to the absence of vegetation and also due to the barren/rocky surface which has tremendous potential to generate runoff. Due to highest mean channel gradient in Tamur sub-basin compared to others, it has the highest flow kinetic velocity. Also, the results show that the Arun sub-catchment has the highest potential to contribute runoff and sediment. One of the major causes behind the high intensity of floods is that the sub-catchments Arun and Sunkosi have a nearly equal time of concentration, so they contribute their peak floods at the same time and hence double the intensity of floods.     

The effect of dissolved barium on biogeochemical processes at cold seeps

A numerical model was applied to investigate and quantify the biogeochemical processes fueled by the expulsion of barium and methane-rich fluids in the sediments of a giant cold-seep area in the Derugin Basin (Sea of Okhotsk). Geochemical profiles of dissolved Ba²⁺, Sr²⁺, Ca²⁺, SO₄²⁻, HS⁻, DIC, I⁻ and of calcium carbonate (CaCO₃) were fitted numerically to constrain the transport processes and the kinetics of biogeochemical reactions. The model results indicate that the anaerobic oxidation of methane (AOM) is the major process proceeding at a depth-integrated rate of 4.9 μmol cm⁻² a⁻¹, followed by calcium carbonate and strontian barite precipitation/dissolution processes having a total depth-integrated rate of 2.1 μmol cm⁻² a⁻¹. At the low seepage rate prevailing at our study site (0.14 cm a⁻¹) all of the rising barium is consumed by precipitation of barite in the sedimentary column and no benthic barium flux is produced. Numerical experiments were run to investigate the response of this diagenetic environment to variations of hydrological and biogeochemical conditions. Our results show that relatively low rates of fluid flow (<∼5 cm a⁻¹) promote the dispersed precipitation of up to 26 wt% of barite and calcium carbonate throughout the uppermost few meters of the sedimentary column. Distinct and persistent events (several hundreds of years long) of more vigorous fluid flow (from 20-110 cm a⁻¹), instead, result in the formation of barite-carbonate crusts near the sediment surface. Competition between barium and methane for sulfate controls the mineralogy of these sediment precipitates such that at low dissolved methane/barium ratios (<4-11) barite precipitation dominates, while at higher methane/barium ratios sulfate availability is limited by AOM and calcium carbonate prevails. When seepage rates exceed 110 cm a⁻¹, barite precipitation occurs at the seafloor and is so rapid that barite chimneys form in the water column. In the Derugin Basin, spectacular barite constructions up to 20 m high, which cover an area of roughly 22 km² and contain in excess of 5 million tons of barite, are built through this process. In these conditions, our model calculates a flux of barium to the water column of at least 20 μmol cm⁻² a⁻¹. We estimate that a minimum of 0.44 × 10⁶ mol a⁻¹ are added to the bottom waters of the Derugin Basin by cold seep processes, likely affecting the barium cycle in the Sea of Okhotsk.