A preliminary methods comparison for measurement of dissolved organic nitrogen in seawater

Routine determination of dissolved organic nitrogen (DON) is performed in numerous laboratories around the world using one of three families of methods: UV oxidation (UV), persulfate oxidation (PO), or high temperature combustion (HTC). Essentially all routine methods measure total dissolved nitrogen (TDN) and calculate DON by subtracting the dissolved inorganic nitrogen (DIN). While there is currently no strong suggestion that any of these methods is inadequate, there are continuing suspicions of slight inaccuracy by UV methods.This is a report of a broad community methods comparison where 29 sets (7 UV, 13 PO, and 9 HTC) of TDN analyses were performed on five samples with varying TDN and DIN concentrations. Analyses were done in a “blind” procedure with results sent to the first author. With editing out one set of extreme outliers (representing 5 out of 145 ampoules analyzed), the community comparability for analyzing the TDN samples was in the 8–28% range (coefficient of variation representing one standard deviation for the five individual samples by 28 analyses). When DIN concentrations were subtracted uniformly (single DIN value for each sample), the comparability was obviously worse (19–46% cv). This comparison represents a larger and more diverse set of analyses, but the overall comparability is only marginally better than that of the Seattle workshop of a decade ago. Grouping methods, little difference was seen other than inconclusive evidence that the UV methods gave TDN values for several of the samples higher than HTC methods. Since there was much scatter for each of the groups of methods and for all analyses when grouped, it is thought that more uniformity in procedures is probably needed. An important unplanned observation is that variability in DIN analyses (used in determining the final analyte in most UV and PO methods) is essentially as large as the variability in the TDN analyses.This exercise should not be viewed as a qualification exercise for the analysts, but should instead be considered a broad preliminary test of the comparison of the families of methods being used in various laboratories around the world. Based on many independent analyses here, none of the routinely used methods appears to be grossly inaccurate, thus, most routine TDN analyses being reported in the literature are apparently accurate. However, it is not reassuring that the ability of the international community to determine DON in deep oceanic waters continues to be poor. It is suggested that as an outgrowth of this paper, analysts using UV and PO methods experiment and look more carefully at the completeness of DIN conversion to the final analyte and also at the accuracy of their analysis of the final analyte. HTC methods appear to be relatively easy and convenient and have potential for routine adoption. Several of the authors of this paper are currently working together on an interlaboratory comparison on HTC methodology.     

The MEMIN research unit: Scaling impact cratering experiments in porous sandstones

Abstract– The MEMIN research unit (Multidisciplinary Experimental and Modeling Impact research Network) is focused on analyzing experimental impact craters and experimental cratering processes in geological materials. MEMIN is interested in understanding how porosity and pore space saturation influence the cratering process. Here, we present results of a series of impact experiments into porous wet and dry sandstone targets. Steel, iron meteorite, and aluminum projectiles ranging in size from 2.5 to 12 mm were accelerated to velocities of 2.5–7.8 km s^?1, yielding craters with diameters between 3.9 and 40 cm. Results show that the target’s porosity reduces crater volumes and cratering efficiency relative to nonporous rocks. Saturation of pore space with water to 50% and 90% increasingly counteracts the effects of porosity, leading to larger but flatter craters. Spallation becomes more dominant in larger‐scale experiments and leads to an increase in cratering efficiency with increasing projectile size for constant impact velocities. The volume of spalled material is estimated using parabolic fits to the crater morphology, yielding approximations of the transient crater volume. For impacts at the same velocity these transient craters show a constant cratering efficiency that is not affected by projectile size.     

Hypervelocity impacts on dry and wet sandstone: Observations of ejecta dynamics and crater growth

Abstract– This study deals with the investigation of highly dynamic processes associated with hypervelocity impacts on porous sandstone. For the impact experiments, two light‐gas accelerators with different calibers were used, capable of accelerating steel projectiles with diameters ranging from 2.5 to 12 mm to several kilometers per second. The projectiles impacted on dry and water‐saturated Seeberger Sandstone targets. The study includes investigations of the influence of pore water on the shape of the ejecta cloud as well as transient crater growth. The results show a significant influence of pore water on ejecta behavior. Steeper ejecta cone angles are observed if the impacts are conducted on wet sandstones. The transient crater grows at a faster rate and reaches a larger diameter if the target is water saturated. In our experiments, target porosity leads to smaller crater sizes compared with nonporous targets. Water within the pore space reduces porosity and counteracts this process. Power law fits were applied to the crater growth curves. The results show an increase in the scaling exponent μ with increasing pore space saturation.     

Impact cratering in sandstone: The MEMIN pilot study on the effect of pore water

Abstract– Planetary surfaces are subjected to meteorite bombardment and crater formation. Rocks forming these surfaces are often porous and contain fluids. To understand the role of both parameters on impact cratering, we conducted laboratory experiments with dry and wet sandstone blocks impacted by centimeter‐sized steel spheres. We utilized a 40 m two‐stage light‐gas gun to achieve impact velocities of up to 5.4 km s^?1. Cratering efficiency, ejection velocities, and spall volume are enhanced if the pore space of the sandstone is filled with water. In addition, the crater morphologies differ substantially from wet to dry targets, i.e., craters in wet targets are larger, but shallower. We report on the effects of pore water on the excavation flow field and the degree of target damage. We suggest that vaporization of water upon pressure release significantly contributes to the impact process.     

A porosity-gradient replacement approach for computational simulation of chemical-dissolution front propagation in fluid-saturated porous media including pore-fluid compressibility

In dealing with chemical-dissolution-front propagation problems in fluid-saturated porous media, the chemical dissolution front represented by the porosity of the medium may have a very steep slope (i.e., a very large porosity gradient) at the dissolution front, depending on the mineral dissolution ratio that is defined as the equilibrium concentration of the dissolved minerals in the pore-fluid to the solid molar density of the dissolvable minerals in the solid matrix. When the mineral dissolution ratio approaches zero, the theoretical value of the porosity gradient tends to infinity at the chemical dissolution front. Even for a very small value of the mineral dissolution ratio, which is very common in geochemical systems, the porosity gradient can be large enough to cause the solution hard to converge when the conventional finite element method is used to solve a chemical dissolution problem in a fluid-saturated porous medium where the pore-fluid is compressible. To improve the convergent speed of solution, a porosity-gradient replacement approach, in which the term involving porosity-gradient computation is replaced by a new term consisting of pore-fluid density-gradient and pressure-gradient computation, is first proposed and then incorporated into the finite element method in this study. Through comparing the numerical results obtained from the proposed approach with the theoretical solutions for a benchmark problem, it has been demonstrated that not only can the solution divergence be avoid, but also the accurate simulation results can be obtained when the proposed porosity-gradient replacement approach is used to solve chemical-dissolution-front propagation problems in fluid-saturated porous media including pore-fluid compressibility.     

Soft-sediment deformation of Late Pleistocene sediments along the southwestern coast of the Baltic Sea (NE Germany)

A 1,460-m-long profile of a Late Glacial subglacial, glacio-fluvial, glacio-limnic and glacio-deltaic sequence exposed at a cliff section on Usedom Island (SW Baltic Sea coast) is described. The sequence is up to 31 m thick and shows sedimentary structures typical of a glacial setting. Soft-sediment deformation is encountered and is associated with changes in lithology. These deformations include liquefaction, slumping, and faulting. As the most plausible cause, earthquake-induced shaking is discussed. The associated neotectonic activity is seen as a consequence of the postglacial isostatic crustal rebound. As the deglaciation earthquake ratio diminishes with time and as the rebound is phasing out, no large earthquakes are anticipated for northern Germany, although in conclusion the lithosphere of the North German Basin has to be regarded as weakened by repeated ice loading and deloading.     

Regional-scale airborne electromagnetic surveying of the Yucatan karst aquifer (Mexico): geological and hydrogeological interpretation

Geometry and connectivity of high-permeability zones determine groundwater flow in karst aquifers. Efficient management of karst aquifers requires regional mapping of preferential flow paths. Remote-sensing technology provides tools to efficiently map the subsurface at such scales. Multi-spectral remote sensing imagery, shuttle radar topography data and frequency-domain airborne electromagnetic (AEM) survey data were used to map karst-aquifer structure on the Yucatan Peninsula, Mexico. Anomalous AEM responses correlated with topographic features and anomalous spectral reflectance of the terrain. One known preferential flow path, the Holbox fracture zone, showed lower bulk electrical resistivity than its surroundings in the AEM surveys. Anomalous structures delineated inland were sealed above by a low-resistivity layer (resistivity: 1–5 Ωm, thickness: 5–6?m). This layer was interpreted as ejecta from the Chicxulub impact (Cretaceous/Paleogene boundary), based on similar resistivity signatures found in borehole logs. Due to limited sensitivity of the AEM survey, the subsurface configuration beneath the low-resistivity layer could not be unambiguously determined. AEM measurements combined with remote-sensing data analysis provide a potentially powerful multi-scale methodology for structural mapping in karst aquifers on the Yucatan Peninsula and beyond.     

BAM‐S005 Type A and B: New Silicate Reference Glasses for Microanalysis

To test whether the silicate reference glasses BAM‐S005‐A and BAM‐S005‐B from BAM (The Federal Institute for Materials Research and Testing, Germany) are suitable materials for microanalysis, we investigated the homogeneity of these reference glasses using the microanalytical techniques EPMA, LA‐ICP‐MS and SIMS. Our study indicated that all major and most trace elements are homogeneously distributed at micrometre sampling scale in both types of glass. However, some trace elements (e.g., Cs, Cl, Cr, Mo and Ni) seem to be inhomogeneously distributed. We also determined the composition of BAM‐S005‐A and BAM‐S005‐B. The EPMA data of major elements confirmed the information values specified by the certificate. With the exception of Sr, Ba, Ce and Pb, our trace element data by LA‐ICP‐MS were also in agreement with the certified values within the stated uncertainty limits. The reasons for the discrepancy in these four elements are still unclear. In addition, we report new data for twenty‐two further trace elements, for which the concentrations were not certified. Based on our investigation, we suggest that both of these materials are suitable for many microanalytical applications.     

Quaternary coastline evolution of Lake Ohrid (Macedonia/Albania)

Lake Ohrid (between FYR of Macedonia and Albania), situated in an active tectonic region of the Balkanides, is characterized by N ?? S trending active faults. To reconstruct the Holocene shoreline evolution we investigated the coastline using sediment cores and geophysical methods to image sedimentary and tectonic structures. We revealed areas of differing sedimentation regimes. The plains north and south of the lake are dominated by clastic input related to climate variations and uplift/erosion, whereas the steep western and eastern margins are controlled by recent tectonics. Furthermore, no evidence for a much higher lake-level during the Holocene was found in the plains north and south of the lake, except rare temporary floodings. This is supported by mappings of the limestone cliffs around Lake Ohrid, which yielded no evidence for abrasional platforms or notches as indicators for past highstands.