Dissolved organic matter tracers reveal contrasting characteristics across high arsenic aquifers in Cambodia:A fluorescence spectroscopy study

Organic matter in the environment is involved in many biogeochemical processes,including the mobilization of geogenic trace elements,such as arsenic,into groundwater.In this paper we present the use of fluorescence spectroscopy to characterize the dissolved organic matter(DOM)pool in heavily arsenicaffected groundwaters in Kandal Province,Cambodia.The fluorescence DOM(fDOM)characteristics between contrasting field areas of differing dominant lithologies were compared and linked to other hydrogeochemical parameters,including arsenic and dissolved methane as well as selected sedimentary characteristics.Absorbance-corrected fluorescence indices were used to characterize depth profiles and compare field areas.Groundwater fDOM was generally dominated by terrestrial humic and fulvic-like components,with relatively small contributions from microbially-derived,tryptophan-like components.Groundwater fDOM from sand-dominated sequences typically contained lower tryptophan-like,lower fulvic-like and lower humic-like components,was less bioavailable,and had higher humification index than clay-dominated sequences.Methane concentrations were strongly correlated with fDOM bioavailability as well as with tryptophan-like components,suggesting that groundwater methane in these arsenic-prone aquifers is likely of biogenic origin.A comparison of fDOM tracers with sedimentary OM tracers is consistent with the hypothesis that external,surface-derived contributions to the aqueous DOM pool are an important control on groundwater hydrogeochemistry.     

Tidal hydrology and habitat utilization by resident nekton in<Emphasis Type="Italic">Pragmites</Emphasis> and Non-<Emphasis Type="Italic">Phragmites</Emphasis> Marshes

We compared nekton densities over a range of measured flooding conditions and locations withinPhragmites australis andSpartina alterniflora (salt marsh cordgrass) at the Charles Wheeler Salt Marsh, located on the lower Housatonic River estuary in southwestern Connecticut. Nekton were sampled on nine spring high tide events from May to October 2000 using bottomless lift nets positioned between 0–5 and 10–20 m from the creek edge. Flooding depth, duration, and frequency were measured from each vegetation type during each sampling month. Benthic macroinvertebrate density was also measured within each vegetation type in May, July, and September. Frequency of flooding was 52% lower and flooding depth and duration were also significantly reduced inP. australis relative toS. alterniflora. A total of 4,197 individuals representing 7 species, mostlyPalaemonetes pugio (dagger-blade grass shrimp) andFundulus heteroclitus (common mummichog), were captured.P. pugio densities were significantly greater inS. alterniflora as were benthic macroinvertebrate density and taxa richness during May, but not during June or October. Total fish density was not significantly different betweenP. australis andS. alterniflora and was independent of location on the marsh. Significantly more juvenileF. heteroclitus were collected withinS. alterniflora relative toP. australis in June and July, suggesting that recruitment of this species may be lower inP. australis habitat. Fish density generally did not vary predictably across the range of flooding depth and duration; there was a positive relationship between flooding depth and fish density inS. alterniflora. The measured reduction in flooding frequency (52%) withinP. australis at the Housatonic site would result in an average total monthly fish use, expressed as density, of 447 ind m⁻² forP. australis and 947 ind m⁻² forS. alterniflora. WhenP. australis expansion results in reduction of flooding frequency and duration, nekton community composition can change, access to the marsh surface is reduced twofold, and nursery habitat function may be impaired.     

Inuit spring hunting techniques and local knowledge of the ringed seal in Arctic Bay (Ikpiarjuk), Nunavut

Inuit hunting techniques used to catch ringed seals ( Phoca hispida ) were observed April-June 1993 on the land-fast ice of Admiralty Inlet, Nunavut, and adjoining fjords and bays. In addition, a survey of hunting techniques and knowledge of ringed seal biology and behaviour was conducted in the community of Arctic Bay (Ikpiarjuk), Nunavut, January-February 1994. A total of 246 seal structures were found in 31 days of hunting and 34 successful kills were observed. An experienced Inuk hunter found subnivean structures by sight, by walking on drifts and by probing snowdrifts with a harpoon ( unaaq ). Most structures were found using subtle visual cues. Breaking through the roof of a lair was the most common hunting technique observed in this study. Pups captured in this manner were subsequently used to lure the mother back into the breathing hole where she was harpooned. Ringed seals were also hunted by a number of other methods that have been described previously in the literature. Respondents in the hunter survey indicated that the ringed seal was the most important animal used by Arctic Bay Inuit. They also reported a variety of biological findings about ringed seals including: size differences among seals in different regions of the pack ice; that adult male ringed seals ( tiggak ) emitted a strong, mustelid-like odour from December until late May or early June. Hunters also reported that males were occasionally caught when coming to retrieve pups. All respondents reported seeing increasing frequencies of liver abnormalities in their ringed seal catches.     

A Method for Installing Miniature Multilevel Sampling Wells

Abstract. A method has been developed to install miniature multilevel ground-water sampling wells in shallow, unconsoli-dated aquifers at sites without truck access. An advantage of these wells over the traditional bundle-type multilevel is that this type of installation causes minimal aquifer disturbance. Thus, miniature multilevels can be installed while a tracer test is in progress. Furthermore, only hand tools are needed in the field, and equipment and materials are easily obtained and inexpensive. The time required for installation is comparable to other methods.     

Spatial coherence of temperature fluctuations in the atmospheric surface layer

Simultaneous temperature fluctuations have been measured along directions both parallel and orthogonal to the wind direction in the atmospheric surface layer. Ensemble-averaged temperature distributions associated with the ramp-like feature observed in instantaneous temperature traces indicate that the average duration of the ramp is approximately independent of height. Application of Davenport's geometric similarity of coherence of temperature fluctuations yields approximate estimates for the spatial extent of the structure characterized by the ramp. The longitudinal extent is approximately 12 times the vertical extent and 17 times the lateral extent.     

Temperature structure in the atmospheric surface layer

Production, transport and dissipation terms in the temperature variance equation have been measured in the atmospheric surface layer. The transport term is, within the experimental uncertainty, negligible. The dissipation term, determined by assuming local isotropy, is approximately equal to production under near-neutral conditions. For moderately unstable conditions, the ratio of production to dissipation is 1.4. The resulting imbalance in the budget is attributed to the inequality between the three components of the dissipation term. The Kolmogorov constant for temperature is found to be about 0.8.     

Late Holocene climatic changes in Tierra del Fuego based on multiproxy analyses of peat deposits

A ca. 1400-yr record from a raised bog in Isla Grande, Tierra del Fuego, Argentina, registers climate fluctuations, including a Medieval Warm Period, although evidence for the ‘Little Ice Age’ is less clear. Changes in temperature and/or precipitation were inferred from plant macrofossils, pollen, fungal spores, testate amebae, and peat humification. The chronology was established using a ¹⁴C wiggle-matching technique that provides improved age control for at least part of the record compared to other sites. These new data are presented and compared with other lines of evidence from the Southern and Northern Hemispheres. A period of low local water tables occurred in the bog between A.D. 960-1020, which may correspond to the Medieval Warm Period date range of A.D. 950-1045 generated from Northern Hemisphere tree-ring data. A period of cooler and/or wetter conditions was detected between ca. A.D. 1030 and 1100 and a later period of cooler/wetter conditions estimated at ca. cal A.D. 1800-1930, which may correspond to a cooling episode inferred from Law Dome, Antarctica.     

Rapid formation of the Small Isles Tertiary centre constrained by precise Ar/Ar and U–Pb ages

The relative chronology of magmatic and tectonic events is key to an understanding of the influence of the Iceland plume on the North Atlantic. In particular, the location and duration of magmatism is of fundamental importance. Initial widespread flood basalt formation occurred in Baffin Island, Greenland, and Britain before complete plate break up at 56 Ma after which time magmatism became concentrated in the active rift zone.

Historically the British Tertiary Igneous Province (BTIP) has been instrumental in advancing many concepts of igneous petrology. However, the absolute age and duration of the province remains unresolved. Here, we present new internally consistent ⁴⁰Ar/³⁹Ar ages that help to constrain the volcanic activity in the Small Isles centre to within 2 my. This short duration has implications for the onset of magmatism in the larger North Atlantic province, the rapid unroofing of the Rum volcano, and more significantly, some of the evidence used to propose pulsing of the Iceland plume.     

From the kitchen and the field: Gender and maize diversity in the Bajío region of Mexico

The conservation of crop genetic diversity in farmers' fields is important for future food security. Recent research on women and biodiversity has emphasized the importance of women's knowledge in plant domestication and biodiversity conservation. This paper presents a case study of the differences in women's and men's knowledge of maize landraces in four different environments in the Bajío region of Mexico. We argue that research on crop diversity and conservation needs to include both men and women farmers' knowledge. Gendered knowledge results from men and women in a household being responsible for different tasks and sometimes for farming separate plots. In addition, as economic pressures increasingly force men to work away from their communities for extended periods, women become the primary agricultural decision-makers.