Spectrophotometric determination of pH in seawater off Taiaroa Head,Otago, New Zealand: Full-spectrum modelling and prediction of pCO2 levels

Accurate measurement of seawater pH has long been sought by marine chemists (for example: [Dickson, A.G. 1993a. The measurement of sea water pH. Marine Chemistry, 44, 131–142, Dickson, A.G. 1993b. pH buffers for sea water media based on the total hydrogen ion concentration scale. Deep-Sea Research, 40, 107–118; Zhang, 1996; Tapp, M., Hunter, K.A., Currie, K. and Macaskill, B. 2000. Apparatus of continuous-flow underway spectrophotometric measurement of surface water pH. Marine Chemistry 72(2–4), 193–202; Friis, K., Koetzinger, A., Wallace, D.W.R. 2004. Spectrophotometric pH measurement in the ocean: Requirements, design and testing of an autonomous charge-coupled device detector system. Limnology and Oceanography: Methods 2, 126–136]. Recently, such attempts have taken on greater significance as anthropogenic carbon dioxide emissions may create rapidly changing oceanic pH. Spectrophotometric techniques have been accepted generally as the best for determination of seawater pH. Here we report a new technique using thymol blue as the indicator dye and fitting the entire spectrum from 400 to 900 nm rather than measuring the absorbance values at only two or three points in the spectrum. This full-spectrum modelling enables a reduction in signal to noise over other techniques. In the laboratory, we find with seawater samples a pH precision increase of five-fold “within” a sample and seven-fold “between” samples when comparing the full spectrum to the three-point method of analysis [Zhang, H., Byrne, R.H. 1996. Spectrophotometric pH measurements of surface seawater at in-situ conditions: absorbance and protonation behaviour of thymol blue. Marine Chemistry 52, 17–25].     

Study on the connectivity of heavy oil reservoirs by ultraviolet spectrum technique in the western part of the QHD32-6 oilfield

As a new method, the ultraviolet spectrum technique is applied to studying the connectivity of biode-gradable heavy oil reservoirs. The similarity of crude oils can be judged according to the extinction coefficient （E） because aromatic hydrocarbons and non-hydrocarbons have conjugated bonds and obvious absorption in the ultraviolet range, and different materials have different characteristics and additives. The relationship diagram is made in terms of the extinction coefficients （E） of the samples by taking E as the Y-axis and wavelength as the X-axis. The connectivity of oil reservoirs is estimated according to the curve positions and characteristic fingerprints of the sampies. The connectivity of part of the reservoirs in the western part of the QHD32-6 oilfield was studied with this method. The results showed that the connectivity of samples from wells F7 and F8 in the Nm-2 oil reservoir zone is good, that of samples from wells F17 and F20 in the Nm-1 oil reservoir zone also is good, and that of samples from wells F17, F19, and F20 is poor.     

Bringing GPS into harsh environments for fully automated deformation monitoring

Engineering projects that require deformation monitoring frequently utilize geodetic sensors to measure displacements of target points located in the deformation zone. In situations where control stations and targets are separated by a kilometer or more, GPS can offer higher precision position updates at more frequent intervals than can normally be achieved using total station technology. For large-scale deformation projects requiring the highest precision, it is therefore advisable to use a combination of the two sensors. In response to the need for high precision, continuous GPS position updates in harsh deformation monitoring environments, a software has been developed that employs triple-differenced carrier-phase measurements in a delayed-state Kalman filter. Two data sets were analyzed to test the capabilities of the software. In the first test, a GPS antenna was displaced using a translation stage to mimic slow deformation. In the second test, data collected at a large open pit mine were processed. It was shown that the delayed-state Kalman filter developed could detect millimeter-level displacements of a GPS antenna. The actual precision attained depends upon the amount of process noise infused at each epoch to accommodate the antenna displacements. Higher process noise values result in quicker detection times, but at the same time increase the noise in the solutions. A slow, 25 mm displacement was detected within 30 min of the full displacement with sigma values in E, N and U of ±10 mm or better. The same displacement could also be detected in less than 5 h with sigma values in E, N and U of ±5 mm or better. The software works best for detecting long period deformations (e.g., 20 mm per day or less) for which sigma values of 1–2 mm are attained in all three solution components. It was also shown that the triple-differenced carrier-phase observation can be used to significantly reduce the effects of residual tropospheric delay that would normally plague double-differenced observations in harsh GPS environments.

基于GIS的北京城市形态研究

经典的城市形态理论包括同心圆理论、扇形理论和多核心理论.利用2002年北京市土地利用图,采用GIS缓冲区分析的方法,分析了北京市各功能用地的方向特征和圈层特征.结果表明:北京市的土地利用体现了明显的圈层特征,同时各类功能用地在各方向的分布又明显受到了河流、交通干道和工业区等地理要素的影响.北京没有形成城市总体规划的多中心布局,第一道绿化隔离地区中绿地面积没有明显高出其他地区,基本上已经失去了中心城区和边缘集团隔离开的功能.总体上,北京城市空间形态主要是同心圆和扇形的结合,更接近同心圆理论和扇形理论的混合形式.     

A bootstrap based space–time surveillance model with an application to crime occurrences

This study proposes a bootstrap-based space–time surveillance model. Designed to find emerging hotspots in near-real time, the bootstrap based model is characterized by its use of past occurrence information and bootstrap permutations. Many existing space–time surveillance methods, using population at risk data to generate expected values, have resulting hotspots bounded by administrative area units and are of limited use for near-real time applications because of the population data needed. However, this study generates expected values for local hotspots from past occurrences rather than population at risk. Also, bootstrap permutations of previous occurrences are used for significant tests. Consequently, the bootstrap-based model, without the requirement of population at risk data, (1) is free from administrative area restriction, (2) enables more frequent surveillance for continuously updated registry database, and (3) is readily applicable to criminology and epidemiology surveillance. The bootstrap-based model performs better for space–time surveillance than the space–time scan statistic. This is shown by means of simulations and an application to residential crime occurrences in Columbus, OH, year 2000.     

Multiple Volcanic Episodes of Flood Basalts Caused by Underplating

Most Large igneous provinces (LIPs) are emplaced within <10 Ma, with a main pulse of the magmatism in<1 Ma[1]. For example, the Siberian Traps [2] and the Deccan Traps [3] were probably erupted within one million years. Many events, such as the Columbia River event, feature a single pulse of magmatism, followed by a protrac-ted period of magmatism at a much lower rate that is linked to a plume tail[4].     

Estimating hydraulic conductivity using grain-size analyses, aquifer tests, and numerical modeling in a riverside alluvial system in South Korea

Hydraulic conductivity (K) for an alluvial system in a riverbank filtration area in Changwon City, South Korea, has been studied using grain-size distribution, pumping and slug tests, and numerical modeling. The alluvial system is composed of layers: upper fine sand, medium sand, lower fine sand, and a highly conductive sand/gravel layer at the base. The geometric mean of K for the sand/gravel layer (9.89?×?10^?4 m s^?1), as determined by grain-size analyses, was 3.33 times greater than the geometric mean obtained from pumping tests (2.97?×?10^?4 m s^?1). The geometric mean of K estimates obtained from slug tests (3.08?×?10^?6 m s^?1) was one to two orders of magnitude lower than that from pumping tests and grain-size analyses. K estimates derived from a numerical model were compared to those derived from the grain-size methods, slug tests and pumping tests in order to determine the degree of deviation from the numerical model. It is considered that the K estimates determined by the slug tests resemble the uppermost part of the alluvial deposit, whereas the K estimates obtained by grain-size analyses and pumping tests are similar to those from the numerical model for the sand/gravel layer of the riverside alluvial system.     

The contact binary system YY Eri

Relatively new and unanalysed photometric data-sets of the contact binary system YY Eri are presented. The light curves have been analysed using information limit optimization techniques, and the Binary Maker program of Bradstreet (1992).Comparison of the results allows insight into determinacy questions affecting the W UMa type of light curve, which relates to our general understanding of contact binaries. A limiting contact configuration cannot be ruled out on the basis of empirical data-analysis alone.Very careful analysis of the photospheric flux distribution over the surface of the Sun may help establish appropriate values of the gravity brightening parameter for cool dwarf stars. At present, however, empirical photometric information on contact binaries is non-discriminatory: i.e. alternative cosmogonies can find alternative support from available evidence. The implication is then for more and better observational data to allow better real independent parameter determination.     

OBE理念下GIS空间分析课程思政教学设计与实践

以成果导向教育(Outcome Based Education,OBE)和课程思政理念为指导进行课程设计与实践,是地理信息科学专业应用型人才培养的发展趋势.围绕专业人才培养目标和课程教学目标,以反向设计为原则,结合专业毕业要求,确定课程学习成果,然后以成果为导向,设计实施教学改革,将思政元素有机融入专业教学中,培养学生综合素养.地理信息系统(Geographic Information System,GIS)方向的课程《GIS空间分析》是地理信息科学专业核心课程,探索和实施成果导向下的课程思政教学目标的达成,围绕教学目标进行有效的教学设计,结合课程内容从理论知识和实践操作两个层面进行课程思政教学融入设计,提出课程思政融入专业课教学的典型案例和实施路径,包括制定课程目标、确定学习成果、探索和实施新型教学方式、优化课程考核和评价方式等方面.     

Infinitesimal orbits around lagrange points in the elliptic,restricted three-body problem

This study presents a method of obtaining asymptotic approximations for motions near a Lagrange point in the planar, elliptic, restricted three-body problem by using a von Zeipel-type method. The calculations are carried out for a second-order escape solution in the proximity of the equilateral Lagrange point, L ₄, where the primaries' orbital eccentricity is taken as the small parameter .