Composition and origin of organic matter in surface sediments of Lake Sarbsko: A highly eutrophic and shallow coastal lake (northern Poland)

We present an organic geochemical study of surface sediments of Lake Sarbsko, a shallow coastal lake on the middle Polish Baltic coast. The aim was to provide evidence concerning the origin of the organic matter (OM) and its compositional diversity in surface deposits of this very productive, highly dynamic water body. The content and composition of the OM in the bottom sediments were investigated at 11 sampling stations throughout the lake basin. OM sources were assigned on the basis of bulk indicators [total organic carbon (TOC), total nitrogen (TN), δ¹³C_TOC and δ¹⁵N and extractable OM yield], biomarker composition of extractable OM and compound-specific C isotope signatures. The source characterization of autochthonous compounds was verified via phytoplankton analysis. The distribution of gaseous hydrocarbons in the sediments, as well as temporal changes in lake water pH, the concentration of DIC (dissolved inorganic carbon) and δ¹³C_DIC were used to trace OM decomposition.The sedimentary OM is composed mainly of well preserved phytoplankton compounds and shows minor spatial variability in composition. However, the presence of CH₄ and CO₂ in the bottom deposits provides evidence for microbial degradation of sedimentary OM. The transformation of organic compounds in surface, bottom and pore waters via oxidative processes influences carbonate equilibrium in the lake and seasonally favours precipitation or dissolution of CaCO₃.The data enhance our understanding of the relationships between the composition of sedimentary OM and environmental conditions within coastal ecosystems and shed light on the reliability of OM proxies for environmental reconstruction of coastal lakes.     

Devitrite (Na2Ca3Si6O16)—structural, spectroscopic and computational investigations on a crystalline impurity phase in industrial soda-lime glasses

Single crystals of devitrite (Na₂Ca₃Si₆O₁₆) were synthesized as pale-yellow transparent needle shaped crystals using a Na₂MoO₄-flux. Experiments aiming to prepare the K-equivalent of devitrite from the corresponding K₂MoO₄-flux were unsuccessful. The crystal structure of devitrite was determined from single-crystal X-ray diffraction data (Mo-K_α radiation, 2θ_max.?=?25.34°, R_int?=?2.66%) and refined in space group P $ \bar{1} $ (no. 2) to R(|F|)?=?3.08% using 2,513 observed reflections with I?>?2σ(I). Unit-cell parameters are: a?=?7.2291(8), b?=?10.1728(12), c?=?10.6727(12) Å, α?=?95.669(9), β?=?109.792(10), γ?=?99.156(9)°, V?=?719.19(14) ų, Z?=?2. The structure belongs to the group of multiple chain silicates consisting of dreier quadruple chains, i.e. the crystallochemical formula can be written as $ {\hbox{N}}{{\hbox{a}}_2}{\hbox{C}}{{\hbox{a}}_3}\left\{ {{\mathbf{uB}}{,4}_\infty^1} \right\}\left[ {^3{\hbox{S}}{{\hbox{i}}_6}} \right.\left. {{{\hbox{O}}_{16}}} \right\} $ . Linkage between the bands running along [100] is provided by double chains of edge sharing CaO₆-octahedra as well as additional more irregularly coordinated Na- and Ca-cations located in the tunnel-like cavities of the mixed tetrahedral-octahedral framework. Structural investigations were completed by Raman and infrared spectroscopical studies. The allocation of the bands to certain vibrational species was aided by density functional theory (DFT) calculations.     

Fabric evolution at basement–cover interfaces in a fold-and-thrust belt and implications for décollement tectonics (Autochthon, Lower Allochthon, central Scandinavian Caledonides)

Microstructural and magnetic investigations (anisotropy of magnetic susceptibility, AMS) on sections across basement–cover interfaces (BCI) revealed a complex evolution in the crystalline basement rocks beneath and in the basal units of the Caledonian fold-and-thrust belt: (1) Pre-Caledonian mylonitic fabrics in basement granite relate to steep shear zones. (2) Palaeoweathering formed smectite and illite at the expense of feldspar and mica. Secondary Fe-bearing clay minerals and the intensity of the chemical weathering control the bulk susceptibility. Changing susceptibility and AMS relate to a (time) sequence from primary magnetite to secondary paramagnetic clay to pyrite and ferrimagnetic pyrrhotite. (3) Burial compaction with BCI-parallel fabrics. (4) Caledonian cleavage, overprinted by décollement zones with S–C–C′ fabrics. Décollement cataclasis overprinted pre-existing magnetic fabrics and produced horizontal magnetic lineations and subhorizontal foliations defined by the S–C–C′ fabrics. Clay mineral enrichment, together with subsequent, BCI-parallel compaction fabrics, decreased the shear strength in the basement rocks beneath the BCI. Detachments initiated at such low-strength zones and produced allochthonous units with their footwall within crystalline basement rocks, an observation of general importance for orogenic fold-and-thrust belts.     

Complex impact assessment of coastal development in the United Arab Emirates using GIS: a case study of Wurayah Biosphere Reserve

Wadi Wurayah area is one of the major wadis originating and running on the Oman Mountains and drains into the Oman Gulf. These wadis in general and Wadi Wurayah in particular are characterized with a rich diversity of rare and mountainous and freshwater habitats and species. These wadis contain unequal, representative, and sensitive areas of the dry lands ecosystem with natural, outstanding landscapes and cultural heritage, while the socioeconomic situation indicates that it has enough socioeconomic infrastructures to develop new alternatives ecologically and economically sustainable. As most of the United Arab Emirates and the region, the study area is undergoing dramatic changes linked to economic diversification and promotion of tourism. Established under the UNESCO’s Man and the Biosphere Program, Wurayah Biosphere Reserve represents protected areas intended to demonstrate well-balanced relationship between conservation of biodiversity and an appropriate local development. The main objectives of this study are to develop an environmental information system to understand the dynamics of human activities associated to land use in the study area, highlight the threats to the environment, educate people about the basic environmental issues and positive traditional practices, and promote tourism. Based on the gained results, the concept of biosphere reserve as a model is to implement ideas of sustainable land use in practice.     

Temporal and geochemical evolution of the Cenozoic intraplate volcanism of Zealandia

In order to constrain better the distribution, age, geochemistry and origin of widespread Cenozoic intraplate volcanism on Zealandia, the New Zealand micro-continent, we report new ⁴⁰Ar/³⁹Ar and geochemical (major and trace element and Sr–Nd–Hf–Pb isotope) data from offshore (Chatham Rise, Campbell and Challenger Plateaus) and onland (North, South, Auckland, Campbell, Chatham and Antipodes Islands of New Zealand) volcanism on Zealandia. The samples include nephelinite, basanite through phonolite, alkali basalt through trachyte/rhyolite, and minor tholeiite and basaltic andesite, all of which have ocean island basalt (OIB)-type trace element signatures and which range in age from 64.8 to 0.17 Ma. Isotope ratios show a wide range in composition (⁸⁷Sr/⁸⁶Sr = 0.7027–0.7050, ¹⁴³Nd/¹⁴⁴Nd = 0.5128–0.5131, ¹⁷⁷Hf/¹⁷⁶Hf = 0.2829–0.2831, ²⁰⁶Pb/²⁰⁴Pb = 18.62–20.67, ²⁰⁷Pb/²⁰⁴Pb = 15.54–15.72 and ²⁰⁸Pb/²⁰⁴Pb = 38.27–40.34) with samples plotting between mid-ocean-ridge basalts (MORB) and Cretaceous New Zealand intraplate volcanic rocks.Major characteristics of Zealandia's Cenozoic volcanism include longevity, irregular distribution and lack of age progressions in the direction of plate motion, or indeed any systematic temporal or spatial geochemical variations. We believe that these characteristics can be best explained in the context of lithospheric detachment, which causes upwelling and melting of the upper asthenospheric mantle and portions of the removed lithosphere. We propose that a large-scale seismic low-velocity anomaly, that stretches from beneath West Antarctica to Zealandia at a depth of > 600 km may represent a geochemical reservoir that has been in existence since the Cretaceous, and has been supplying the upper mantle beneath Zealandia with HIMU-type plume material throughout the Cenozoic. In addition, the sources of the Cenozoic intraplate volcanism may be at least partially derived through melting of locally detached Zealandia lower lithosphere.     

Coalification and thermal histories of Tertiary basins in relation to late Alpidic evolution of the Eastern Alps

The thermal histories of Tertiary basins situated around and within the Eastern Alps are examined using coalification data.Waples' method is used to estimate paleogeothermal conditions. The data suggest that the basins' thermal histories are intimately related to late Alpidic geodynamics of the Eastern Alps.Basins situated near the thrust front (Eastern Alpine foredeep, Vienna basin) are characterized by hypothermal histories and low coalification gradients. This is a consequence of relatively thick crust, high paleosedimentation rates in the Alpine foredeep, and Oligocene to Early Miocene stacking of cool sediments along the southern margin of the Eastern Alpine foredeep. Extension in the Vienna basin region is restricted mainly to shallow crustal levels and did not change the thermal pattern beneath the Alpine nappes. Major hyperthermal events of Oligocene age and local coalification maxima in the central Slovenian basin date from magmatic activity along the Periadriatic lineament, caused by Oligocene subduction. In Miocene times subduction migrated eastward and magmatic activity shifted to the northern Slovenian and Styrian basins, resulting in a strong hyperthermal phase of Ottnangian to Lower Badenian age in these basins.Rapid uplift of the Tauern window in the central part of the Eastern Alps, due to buoyancy, is related to E-W directed crustal stretching and resulted in raised heat flow in Miocene times in the Tauern window region, and in relatively high rank in adjacent Tertiary basins (Wagrain, Tamsweg).Present geothermal patterns are controlled primarily by raised heat flow along the south-eastern margin of the Alps, a consequence of thinned crust beneath the Pannonian basin.

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Zusammenfassung Die Inkohlungsbilder von tertiären Sedimentbecken, die im Bereich der Ostalpen situiert sind, werden hinsichtlich der thermischen Geschichte diskutiert. In einigen Becken erfolgt eine Abschätzung der paläogeothermischen Verhältnisse mit Hilfe derWaples-Methode. Die Inkohlungsbilder der Tertiärbecken belegen eine enge Beziehung zwischen der thermischen Geschichte dieser Becken und der jungalpidischen Geodynamik der Ostalpen.In der Nähe der Überschiebungsfront gelegene Becken (Molassebecken, Wiener Becken) werden durch hypothermische Verhältnisse und geringe Inkohlung charakterisiert. Dies ist eine Folge relativ dicker Kruste, hoher Paläo-Sedimentationsraten in der alpinen Vortiefe und des Übereinanderstapelns kühler Sedimente am Südrand des Molassebeckens während Oligozän und frühem Miozän. Die Extension im Wiener Becken war auf den obersten Krustenabschnitt beschränkt und hat die thermischen Verhältnisse unterhalb der alpinen Decken nicht beeinflußt.Die magmatische Aktivität entlang der Periadriatischen Naht steht in Zusammenhang mit der oligozänen Subduktion und ist für hyperthermische Ereignisse und lokale Inkohlungsmaxima in oligozänen Sedimenten des zentralen Slowenischen Beckens verantwortlich. Im Miozän wanderte die Subduktion ostwärts und die magmatische Aktivität verlagerte sich in das nördliche Slowenische und Steirische Becken. Dadurch wurde in diesen Becken eine starke hyperthermische Phase während Ottnang bis Unterbaden initiiert.Der rasche isostatische Aufstieg des Tauernfensters in den zentralen Ostalpen steht mit miozäner, E-W gerichteter Dehnungstektonik in Zusammenhang. Er ist für erhöhten Wärmefluß im Miozän im Bereich des Tauernfensters und für die relativ hohe Inkohlung des Wagrainer und Tamsweger Beckens verantwortlich.Die heutigen geothermischen Verhältnisse werden vor allem durch erhöhten Wärmefluß am Südostrand der Alpen geprägt. Dieser ist eine Folge der Krustenausdünnung unter dem Pannonischen Becken.

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Résumé La houillification des bassins sédimentaires tertiaires des Alpes orientales est discutée dans la perspective de leur histoire thermique. Les conditions paléogéothermiques sont estimées au moyen de la méthode deWaples. L'étude de la houillification de ces bassins montre une relation étroite entre leur histoire thermique et la géodynamique des Alpes orientales à la fin du Tertiaire.Ces bassins, situés à proximité du front de charriage — il sagit du Bassin molassique et du Bassin viennois —, se caractérisent par leur condition «hypothermique» et leur faible gradient de houillification; cette propriété provient de l'épaississement de la croute terrestre due à une sédimentation rapide en avant des Alpes et à l'empilement tectonique des sédiments froids les uns sur les autres le long de la bordure méridionale du Bassin molassique au cours de l'Oligocène et du Miocène inférieur. L'extension, dans la région du Bassin viennois, s'est limitée à un niveau crustal peu profond et n'a pas influencé la situation thermique dans les nappes alpines.L'activité magmatique le long du linéament périadriatique, due à la subduction oligocène, est contemporaine des événements «hyperthermiques» et des maxima locaux de houillification dans les sédiments oligocènes du bassin central de Slovénie.Pendant le Miocène, la subduction progressa vers l'est et l'activité magmatique se déplaça vers les bassins de Slovénie septentrionale et de Styrie, avec comme conséquence, dans ces bassins, une phase «hyperthermique» marquée à l'Ottnangien et au Badenien inférieur.La montée isostatique rapide de la Fenêtre des Tauern dans la partie centrale des Alpes orientales est en relation avec l'extension tectonique est-ouest au Miocène; elle est responsable d'un flux thermique élevé dans la région de la Fenêtre et d'une houillification relativement importante dans les bassins tertiaires adjacents de Wagrain et de Tamsweg.La géothermie actuelle de la bordure sud-est des Alpes est régie par un flux thermique élevé, conséquence de l'amincissement crustal sous le bassin Pannonique.

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Carbonatite diversity in the Central Andes: the Ayopaya alkaline province,Bolivia

The Ayopaya province in the eastern Andes of Bolivia, 100 km NW of Cochabamba, hosts a Cretaceous alkaline rock series within a Palaeozoic sedimentary sequence. The alkaline rock association comprises nepheline-syenitic/foyaitic to ijolitic intrusions, carbonatite, kimberlite, melilititic, nephelinitic to basanitic dykes and diatremes, and a variety of alkaline dykes. The carbonatites display a wide petrographic and geochemical spectrum. The Cerro Sapo area hosts a small calciocarbonatite intrusion and a multitude of ferrocarbonatitic dykes and lenses in association with a nepheline-syenitic stock. The stock is crosscut by a spectacular REE-Sr-Th-rich sodalite-ankerite-baryte dyke system. The nearby Chiaracke complex represents a magnesiocarbonatite intrusion with no evidence for a relationship to igneous silicate rocks. The magnesiocarbonatite ( REE up to 1.3 wt%) shows strong HREE depletion, i.e. unusually high La/Yb ratios (520–1,500). Calciocarbonatites ( REE up to 0.5 wt%) have a flatter REE distribution pattern (La/Yb 95–160) and higher Nb and Zr contents. The sodalite-ankerite-baryte dyke system shows geochemical enrichment features, particularly in Na, Ba, Cl, Sr, REE, which are similar to the unusual natrocarbonatitic lavas of the recent volcano of Oldoinyo Lengai, Tanzania. The Cerro Sapo complex may be regarded as an intrusive equivalent of natrocarbonatitic volcanism, and provides an example for carbonatite genesis by late-stage crystal fractionation and liquid immiscibility. The magnesiocarbonatite intrusion of Chiaracke, on the other hand, appears to result from a primary carbonatitic mantle melt. Deep seated mantle magmatism/metasomatism is also expressed by the occurrence of a kimberlite dyke. Neodymium and strontium isotope data (_Nd 1.4–5.4, ⁸⁷Sr/⁸⁶ Sr<Bulk Earth) indicate a depleted mantle source for the alkaline magmatism. The magmatism of the Ayopaya region is attributed to failed rifting of western South America during the Mesozoic and represents the only occurrence of carbonatite and kimberlite rocks in the Andes.     

Calcareous nannoplankton, planktonic foraminiferal, and carbonate carbon isotope stratigraphy of the Cenomanian–Turonian boundary section in the Ultrahelvetic Zone (Eastern Alps, Upper Austria)

Ultrahelvetic units of the Eastern Alps were deposited on the distal European continental margin of the (Alpine) Tethys. The Rehkogelgraben section (“Buntmergelserie”, Ultrahelvetic unit, Upper Austria) comprises a 5 m thick succession of upper Cenomanian marl-limestone cycles overlain by a black shale interval composed of three black shale layers and carbonate-free claystones, followed by lower Turonian white to light grey marly limestones with thin marl layers. The main biostratigraphic events in the section are the last occurrence of Rotalipora and the first occurrences of Helvetoglobotruncana helvetica and Quadrum gartneri. The thickest black shale horizon has a TOC content of about 5%, with predominantly marine organic matter of kerogen type II. Vitrinite reflectance and Rock-Eval parameter T_max (<424 °C) indicate low maturity. HI values range from 261 to 362 mg HC/g TOC. δ¹³C values of bulk rock carbonates display the well documented positive shift around the black shale interval, allowing correlation of the Rehkogelgraben section with other sections such as the Global Boundary Stratotype Section and Point (GSSP) succession at Pueblo, USA, and reference sections at Eastbourne, UK, and Gubbio, Italy. Sediment accumulation rates at Rehkogelgraben (average 2.5 mm/ka) are significantly lower than those at Pueblo and Eastbourne.     

Evidence for a warmer period during the 12th and 13th centuries AD from chironomid assemblages in Southampton Island, Nunavut, Canada

This study presents the Late-Holocene evolution of a northern Southampton Island (Nunavut, Canada) lake, using fossil chironomids supported by sedimentological evidences (XRF, grain size and CNS). All proxies revealed a relatively stable environment during the last millennium with short-lived events driving changes in the entire lake ecosystem. The chironomid-based paleotemperatures revealed variations of significant amplitude coincident with changes in the sediment density and chemical composition of the core. Higher temperature intervals were generally correlated to lower sediment density with higher chironomid concentration and diversity. Higher temperatures were recorded from cal yr AD 1160 to AD 1360, which may correspond to the Medieval Warm Period. Between cal yr AD 1360 and AD 1700, lower temperatures were probably related to a Little Ice Age event. This study presents new information on the timing of known climatic events which will refine our knowledge of the paleoclimate and climatic models of the Foxe Basin region. It also provides a new framework for the evolution of such freshwater ecosystems under the “Anthropocene” and underlines the importance of including sedimentological proxies when interpreting chironomid remains as this combined approach provides an extended overview of the past hydrological and geochemical changes and their impacts on lake biota.     

Gaps in cubic closest packing: from MgO via spinel to the pharmacosiderite crystal structure type

Numerous ordered defect structures are known that are related to the sodium chloride (or MgO) structure type, thus they are basically cubic closest packed (ccp) arrangements with vacancies. For example the NbO type is an MgO type in which one quarter each of the anions and the cations are missing compared to the ccp in such a way that both anions and cations are in square-planar coordination. In spinel, Al₂MgO₄, one half of the octahedrally coordinated cations are missing compared with the MgO type and only one eighth of the tetrahedrally coordinated sites within the ccp are occupied. What these cases have in common is that all these derivatives are rather dense. This is different in pharmacosiderite, K[Fe₄(OH)₄As₃O₁₂]. 6 to 7H₂O, where one half of the anion positions, three quarters of the octahedral sites and five eighth of the tetrahedral sites remain vacant, compared to the spinel type. Pharmacosiderite is a wide open porous structure with zeolitic properties. We are illustrating these relationships using a Bärnighausen symmetry tree and by tables relating the various structure types to each other.