Chemometric analysis of <Superscript>137</Superscript>Cs activity and heavy metals distribution in the Tatras’ soil

The goal of the paper was to determine the activity of ¹³⁷Cs and ⁴⁰K radionuclides as well as heavy metals Zn, Cr, Pb in soil samples taken from the Tatra National Park in the south of Poland. The samples were obtained as cores (10 cm in diameter) from the top 10-cm layer of the soil. Each sample was divided into three subsamples (a, b and c), where a was the subsample closest to the surface and c was the deepest one. Activity of the radionuclides was determined by means of gamma spectrometry, while analysis of heavy metals was performed (after microwave digestion) using atomic absorption spectrometry technique. The highest activity of cesium-137 was detected (5112 ± 120 Bq kg^?1) in the “a” layer of the core with the peak concentration of cesium-137 (14,452 ± 278 Bq m^?2) in the whole soil core. The highest detected concentration of heavy metals was: Zn—52.8 ± 4.4 mg kg^?1, Pb—260.1 ± 9.4 mg kg^?1, Cr—52.8 ± 4.4 mg kg^?1, respectively. Cluster analysis and principal component analysis were used to examine the obtained data. Application of statistical analysis tools allowed specifying the interdependencies between the examined variables.     

The use of selected research methods to describe the pore space of dolomite from copper ore mine,Poland

Basic knowledge of the characteristics of copper-bearing rock such as dolomite is essential to locate those areas of the deposit which have different structural and textural properties. Those regions can be important in terms of the assessment of the possibilities of gas accumulating in them as well as in terms of gasogeodynamic hazard. To better understand those threats, it is necessary to locate, monitor and analyse those areas in detail. This article characterises the structural and textural parameters of dolomite from the Polkowice–Sieroszowice copper mine in Poland. The study involved five samples from various areas of the mine. A number of research methods were selected. Reflected and transmitted light microscopy (MS), computer microtomography (Micro-CT), gas adsorption porosimetry (LPNA), mercury porosimetry (MIP), helium and quasi-fluid pycnometry (Pycno. He, DryFlo). Each of the methods examined a different scope of the pore size, which enabled to achieve a full view of the porous nature of those rocks. We determined their porosity (open, closed, total), surface area as well as mean size and volume of the pores. Also, we studied the character and the pore size distribution from a few nm to a few mm. Comprehensive dolomite properties analyses showed that these rocks are characterised by high structural variability. They have mesopores and macropores but few micropores. The analyses presented in this paper are determined by a large petrographic diversity of the deposits containing dolomite. This article is an example of a comprehensive approach to the rock analysis in copper ore mines.     

Semiannual and annual oscillations of sea level and their impact on asymmetry between El Niño and La Niña episodes

The purpose of this paper is twofold. First, we demonstrate that the asymmetry between El Niño and La Niña events recorded in sea level variation occurs only during extreme episodes of El Niño/Southern Oscillation. Second, we explain that the asymmetry is controlled by certain regular cycles which have time-variable amplitudes. Gridded maps of sea level anomaly that form a spatial-temporal time series (spatial resolution: 1° × 1°, sampling interval: 1 week) spanning the time interval from 14/10/1993 to 18/04/2012 were used. We examined those time series and found that certain regular harmonic signals (periods: 365, 182, 120, 90 and 62 days) are dominant terms of their temporal variability. By subtracting those oscillations from sea level anomaly data, residuals were determined. Using skewness and kurtosis as measures of asymmetry and nonlinearity — after adopting 10-year moving window — we found that the extreme El Niño 1997/1998 has been a dominant driving force of the asymmetry and nonlinearity of El Niño/Southern Oscillation since the end of 1993. In order to detect residual signals that are responsible for the asymmetry, we applied the Fourier Transform Band Pass Filter and found that there are two important oscillations remaining in the residual sea level anomaly data, i.e. the annual and semiannual ones with time-varying amplitudes. We hypothesize that temporarily uneven amplitudes have meaningful impact on the aforementioned asymmetry.     

Lidar observations of volcanic dust over Polish Polar Station at Hornsund after eruptions of Eyjafjallajökull and Grímsvötn

Two significant volcanic eruptions, i.e., Eyjafjallajökull (April–May 2010) and Grímsvötn (May 2011) took place recently in Iceland. Within a few days after eruptions, layers of high aerosol concentration have been observed by multiwavelength lidar of the Polish Polar Station at Hornsund, Svalbard. Measurements of the aerosol’s optical properties indicated a possible presence of volcanic ash transported over the Station. The latter presumption was confirmed by the computed backward trajectories of air masses, showing their paths passing over the location of volcanoes.     

ECHOBASE—A portable geographic fishery research database system

A geographic fishery research database system (GFRDBS), called ECHOBASE, for storing and management of data on pelagic fish resources from acoustic surveys and catch samples, combined with environmental data in a geographic context, has been developed. The system constitutes a portable and inexpensive yet powerful tool for fishery research and environmental monitoring and provides on‐board data processing and mapping capabilities.

Data are acquired from an echosounder, echo signal processor, environmental profiler (CTD probe), and Global Positioning System (GPS) receiver. The electronic digitized maps (based on C‐MAP public format files) provide active on‐screen nautical charts.

The basic GFRDBS platform is a portable PC 486 machine, which is used as an on‐board data acquisition and processing tool running under MS Windows 3.1 operating environment. The system is designed around the Borland's PARADOX package, which provides a relational database for managing acoustic, catch, and environmental data. The ECHOBASE programs were written in Borland C ++ language as a Windows application.     

TraceeElements in Leccinum scabrum mushrooms and topsoils from Kłodzka Dale in Sudety Mountains, Poland

In the current study, we determined concentrations and transfer rates of Ag, Al, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb, P, Rb, Sr and Zn to Brown Birch Scaber Stalks (Leccinum scabrum) mushrooms emerged in the area of Sudety Mountains (Sudetes) in Poland. Fruiting bodies and topsoil samples beneath L. scabrum were collected form the K odzka Dale. The trace elements were determined using validated method and inductively coupled plasma - atomic emission spectroscopy (ICP-AES) for final measurement. Mushrooms contained Ag, Cr, Hg, Co, Ni and Sr at < 1.0 μg/g dry weight; Ba and Pb at ~1.0 μg/g dw; Cd at < 5 μg/g dw; Cu and Mn at > 10 μg/g dw; Al and Ca at ~100 μg/g dw; Fe, Na, Rb and Zn at 100 to 500 μg/g dw, Mg at ~1,000 μg/g dw; P at ~5,000 μg/g dw and K at ~30,000 μg/g dw. Ca, Mn and Ni were nearly equally distributed between stipes and caps; stipes compared to caps were enriched in Ba, Na and Sr, while caps were enriched in Ag, Al, Cd, Co, Cr, Cu, Fe, K, P, Pb, Rb and Zn. The values of bioconcentration factor (BCF) varied highly depending on chemical element and were >1 for Ag, Cd, Cu, K, Mg, Na, P, Rb and Zn, while <1 for Al, Ba, Ca, Co, Cr, Fe, Mn, Ni, Pb and Sr. Topsoil showed elevated content of lead and mean concentration was 99 ± 32 μg/g dw, while cadmium was at 0.41 ± 0.15 and those two highly toxic to human elements occurred in edible caps of L. scabrum at 4.5 ± 2.2 and 2.9 ± 2.0 μg/g dw, respectively.     

Differences in the abiotic parameters of water in coastal lakes in the light of the EU water framework directive: An example of the Polish southern Baltic coast

Coastal lakes have a specific hydrological regime determined by the influence of sea and inland water and the local hydrographic conditions. There are several problems concerning the protection and assessment of water quality of these bodies. The most important features differentiating coastal lakes from other lakes are: high salinity, a wide range of seasonal and short-term water quality changes, and specific aquatic ecosystems adapted to these conditions. These matters have not been sufficiently taken into account in the existing classifications and typologies of lakes in Poland. The problem has not been solved by the establishment of the adequate reference conditions and new guidelines for the classification of water status (which are being prepared according to the Common Strategy for the Implementation of the Water Framework Directive) regarding inland surface waters (rivers and lakes) and marine waters (coastal and transitional). An important issue is to define criteria which would help to distinguish all those hydrographic objects and to establish water quality standards for them.     

Mineral constituents in common chanterelles and soils collected from a high mountain and lowland sites in Poland

This paper reported the results of the determination of Ag, Al, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, P, Pb, Rb, Sr and Zn in Common Chanterelles (Cantharellus cibarius) Fr. and surface soil layer (0-10 cm) underneath the fruiting bodies. Mushrooms and soils were collected from a lowland site in the Hel Peninsula (Baltic Sea coast) and a high mountain site in the Tatra Mountains. The trace elements were determined using validated method and inductively coupled plasma - atomic emission spectroscopy (ICP-AES). Common Chanterelles that emerged at sites poor in mineral nutrients podzols of the Hel Peninsula forests efficiently bioconcentrated several essential trace elements (K, P, Co, Cu, Mn, Na, Zn), while the abundance of those elements in carpophores was around half less compared to specimens from Zakopane region and which emerged in soils much richer in minerals. Common Chanterelles collected at two spatially distant background areas in Poland were only weakly contaminated with metals such as Ag, Cd, Hg and Pb. The maximum tolerable Cd and Pb contents of certain cultivated mushrooms are regulated in the European Union by law and these hazardous metals in C. cibarius were far below tolerance limits set.     

Angular Distributions of Discrete Mesoscale Mapping Functions

The paper presents the results of analyses of numerical experiments concerning GPS signal propagation delays in the atmosphere and the discrete mapping functions defined on their basis. The delays were determined using data from the mesoscale non-hydrostatic weather model operated in the Centre of Applied Geomatics, Military University of Technology. A special attention was paid to investigating angular characteristics of GPS slant delays for low angles of elevation. The investigation proved that the temporal and spatial variability of the slant delays depends to a large extent on current weather conditions.