Removal of bisphenol A (BPA) from biologically treated wastewater by microfiltration and nanofiltration

Bisphenol A (BPA) is an endocrine disruptor that is difficult to completely remove from wastewater by conventional biological methods. Increased post-treatment BPA removal with ceramic membranes is worth investigating because of these membranes’ mechanical and chemical stability and lifespan. To determine the effectiveness of ceramic membranes for post-treatment of biologically treated BPA-contaminated wastewater, microfiltration (MF) and nanofiltration (NF) were conducted. Both processes removed BPA completely at an initial BPA concentration of 0.3 ± 0.14 mg/L. Increased concentration of 0.7 ± 0.29 mg/L decreased BPA removal. MF removed at least 24 % of BPA, presumably because BPA was adsorbed on particulate matter, which was retained by the membrane, or adsorbed on its surface. NF removed up to thrice more BPA. MF and NF completely removed suspended solids and 40–60 % COD. Filtration capacity decreased with time due to fouling but did not depend on initial BPA concentration. BPA concentrations in municipal wastewater are typically lower than the lowest concentration tested, where MF completely removed BPA. Hence, MF ceramic membranes appear a promising solution for post-treatment of BPA-containing wastewater. MF can be used at a much lower transmembrane pressure than NF, requiring less energy to pump wastewater through the membrane, thus reducing costs.     

The thermal decomposition studies of three Polish bituminous coking coals and their blends

The objective of this work was to investigate the thermal decomposition of various bituminous coal blends. Three Polish coals of varying rank (82.7, 86.2 and 88.7 wt.% carbon content) and caking ability (weak, moderate and strong) were collected from the Krupiński, Szczygłowice and Zofiówka mines, respectively. These coals were used to prepare binary and ternary blends. Thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA) were used. The weight loss and heat flow during pyrolysis, and storage/loss elastic modulus measured as a function of increasing temperature were related to the caking ability of coals. Parameters determined with the TGA and the DSC methods in the binary and ternary blends were correlated with the proportion of strongly-caking-coal concentration in the blend. The weight loss of coal blends was found to be additive parameter. The DSC thermograms of binary blends were found to be different from those of the ternary blends, which suggests a different course for this blend pyrolysis.     

Multiple drivers of Holocene lake level changes at a lowland lake in northeastern Germany

Many German lakes experienced significant water level declines in recent decades that are not fully understood due to the short observation period. At a typical northeastern German groundwater‐fed lake with a complex basin morphology, an acoustic sub‐bottom profile was analysed together with a transect of five sediment cores, which were correlated using multiple proxies (sediment facies, μ‐XRF, macrofossils, subfossil Cladocera). Shifts in the boundary between sand and mud deposition were controlled by lake level changes, and hence, allowed the quantification of an absolute lake level amplitude of ~8 m for the Holocene. This clearly exceeded observed modern fluctuations of 1.3 m (AD 1973–2010). Past lake level changes were traced continuously using the calcium‐record. During high lake levels, massive organic muds were deposited in the deepest lake basin, whereas lower lake levels isolated the sub‐basins and allowed carbonate deposition. During the beginning of the Holocene (>9700 cal. a BP), lake levels were high, probably due to final melting of permafrost and dead‐ice remains. The establishment of water‐use intensive Pinus forests caused generally low (3–4 m below modern) but fluctuating lake levels (9700–6400 cal. a BP). Afterwards, the lake showed an increasing trend and reached a short‐term highstand at c. 5000 cal. a BP (4 m above modern). At the transition towards a cooler and wetter late Holocene, forests dominated by Quercus and Fagus and initial human impact probably contributed more positively to groundwater recharge. Lake levels remained high between 3800 and 800 cal. a BP, but the lake system was not sensitive enough to record short‐term fluctuations during this period. Lake level changes were recorded again when humans profoundly affected the drainage system, land cover and lake trophy. Hence, local Holocene water level changes reflect feedbacks between catchment and vegetation characteristics and human impact superimposed by climate change at multiple temporal scales.     

Secondary Ion Mass Spectrometry Bias on Isotope Ratios in Dolomite–Ankerite,Part I: δ18O Matrix Effects

We document the development of a suite of carbonate mineral reference materials for calibrating SIMS determinations of δ¹⁸O in samples with compositions along the dolomite–ankerite solid solution series [CaMg(CO₃)₂–CaFe(CO₃)₂]. Under routine operating conditions for the analysis of carbonates for δ¹⁸O with a CAMECA IMS 1280 instrument (at WiscSIMS, University of Wisconsin‐Madison), the magnitude of instrumental bias along the dolomite–ankerite series decreased exponentially by ~ 10‰ with increasing Fe content in the dolomite structure, but appeared insensitive to minor Mn substitution [< 2.6 mol% Mn/(Ca+Mg+Fe+Mn)]. The compositional dependence of bias (i.e., the sample matrix effect) was calibrated using the Hill equation, which relates bias to the Fe# of dolomite–ankerite [i.e., molar Fe/(Mg+Fe)] for thirteen reference materials (Fe# = 0.004–0.789); for calibrations employing either 10 or 3 μm diameter spot size measurements, this yielded residual values ≤ 0.3–0.4‰ relative to CRM NBS 19 for most reference materials in the suite. Analytical precision was ± 0.3‰ (2s, standard deviations) for 10‐μm spots and ± 0.7‰ (2s) for 3‐μm spots, based on the spot‐to‐spot repeatability of a drift monitor material that ‘bracketed’ each set of ten sample‐spot analyses. Analytical uncertainty for individual sample analyses was approximated by a combination of precision and calibration residual values (propagated in quadrature), suggesting an uncertainty of ± 0.5‰ (2s) for 10‐μm spots and ± 1‰ (2s) for 3‐μm spots.     

From back-arc to rifted margin: Geochemical and Nd isotopic records in Neoproterozoic?-Cambrian metabasites of the Bystrzyckie and Orlickie Mountains (Sudetes,SW Poland)

Metamorphosed during the Variscan orogeny, sediments of the ca. 560 Ma M?ynowiec Formation and ca. 530 Ma Stronie Formation in the Bystrzyckie and Orlickie Mountains (Central Sudetes, Poland) contain metabasites with a range of basaltic compositions. Immobile trace element and Nd isotope features allow distinction of dominant, either E-MORB-like (Group 1: Zr/Nb 9–20, εNd₅₃₀ +2.6 to +6.7) or mildly enriched N-MORB-like tholeiites (Group 2: Zr/Nb 21–27, εNd₅₃₀ +0.2 to +6.7), and scarce but genetically important OIB-like alkaline (Group 3: Zr/Nb 5, εNd₅₃₀ +2.2) or depleted tholeiitic rocks (Group 4: Zr/Nb 67, εNd₅₃₀ +7.9). Neither the radiogenic age nor age relationships between these four groups are known. However, field evidence suggests that the metabasites are younger than the M?ynowiec Formation and that their emplacement must have been coeval with the accumulation of the Stronie Formation sediments. The OIB affinity of Group 3 is interpreted to reflect an enriched mantle (EM)-type asthenopheric source whilst the groups of tholeiitic rocks indicate involvement of depleted (locally slightly residual) MORB-type mantle (DMM). Several geochemical signatures, the decoupling between Nd isotope and trace element characteristics, and melting models indicate variable enrichment of the DMM-like source, here ascribed to asthenosphere-derived OIB-like melts (Group 1 and 2) and a contribution from a supra-subduction zone (Group 2 and 4). Based on contrasting back-arc basin (BAB)- and within-plate-like affinities of the metabasites, and on petrogenetic constraints from the spatially related infill of the Stronie Formation rift basin, the studied magmatic episode is suggested be related to cessation of the supra-subduction zone activity, presumably induced by ridge-trench collision. This event might have led to slab break-off, the development of a transform plate boundary, opening of a slab window and upward migration of sub-slab enriched asthenosphere. Decompression melting of the upwelling asthenosphere could then have produced OIB-like melts which segregated and infiltrated into the mantle of the former subduction zone, with randomly distributed slab-derived components. In an extensional regime, magmas generated at shallow levels from heterogeneous mantle regions were emplaced within sedimentary rocks of the overlying rift basin. The vestiges of subduction-related processes and within-plate style of mantle enrichment suggest that the metabasites could be related to final stages of the Cadomian orogeny and incipient Early Palaeozoic rifting of Gondwana that heralded the opening of the Rheic Ocean.     

Assessment of heavy metal contamination levels of street dust in the city of Lublin,E Poland

Heavy metals are constantly emitted into the environment and pose a major threat to human health, particularly in urban areas. The threat is linked to the presence of Cd, Cr, Cu, Ni, Pb, and Zn in street dust, which consists of mineral and organic particles originating from the soil, industrial emitters, motor vehicles, and fuel consumption. The study objective was to determine the level of street dust contamination with trace metals in Lublin and to indicate their potential sources of origin. The analyses were carried out with an energy-dispersive X-ray fluorescence spectrometer. The sampling sites (49) were located within the city streets characterised by varying intensity of motor traffic. The following mean content values and their variation (SD) were determined: Cd: 5.1?±?1.7 mg kg^?1, Cr: 86.4?±?23.3 mg kg^?1, Cu: 81.6?±?69.2 mg kg^?1, Ni: 16.5?±?3.9 mg kg^?1, Pb: 44.1?±?16.4 mg kg^?1, and Zn: 241.1?±?94.6 mg kg^?1. The level of pollution was assessed with several widely used geochemical indices (geoaccumulation index, enrichment factor, pollution index, index of ecological risk, and potential ecological risk index). For most of the indices, the mean (median) values are arranged in the following manner: Zn?>?Cu(or Cd)?>?Pb?>?Ni?>?Cr. In general, street dust in Lublin does not show pollution with Cr, Ni, and Pb. I_geo and EF indices show moderate levels for Cu, Cd, and Zn; their presence in street dust is linked with anthropogenic factors (motor traffic). A significant threat is posed by Cd, and more than half of the samples show considerable pollution with cadmium (median for the index of ecological risk: 151). The spatial pattern of indices and the results of statistical analyses (CA, PCA) indicate three groups of elements: (1) Cr and Ni: natural origin; (2) Pb: mixed origin; and (3) Cd, Cu, and Zn: anthropogenic origin (mainly motor vehicle traffic). Higher content values for metals of anthropogenic origin in street dust indicate that it is a source of pollution of soil and air in the city.     

Modelling the pre-failure instabilities of sand

A simple incremental model describing the pre-failure behaviour of granular soils is presented. The model describes both the dry/fully drained and undrained response. It takes into account an initial anisotropy of soil and an initial state defined as either contractive or dilative. A physically sound definition of loading/unloading is assumed, which differs from elasto-plastic approaches. The model is based on extensive empirical data and gives predictions conformable with experimental results. It also describes pre-failure instabilities of granular soils, both dry/fully drained and undrained. The Hill’s criterion was used to examine stability. It was shown that this condition can be formulated either in terms of the effective stresses or by the total stresses. In the extreme cases of either dry/fully drained or undrained conditions, these alternative formulations are equivalent. This is not so in the case of partial drainage of pore water and associated volumetric deformations as well as pore pressure changes. The model describes the pre-failure instabilities well, and additionally allows for analytical derivation of the instability line. It was shown that the second order work, appearing in the Hill’s condition, is equivalent to the entropy source.     

On latitudinal variations of temporal characteristics of the VLF chorus in the upper ionosphere

Summary The elements of the VLF chorus, observed simultaneously at a ground station and satellite in polar orbit, can be used to determine the differences in the arrival times of waves and their dependence on latitude. Mostly does not change practically over a wide range of latitudes, however, in some cases it may increase appreciably at low value of L. Model computations of the propagation time, based on the assumption that the source of the chorus is located close to the equatorial plane, have indicated the possibility of explaining the increase in at low latitudes by the presence of a step in the electron density profile close to this plane.

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