Uptake of Indosol Dark-blue GL dye from aqueous solution by water hyacinth roots powder: adsorption and desorption study

Adsorption characteristics of water hyacinth roots powder for the removal of Indosol Dark-blue GL dye were investigated in batch mode. Operating variables, such as initial solution pH, presence of detergent, adsorbent dosage, initial concentration and contact time, were studied. The results showed that the adsorption of dye increased with increasing the initial concentration and contact time. The adsorption is highly pH dependent and adsorption capacity increased with decrease in pH. Kinetic study revealed that the uptake of Indosol Dark-blue GL was very rapid within the first 15 min and equilibrium time was independent of initial concentration. Batch equilibrium experiments were carried out at different pH and found that equilibrium data fitted well to Langmuir isotherm model. The maximum sorption capacity of the adsorbent was found as 86 mg g^?1 at pH 3 which reduced to 64 mg g^?1 at pH 5. The presence of detergent reduced the sorption capacity of the adsorbent significantly. Using equilibrium and kinetic data, the forward and backward rate constants were determined from the unified approach model. Desorption study revealed that the dye can be recovered by swing the pH from low to high.     

Ion-acoustic solitons in pair-ion plasma with non-thermal electrons

Properties of fully nonlinear ion-acoustic solitary waves in an unmagnetized and collisionless pair-ion (PI) plasma containing superthermal electrons obeying Cairns distribution have been analyzed. A linear biquadratic dispersion relation has been derived, which yields the fast (supersonic) and slow (subsonic) modes in a pair-ion-electron plasma with nonthermal electrons. For nonlinear analysis, Korteweg-de Vries equation is obtained using the reductive perturbation technique. It is found that in case of slow mode, both electrostatic hump and dip type structures are formed depending on the temperature difference between positively and negatively charged ions, whereas, only dip type solitary structures have been observed for fast mode. The present work may be employed to explore and to understand the formation of solitary structures in the space (especially, the Earth’s ionosphere where two distinct pair ion species (H ^±) are present) and laboratory produced pair-ion plasmas with nonthermal electrons.     

Relative Sea Level Changes in Maldives and Vulnerability of Land Due to Abnormal Coastal Inundation

Oceanic Islands in the Pacific and Indian Oceans have extremely small land areas, usually less than 500 km2, with maximum height about 4 m above sea level. The Republic of Maldives is an independent island nation in the Indian Ocean south of Sri Lanka which stretches vertically in the Indian Ocean from 07° 06'N - 0° 42'S. The land area of this island country is about 300 km2, and none of Maldives' 1190 islands has an elevation more than 3 m above sea level. In fact the Maldives has the distinction of being the flattest country on earth, making it extremely vulnerable to the effects of global warming. Of the south Asian countries, the Maldives is the most vulnerable nation, facing severe consequences as a result of global warming and sea level rise (SLR). Because of their obvious vulnerability to SLR, the Government of Maldives is very much concerned about climate change. As global warming and the related SLR is an important integrated environmental issue, the need of the hour is to monitor and assess these changes. The present article deals mainly with the analysis of the tidal and Sea Surface Temperature (SST) data observed at Male and Gan stations along the Maldives coast in the northern and southern hemispheres, respectively. The objective of the analysis is to study the trends of these parameters. Trend analysis is also performed on the corresponding air temperature data of both stations. The results show that Maldives coastal sea level is rising in the same way (rising trend) as the global sea level. The mean tidal level at Male has shown an increasing trend of about 4.1 mm/year.Similarly at Gan, near the equator,it has registered a positive trend of about 3.9 mm/year.Sea level variations are the manifestations of various changes that are taking place in the Ocean-Atmosphere system. Therefore, the variations in SST and air temperature are intimately linked to sea level rise. It is found that SST and air temperature have also registered an increasing trend at both stations. The evidence of rising trends suggest that careful future monitoring of these parameters is very much required. Tropical cyclones normally do not affect the Maldives coast. However, due to its isolated location, the long fetches in association with swells generated by storms, that originated in the far south have resulted in flooding. Thus the rising rate of sea level with high waves and flat topography have increased the risk of flooding and increased the rate of erosion and alteration of beaches.     

湖泊碎屑岩沙坝成因机制及构型表征研究进展*

湖泊碎屑岩沙坝因波浪和沿岸流的反复冲刷,成熟度较高,显示出巨大的油气勘探潜力,已成为隐蔽油气藏勘探的重点。作者在大量文献调研的基础上,总结了近年来前人在滩坝定义、沉积特征、主控因素、成因机制及内部构型研究中的重要进展,在此基础上提出了沙坝演化阶段及沉积构型的新认识。结果表明,沙坝完整的演化历程主要包括4个阶段,分别是弱波浪作用阶段、动荡水流—冲洗回流阶段、风成阶段及沼泽化阶段。影响沙坝发育的控制因素多样,其中物源和风场是沙坝发育的根本因素,两者分别影响了沙坝发育的物质来源和能量供给;而风场所决定的水动力是影响沙坝储集体发育的最直接因素;构造运动和层序演化则控制沙坝的分布位置及保存程度;各因素综合作用决定了坝的形态、发育规模及保存状况。依据前人构型理论,将沙坝构型按照正序方案依次划分为6级,对构型表征方法和沙坝3~5级构型定量表征进行了初步探索,以期为滩坝砂体勘探开发提供理论和实践支持。     

Mineralogical and geochemical study of bentonite deposits of Garhi Chandan area,District Nowshera,Khyber Pakhtunkhwa,Pakistan

The Pliocene-Pleistocene Ghari Chandan Formation consists of lacustrine-fluvio-deltaic deposits exposed in the Attock-Cherat Range. Three beds of bentonite deposits occur in the upper part of the formation. An average thickness of each layer ranges from 0.4 to 1 m with a total strike length of ~5 Km. Montmorillonite and saponite clay minerals with admixtures of quartz, feldspar, muscovite, biotite, and hornblende were identified in these samples. Compositionally these beds are similar and comprised of dioctahedral smectite. The differential thermal analyses of bentonite reveals high thermal stability of the deposits. Detailed mineralogical and geochemical investigations suggest that the Garhi Chandan deposit is a mixture of calcic and sodic bentonite derived from andesitic and trachyandesitic source rock. Heavy metal concentration reduces the overall adsorbing capacity of the deposit.     

Potentiality of open burnt clay as an adsorbent for the removal of Congo red from aqueous solution

Open burnt clay was studied as a potential adsorbent for the adsorption of Congo red (a reactive dye) from aqueous solution. The effect of contact time, pH, adsorbent dosage and temperature were studied. It was observed that the amount of Congo red retained increase with decreasing pH and increasing initial concentration. Removal percentage at pH 2 and 3 are almost same. The adsorption capacity of regenerated burnt clay was showed more than 98 % recovery of the adsorption efficiency of initial virgin adsorbent. The equilibrium data were described well by both Langmuir and Freundlich isotherm model. The adsorption capacity of some natural adsorbents, namely rice husk, wood charcoal, tea waste etc. were also investigated and compared with that of open burnt clay.