Characteristics of lipid tracer compounds transported to the Arabian Gulf by runoff from rivers and atmospheric dust transport

River runoff and atmospheric fallout (dust and air particulate matter) are major input sources of natural and anthropogenic terrestrial organic and inorganic components to the Arabian seas. In this study, we report on the various lipid tracer compounds that might be transported to the Arabian Gulf by rivers, dust, and air particulate matter. These are based on geochemical analysis of sediment, dust, and particulate samples collected from Iraq, Kuwait, and Saudi Arabia. The samples were extracted with a dichloromethane/methanol mixture and analyzed by gas chromatography-mass spectrometry. The extractable organic compounds (lipids) in the samples include n-alkanes, n-alkanoic acids, n-alkanols, methyl n-alkanoates, steroids, triterpenoids, carbohydrates, and petroleum hydrocarbons. The steroids and triterpenoids were major components in river and wetland samples. The major sources of these lipids were from natural vegetation, microbial (plankton and bacteria) residues in the sediments, sand, and soils, with some contribution from anthropogenic sources. Accordingly, these sources could be major inputs to the Arabian seas besides the autochthonous marine products. Future studies of the organic and inorganic biogeochemistry on river, dust, and coastal areas are needed to characterize the various regional sources, transformation, and diagenetic processes of the organic matter en route to the marine environment.     

From outcrop and petrographic studies to basin-scale fluid flow modelling: The use of the Albanian natural laboratory for carbonate reservoir characterisation

The Albanian fold-and-thrust belt and the Peri-Adriatic Depression are well documented by means of seismic reflection profiles, GPS reference points, potential data, wells and outcrops. The continuous Oligocene to Plio-Quaternary sedimentary records help to constrain both the burial history of Mesozoic carbonate reservoirs, the timing of their deformation, and the coupled fluid flow and diagenetic scenarios.Since the mid-90s, the Albanian foothills were used as a natural laboratory to develop a new integrated methodology and work flow for the study of sub-thrust reservoir evolution, and to validate on real case studies the use of basin modelling tools as well as the application of new analytical methods for the study petroleum systems in tectonically complex areas.The integration of the interactions between petrographic and microtectonic studies, kinematic, thermal and fluid flow basin modelling, is described in detail. The fracturing of the reservoir intervals has a pre-folding origin in the Albanides and relates to the regional flexuring in the foreland. The first recorded cement has a meteoric origin, implying downward migration and the development of an earlier forebulge in the Ionian Basin. This fluid, which precipitates at a maximum depth of 1.5 km, is highly enriched in strontium, attesting for important fluid–rock interaction with the Triassic evaporites, located in diapirs. From this stage, the horizontal tectonic compression increases and the majority of the fluid migrated under high pressure, characterised by brecciated and crack-seal vein. The tectonic burial increased due to the overthrusting, that is pointed out by the increase of the precipitation temperature of the cements. Afterwards, up- or downward migration of SO₄²⁻, Ba²⁺ and Mg²⁺-rich fluids, which migrated probably along the décollement level, allows a precipitation in thermal disequilibrium. This period corresponds to the onset of the thrusting in the Ionian Zone. The last stage characterised the uplift of the Berati belt, developing a selective karstification due likely to the circulation of meteoric fluid.The main results of the fluid flow modelling show that the Upper Cretaceous–Paleocene carbonate reservoirs in the Ionian zone have been charged from the Tortonian onward, and that meteoric fluid migration should have intensely biodegraded the hydrocarbon in place. Concerning the migration paths, it has been demonstrated that the thrusts act principally as flow barriers in Albania, mainly due the occurrence of evaporites (non-permeable), except in the foreland, where they do not occur.     

Calculation of Well Index for Nonconventional Wells on Arbitrary Grids

Wells are seldom modeled explicitly in large scale finite difference reservoir simulations. Instead, the well is coupled to the reservoir through the use of a well index, which relates wellbore flow rate and pressure to grid block quantities. The use of an accurate well index is essential for the detailed modeling of nonconventional wells; i.e., wells with an arbitrary trajectory or multiple branches. The determination of a well index for such problems is complicated, particularly when the simulation grid is irregular or unstructured. In this work, a general framework for the calculation of accurate well indices for general nonconventional wells on arbitrary grids is presented and applied. The method entails the use of an accurate semianalytical well model based on Green's functions as a reference single phase flow solution. This result is coupled with a finite difference calculation to provide an accurate well index for each grid block containing a well segment. The method is demonstrated on a number of homogeneous example cases involving deviated, horizontal and multilateral wells oriented skew to the grid. Both Cartesian and globally unstructured multiblock grids are considered. In all these cases, the method is shown to provide results that are considerably more accurate compared to results using standard procedures. The method is also applied to heterogeneous problems involving horizontal wells, where it is shown to be capable of approximating the effects of subgrid heterogeneity in coarse finite difference models.     

Influence of saturation on rainfall generated landslides in shale along Murree-Kohala road,Pakistan

On August 10, 2010 a series of landslides of more than 90,000 m³ occurred along the Muree-Kohala road in the northern area of Pakistan. A study was undertaken to evaluate the likely impacts of percent saturation and bulk density on mobilized shear strength along the basal rupture surface of the landslide. A series of unconfined compression test and unconsolidated undrained triaxial tests were performed on remolded samples of different densities with varied percentages of saturation. The results of these tests suggest that soil cohesion and friction decreases with increasing saturation. The tests also showed that the shear strength parameters tend to increase with increasing dry density; however, all the samples exhibited a noticeable loss of shear strength with increasing degree of saturation, independent of soil density.Limit equilibrium slope stability analyses were performed along the most probable failure planes, based on shear strength parameters corresponding to degrees of saturation, which varied between 30% to about 100%. This resulted in drop of factor of safety from FS = 1.64 down to 0.51 as the degree of saturation approaches unity.These results suggest that the causative factor in triggering the landslide along Murree-Kohala was the partial saturation of the zone that developed the basal rupture plane. As rain infiltrated the slope, the bulk unit weight of the soil increased, while the shear strength along the developing plane of rupture decreased sufficiently to concentrate shear strain when the material became more than 60% saturation (FS < 1.0).     

Determination of possible responses of Radon-222, magnetic effects,and total electron content to earthquakes on the North Anatolian Fault Zone,Turkiye: an ARIMA and Monte Carlo Simulation

Natural Hazards - Around the world, earthquake forecasting studies have become very important nowadays due to the increase in number of fatal earthquakes annually. This paper proposes to achieve a...     

Experimental evaluation of the anisotropic critical state theory for sand using 3D fabric evolution data of triaxial experiments

Acta Geotechnica - The critical state theory has been widely implemented in many models to predict the constitutive behavior of clayey soil. However, the notion of a unique critical state locus for...     

Mesoscale and Nutrient Conditions Associated with the Massive 2008 Cochlodinium polykrikoides Bloom in the Sea of Oman/Arabian Gulf

Cochlodinium polykrikoides formed large blooms in the coastal waters of Oman from October 2008 through mid-January 2009, and satellite images from Aqua-MODIS and region-wide reports suggest that this bloom was found throughout the Arabian Gulf and Sea of Oman for more than 10 months. The unusual occurrence of this species appears to have supplanted the more regularly occurring bloom species, Noctiluca scintillans, in 2008–2009. For the first 2 weeks of the coastal Omani bloom, C. polykrikoides abundance was near monospecific proportions, with cell densities ranging from 4.6?×?10³ to 9?×?10⁶ cells L^?1 and very high levels of chlorophyll a (78.0 μg L^?1) were also recorded. The regional progression of the bloom likely began with stronger than normal upwelling along the Iranian and northern Omani coasts during the southwest monsoon in late summer, followed by discharge of unusually warm coastal plume water along the coast of Oman with the reversal of monsoonal winds in late October. The occurrence and persistence of high densities of C. polykrikoides in Oman coastal water were also significantly influenced by an elevated nutrient load and warmer than normal temperatures. Concentrations of nutrients, especially NH₄ ⁺, urea, PO₄ ^3?, and organic nitrogen and phosphorus, were manyfold higher than observed in the year prior or since. These findings suggest that mesoscale features were important in bloom dynamics more regionally, but locally the bloom was sustained by nutrient enrichment supplemented by its mixotrophic capabilities.     

Cadmium (Cd) concentration in wheat (<Emphasis Type="Italic">Triticum aestivum</Emphasis>) grown in Cd-spiked soil varies with the doses and biochar feedstock

Biochar is considered a promising amendment for the reduction of metal concentration in plants; however, the effects of biochar in terms of dose and feedstock on metal uptake by plants remain widely unclear. In the current study, three individual biochars were prepared at 450 °C from different feedstocks (wheat straw, sukh chain (Pongamia pinnata), and cotton sticks). The main aim was to evaluate their ability to remediate cadmium (Cd)-spiked soil in terms of growth response and Cd uptake by wheat (Triticum aestivum) tissues. Biochars were separately applied at 0, 1, and 2% (w/w) in Cd-spiked soil and wheat was grown until maturity in pots and then morphological and physiological parameters and Cd concentrations in grains, roots, and shoots were determined. The post-harvest soil was analyzed for extractable Cd concentrations. Plants grown in Cd-spiked soil treated with biochars had higher seed germination, lengths of roots, shoots, and spikes, grains per spike and leaf relative water contents, chlorophyll contents, and dry weight of roots, shoots, and grains as compared to the untreated control. Biochar treatments significantly decreased the Cd concentrations in shoots, roots, and grains as well as total Cd uptake by grains. Soil extractable Cd concentrations were significantly decreased with biochar treatments. The application of 2.0% wheat straw biochar was the most efficient treatment in increasing grain yield and decreasing Cd in grains as well as soil extractable Cd than the other two biochars and doses applied.     

Seismic Hazard Assessment in the Tihamat Asir Region, Southwestern Saudi Arabia

The occurrence of earthquakes, faulting of Pleistocene sediments, uplifting of Pleistocene coral reefs, recent incised wadis and lava effusions in addition to hot springs all clearly indicate that southeastern Saudi Arabia is tectonically active. This paper reviews the tectonic features of southwestern Saudi Arabia and provides new approaches and maps for the interpretation of old and recent earthquake data for improved assessment of the regional tectonics. A regionalized variable approach is used to develop earthquake groundmotion hazard maps for the region, based on geostatistical methods using the kriging technique. This hazard must be considered in any design/construction of engineering structures in the region. The application of kriging for estimating the ground shaking in the study region succeeded clearly in accomplishing its ultimate aim where the generated groundmotions are well correlated with the instrumental magnitude and historical intensity of any earthquake occurrence in the study region.     

The Gulf co-operation Council (GCC): Industrial co-operation in “A Gulf of Difference”

The current attempts by the Gulf Co-operation Council (GCC) countries to co-ordinate their industrial effort is hampered by the very structure of their economies, their varying fortunes, external trading and business dealings and internal programmes of socio-economic development. Unlike the common belief that the Arab Gulf is a homogeneous region, heterogeneity has been traced within the various socio-economic aspects. A telling case in point is the cement industry. It is packed with much of the contradictions of attempted co-operation and yet gives some hope for any future concerted industrial integration effort.