Carbon and hydrogen isotopic evidence for the origin of combustible gases in water-supply wells in north-central Pennsylvania

The origin of the combustible gases in groundwater from glacial-outwash and fractured-bedrock aquifers was investigated in northern Tioga County, Pennsylvania. Thermogenic methane (CH₄) and ethane (C₂H₆) and microbial CH₄ were found. Microbial CH₄ is from natural in situ processes in the shale bedrock and occurs chiefly in the bedrock aquifer. The δ¹³C values of CH₄ and C₂H₆ for the majority of thermogenic gases from water wells either matched or were between values for the samples of non-native storage-field gas from injection wells and the samples of gas from storage-field observation wells. Traces of C₂H₆ with microbial CH₄ and a range of C and H isotopic compositions of CH₄ indicate gases of different origins are mixing in sub-surface pathways; gas mixtures are present in groundwater. Pathways for gas migration and a specific source of the gases were not identified. Processes responsible for the presence of microbial gases in groundwater could be elucidated with further geochemical study.     

A model of household preparedness for earthquakes: how individuals make meaning of earthquake information and how this influences preparedness

One way to reduce the risk from earthquakes is for individuals to undertake preparations for earthquakes at home. Common preparation measures include gathering together survival items, undertaking mitigation actions, developing a household emergency plan, gaining survival skills or participating in wider social preparedness actions. While current earthquake education programmes advocate that people undertake a variety of these activities, actual household preparedness remains at modest levels. Effective earthquake education is inhibited by an incomplete understanding of how the preparedness process works. Previous research has focused on understanding the influence individual cognitive processes have on the earthquake preparedness process but has been limited in identifying other influences posed by the wider social contextual environment. This project used a symbolic interactionism perspective to explore the earthquake preparedness process through a series of qualitative interviews with householders in three New Zealand urban locations. It investigated earthquake information that individuals are exposed to, how people make meaning of this information and how this relates to undertaking actual preparedness measures. During the study, the relative influence of cognitive, emotive and societal factors on the preparedness process was explored and the interactions between these identified. A model of the preparedness process based on the interviews was developed and is presented in this paper.     

The role of ejecta in the small crater populations on the mid-sized saturnian satellites

We find evidence, by both observation and analysis, that primary crater ejecta play an important role in the small crater (less than a few km) populations on the saturnian satellites, and more broadly, on cratered surfaces throughout the Solar System. We measure crater populations in Cassini images of Enceladus, Rhea, and Mimas, focusing on image data with scales less than 500 m/pixel. We use recent updates to crater scaling laws and their constants (Housen, K.R., Holsapple, K.A. [2011]. Icarus 211, 856–875) to estimate the amount of mass ejected in three different velocity ranges: (i) greater than escape velocity, (ii) less than escape velocity and faster than the minimum velocity required to make a secondary crater (v_min), and (iii) velocities less than v_min. Although the vast majority of mass on each satellite is ejected at speeds less than v_min, our calculations demonstrate that the differences in mass available in the other two categories should lead to observable differences in the small crater populations; the predictions are borne out by the measurements we have made to date. In particular, Rhea, Tethys, and Dione have sufficient surface gravities to retain ejecta moving fast enough to make secondary crater populations. The smaller satellites, such as Enceladus but especially Mimas, are expected to have little or no traditional secondary populations because their escape velocities are near the threshold velocity necessary to make a secondary crater. Our work clarifies why the Galilean satellites have extensive secondary crater populations relative to the saturnian satellites. The presence, extent, and sizes of sesquinary craters (craters formed by ejecta that escape into temporary orbits around Saturn before re-impacting the surface, see Dobrovolskis, A.R., Lissauer, J.J. [2004]. Icarus 169, 462–473; Alvarellos, J.L., Zahnle, K.J., Dobrovolskis, A.R., Hamill, P. [2005]. Icarus 178, 104–123; Zahnle, K., Alvarellos, J.L., Dobrovolskis, A.R., Hamill, P. [2008]. Icarus 194, 660–674) is not yet well understood. Finally, our work provides further evidence for a “shallow” size–frequency distribution (slope index of ～2 for a differential power-law) for comets a few kilometers diameter and smaller.     

Quantification of middle and lower cloud variability and mesoscale dynamics from Venus Express/VIRTIS observations at 1.74 μm

We present an analysis of VIRTIS-M-IR observations of 1.74 μm emission from the nightside of Venus. The 1.74 μm window in the near infrared spectrum of Venus is an ideal proxy for investigating the evolution of middle and lower cloud deck opacity of Venus because it exhibits good signal to noise due to its brightness, good contrast between bright and dark regions, and few additional sources of extinction beside the clouds themselves. We have analyzed the data from the first 407 orbits (equivalent to 407 Earth days) of the Venus Express mission to determine the magnitude of variability in the 1.74 μm radiance. We have also performed an analysis of the evolution of individual features over a span of roughly 5–6 h on two successive orbits of Venus Express. We find that the overall 1.74 μm brightness of Venus has been increasing through the first 407 days of the mission, indicating a gradual diminishing of the cloud coverage and/or thickness, and that the lower latitudes exhibited more variability and more brightening than higher latitudes. We find that individual features evolve with a time scale of about 30 h, consistent with our previous analysis. Analysis of the evolution and motion of the clouds can be used to estimate the mesoscale dynamics within the clouds of Venus. We find that advection alone cannot explain the observed evolution of the features. The measured vorticity and divergence in the vicinity of the features are consistent with evolution under the influence of significant vertical motions likely driven by a radiative dynamical feedback. We measure a zonal wind speed of around 65 m/s, and a meridional wind speed around 2.5 m/s by tracking the motion of the central region of the features. But we also find that the measured wind speeds depend strongly on the points chosen for the wind speed analysis.     

Rethinking the nature of urban environmental politics: Security, subjectivity, and the non-human

The growing field of urban political ecology (UPE) has greatly advanced understandings of the socio-ecological transformations through which urban economies and environments are produced. However, this field has thus far failed to fully consider subjective (and subject-forming) dimensions of urban environmental struggle. I argue that this can be overcome through bringing urban political ecology into conversation with both post-structural political ecology and critical geopolitics. Bridging these literatures focuses attention on practices of socio-ecological exclusion and attachment through which environmental subjectivities are formed. This argument is drawn out through a case study of the politics of local economic development and conservation within the watershed of the Big Darby Creek near Columbus, Ohio. This struggle was driven by a preservationist movement that coalesced around a shared understanding of socio-ecological hybridity as a source of metaphysical insecurity. Hybridity appears here as a site of political and ethical struggle over social and ecological exclusions produced in the pursuit of security. This case study demonstrates a paradox of environmental politics: the non-human is at once a site of constituent possibilities for identity and subjectivity as well as forces which seek to foreclose this radical openness. Recognizing the paradoxical nature of environmental struggle allows for a more complex and nuanced account of the multifarious forces that shape the formation of environmental subjectivities.     

Vegetational response to human colonisation of the coastal and volcanic environments of Ketilsstaðir, southern Iceland

Tephra-dated, high-resolution pollen profiles from Ketilsstaðir, southern Iceland, indicate a largely unwooded pre-settlement environment, a probable consequence of the exposed coastal location. The degree of change associated with the Norse landnám is more limited than in many Icelandic pollen diagrams. There are three main periods of change in the post-settlement vegetational development of the area. Firstly, Norse settlement affected the hydrology of the bog, resulting in the near-disappearance of Sphagnum and agricultural activity led to a reduction of some species (e.g. Angelica spp. and, Salix). Secondly, the establishment of probable permanent settlement in the mid-11th century AD initiated expansion of such apophytic taxa as Plantago spp. Lactuceae, Ranunculus spp. and Pteridophytes. Thirdly, the ≥ 10 cm thick Katla tephra, deposited in AD 1357, enhanced drainage of the bog surface, favouring dryland taxa (e.g. Poaceae, Galium and Lactuceae). The tephra deposit and the associated drainage probably caused or contributed to the local extinction of the wetland beetle Hydraena britteni. The study has enabled a series of natural and humanly-related issues to be addressed including tephra-vegetation relationships, the anthropogenic reduction in plant diversity, and comparisons between historical and environmental settlement records.     

Sand beach ridges record 6000 year history of extreme tropical cyclone activity in northeastern Australia

Sand beach ridges are considered to be derived either from aeolian processes and/or waves but their deposition by individual or multiple storms has not been investigated in any detail. We use numerical meteorological and oceanographic models to determine the origin of a sequence of 29 shore parallel sand beach ridges in northeastern Australia. The results suggest that the ridges were constructed by waves and that the final form or height of the ridges is a function of high-energy tropical cyclone generated waves plus storm tides. Hence these landforms archive a nearly 6000 year long history of intense tropical cyclones. The record implies that these extreme tempests occur considerably more frequently than that suggested by the short historical record for this region. The genesis of this sand beach ridge plain has implications for the interpretation of similar sequences elsewhere along the northeast coast of Australia and in comparable environments globally. If other similar sand beach ridge plains have also been deposited by like processes it stands to reason that these long-term records of high intensity tropical cyclones can be used to ascertain a regional scale risk assessment from this hazard.     

Movement,memory, landscape: an excursion in non-representational thought

This paper is an excursion in non-representational thought. The primacy of movement charges this creative geography. Movement as sensation, thought, matter and memory crystallizes in ongoing assemblages (effects) we term selves and landscapes. This movement ontology is animated by a stream of thought running through Bergson, Deleuze, and Massumi, and by Ingold’s temporality of landscape. Memory is vital, as past (virtual) and present (actual) coexist, pushing forward in duration, the dynamic continuation of movement and sensation. David Lynch’s film, The Straight Story, offers dramatic illustration of the entanglement of movement, memory, and landscape. Landscape is emergent as relational lines of movement, an ongoing meshwork of practices and movement signatures. Alvin Straight’s paced journey through Iowa on a John Deere lawn mower during autumn harvest is a road to reminiscence and reconciliation, an American sublime. Lynch’s movement-images and soundscapes are sensorial undulations that illumine landscape as movement of incorporation, ‘dwelling’ in the moment to moment, geographies of care. The take-home message is that we are nothing more and nothing less than agents, next selves, ‘passing’ through. The collective trace of our ‘passings’ constitutes the making and remaking of place.

Organic matter heterogeneities in 2.72 Ga stromatolites: Alteration versus preservation by sulfur incorporation

The stromatolites of the weakly metamorphosed 2.72 Ga Tumbiana Formation present abundant organic globules that resemble in size, shape and distribution the microorganisms observed in modern stromatolites. In order to evaluate the significance of these cell-like organic materials, we characterized organic matter in-situ down to the nanoscale using a combination of Fourier-transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), Raman microspectroscopy, scanning transmission X-ray microscopy (STXM) and transmission electron microscopy (TEM).These analyses revealed the occurrence of two distinct types of organic matter forming μm-scale textural and chemical heterogeneities distributed in distinct mineralogical laminae of the stromatolites. Type A organic matter, which is by far the most abundant, consists of sulfur-poor organic matter that is located in mud-type laminae at grain boundaries, mostly in association with silicate minerals. In contrast, Type B organic matter is rare and preserved as inclusions in the core of calcite grains forming laminates. It occurs as micrometer-sized cell-like globules containing variable amounts of organic sulfur likely in the form of thiophenes.Different scenarios may account for these compositional heterogeneities in the kerogen. Based on textural and compositional analogies with modern stromatolites, it is argued that Type B sulfur-rich globules may represent microbial cells protected by mineral encapsulation and selectively preserved through polymerization by early diagenetic sulfurization. In modern sediments, this reaction is fuelled by bacterial sulfate reduction (BSR). This metabolism has been widely considered as a major driver in modern stromatolites calcification and could thus have played an important role in the formation of the Tumbiana Formation stromatolites. In contrast, Type A sulfur-poor organic matter corresponds to either fossil extracellular polymer substances (EPS) or recondensed kerogen. This pool was likely not sulfurized due to either local and/or timely variations in the concentrations of H₂S or adverse pyritization driven by the availability of iron. Our observations thus show the need to use spatially-resolved techniques to complement organic geochemistry analyses and provide a detailed analysis of the organic carbon pools composing Archean stromatolites.