Estimation of trace element concentrations in the lunar magma ocean using mineral‐ and metal‐silicate melt partition coefficients

This study uses experimentally determined plagioclase‐melt D values to estimate the trace element concentrations of Sr, Hf, Ga, W, Mo, Ru, Pd, Au, Ni, and Co in a crystallizing lunar magma ocean at the point of plagioclase flotation. Similarly, experimentally determined metal‐silicate partition experiments combined with a composition model for the Moon are used to constrain the concentrations of W, Mo, Ru, Pd, Au, Ni, and Co in the lunar magma ocean at the time of core formation. The metal‐silicate derived lunar mantle estimates are generally consistent with previous estimates for the concentration of these elements in the lunar mantle. Plagioclase‐melt derived concentrations for Sr, Ga, Ru, Pd, Au, Ni, and Co are also consistent with prior estimates. Estimates for Hf, W, and Mo, however, are higher. These elements may be concentrated in the residual liquid during fractional crystallization due to their incompatibility. Alternatively, the apparent enrichment could reflect the inappropriate use of bulk anorthosite data, rather than data for plagioclase separates.     

On the discovery of CO nighttime emissions on Titan by Cassini/VIMS: Derived stratospheric abundances and geological implications

We present a quantitative analysis of CO thermal emissions discovered on the nightside of Titan by Baines et al. [2005. The atmospheres of Saturn and Titan in the near-infrared: First results of Cassini/VIMS. Earth, Moon, and Planets, 96, 119–147]. in Cassini/VIMS spectral imagery. We identify these emission features as the P and R branches of the 1-0 vibrational band of carbon monoxide (CO) near 4.65 μm. For CH₃D, the prominent Q branch of the ν₂ fundamental band of CH₃D near 4.55 μm is apparent. CO₂ emissions from the strong v₃ vibrational band are virtually absent, indicating a CO₂ abundance several orders of magnitude less than CO, in agreement with previous investigations. Analysis of CO emission spectra obtained over a variety of altitudes on Titan's nightside limb indicates that the stratospheric abundance of CO is 32±15 ppm, and together with other recent determinations, suggests a vertical distribution of CO nearly constant at this value from the surface throughout the troposphere to at least the stratopause near 300 km altitude. The corresponding total atmospheric content of CO in Titan is 2.9±1.5×10¹⁴ kg. Given the long lifetime of CO in the oxygen-poor Titan atmosphere (0.5–1.0 Gyr), we find a mean CO atmospheric production rate of 6±3×10⁵ kg yr⁻¹. Given the lack of primordial heavy noble gases observed by Huygens [Niemann et al., 2005. The abundances of constituents of Titan's atmosphere from the GCMS on the Huygens probe. Nature, 438, 779–784], the primary source of atmospheric CO is likely surface emissions. The implied CO/CH₄ mixing ratio of near-surface material is 1.8±0.9×10⁻⁴, based on an average methane surface emission rate over the past 0.5 Gyr of 1.3×10⁻¹³ gm cm⁻² s⁻¹ as required to balance hydrocarbon haze production via methane photolysis [Wilson and Atreya, 2004. Current state of modeling the photochemistry of Titan's mutually dependent atmosphere and ionosphere. J. Geophys. Res. 109, E06002 Doi:10.1029/2003JE002181]. This low CO/CH₄ ratio is much lower than expected for the sub-nebular formation region of Titan and supports the hypothesis [e.g., Atreya et al., 2005. Methane on Titan: photochemical-meteorological-hydrogeochemical cycle. Bull. Am. Astron. Soc. 37, 735] that the conversion of primordial CO and other carbon-bearing materials into CH₄-enriched clathrate-hydrates occurs within the deep interior of Titan via the release of hydrogen through the serpentinization process followed by Fischer–Tropsch catalysis. The time-averaged predicted emission rate of methane-rich surface materials is 0.02 km³ yr⁻¹, a value significantly lower than the rate of silicate lava production for the Earth and Venus, but nonetheless indicative of significant active geological processes reshaping the surface of Titan.     

An investigation of possible causes of the holes in the condensational Venus cloud using a microphysical cloud model with a radiative-dynamical feedback

Near-infrared observations of the nightside of Venus reveal regions of high brightness temperatures. These regions of high brightness temperatures are caused by the localized evaporation of the middle and lower cloud decks, which are about 50 to 60 km above the surface of the planet. We simulate the Venus condensational middle and lower cloud deck with the University of Colorado/NASA Ames Community Aerosol and Radiation Model for Atmospheres (CARMA). Our simulated clouds have similar characteristics to the observed Venus clouds. Our radiative transfer model reproduces the observed temperature structure and atmospheric stability structure within the middle cloud region. A radiative-dynamical feedback occurs which generates mixing due to increased absorption of upwelling infrared radiation within the lower cloud region, as previously suggested by others. We find that localized variations in temperature structure or in sub-grid scale mixing cannot directly explain the longevity and optical depth of the clouds. However, vertical motions are capable of altering the cloud optical depth by a sufficient magnitude in a short enough timescale to be responsible for the observed clearings.     

On the negligible surface age of Triton

New mapping reveals 100 probable impact craters on Triton wider than 5 km diameter. All of the probable craters are within 90° of the apex of Triton's orbital motion (i.e., all are on the leading hemisphere) and have a cosine density distribution with respect to the apex. This spatial distribution is difficult to reconcile with a heliocentric (Sun-orbiting) source of impactors, be it ecliptic comets, the Kuiper Belt, the scattered disk, or tidally-disrupted temporary satellites in the style of Shoemaker-Levy 9, but it is consistent with head-on collisions, as would be produced if a prograde population of planetocentric (Neptune-orbiting) debris were swept up by retrograde Triton. Plausible sources include ejecta from impact on or disruption of inner/outer moons of Neptune. If Triton's small craters are mostly of planetocentric origin, Triton offers no evidence for or against the existence of small comets in the Kuiper Belt, and New Horizons observations of Pluto must fill this role. The possibility that the distribution of impact craters is an artifact caused by difficulty in identifying impact craters on the cantaloupe terrain is considered and rejected. The possibility that capricious resurfacing has mimicked the effect of head-on collisions is considered and shown to be unlikely given current geologic constraints, and is no more probable than planetocentrogenesis. The estimated cratering rate on Triton by ecliptic comets is used to put an upper limit of ∼50 Myr on the age of the more heavily cratered terrains, and of ∼6 Myr for the Neptune-facing cantaloupe terrain. If the vast majority of cratering is by planetocentric debris, as we propose, then the surface everywhere is probably less than 10 Myr old. Although the uncertainty in these cratering ages is at least a factor ten, it seems likely that Triton's is among the youngest surfaces in the Solar System, a candidate ocean moon, and an important target for future exploration.