Origin and Formation of Sulfate in Soils from Three Ohio Counties

Sulfate induced heave has been attributed to ettringite, which can form when there is an elevated pH as well as sufficient amounts of aluminum, sulfate, calcium and water present. The primary objective of this project was to study the origin and formation of sulfate in Ohio soils in order to assist with selecting appropriate soil stabilization strategies for future roadway construction. Three roadway construction project areas were evaluated: State Route 2 in Lake (LAK) County, US Highway 24 in Paulding and Defiance Counties and Interstate-71 in Morrow (MRW) County. Defiance County had the most soil samples with sulfate concentrations above acceptable risk level (3000 mg/kg SO₄). Morrow County had the next highest number of unacceptable sulfate levels. Of the 42 Lake County soils analyzed, 11 contained sulfate above acceptable risk level. The soils surrounding the road construction activities along State Route 2 and US-24 had similar geological characteristics. A potential source of sulfate in Paulding and Defiance Counties was attributed to the direct deposition of gypsum as a soil amendment for farmlands. The most likely sources of soil sulfate in Morrow County were deposition of gypsum for farmland activities and the oxidative weathering of pyrite.     

Empirical Estimates of Global Climate Sensitivity： An Assessment of Strategies Using a Coupled GCM

A control integration with the normal solar constant and one with it increased by 2.5% in the National Center for Atmospheric Research （NCAR） coupled atmosphere-ocean Climate System Model were conducted to see how well the actual realized global warming could be predicted just by analysis of the control results. This is a test, within a model context, of proposals that have been advanced to use knowledge of the present day climate to make ＂empirical＂ estimates of global climate sensitivity. The scaling of the top-of-the-atmosphere infrared flux and the planetary albedo as functions of surface temperature was inferred by examining four different temporal and geographical variations of the control simulations. Each of these inferences greatly overestimates the climate sensitivity of the model, largely because of the behavior of the cloud albedo. In each inference the control results suggest that cloudiness and albedo decrease with increasing surface temperature. However, the experiment with the increased solar constant actually has higher albedo and more cloudiness at most latitudes. The increased albedo is a strong negative feedback, and this helps account for the rather weak sensitivity of the climate in the NCAR model. To the extent that these model results apply to the real world, they suggest empirical evaluation of the scaling of global-mean radiative properties with surface temperature in the present day climate provides little useful guidance for estimates of the actual climate sensitivity to global changes.     

FUV and NIR size of the HI selected low surface brightness galaxies

How low surface brightness galaxies(LSBGs)form stars and assemble stellar mass is one of the most important questions related to understanding the LSBG population.We select a sample of 381 HI bright LSBGs with both far ultraviolet(FUV)and near infrared(NIR)observations to investigate the star formation rate(SFR)and stellar mass scales,and the growth mode.We measure the FUV and NIR radii of our sample,which represent the star-forming and stellar mass distribution scales respectively.We also compare the FUV and H band radius-stellar mass relation with archival data,to identify the SFR and stellar mass structure difference between the LSBG population and other galaxies.Since galaxy HI mass has a tight correlation with the HI radius,we can also compare the HI and FUV radii to understand the distribution of HI gas and star formation activities.Our results show that most of the HI selected LSBGs have extended star formation structure.The stellar mass distribution of LSBGs may have a similar structure to disk galaxies at the same stellar mass bins,but the star-forming activity of LSBGs happens at a larger radius than the high surface density galaxies,which may help to identify the LSBG sample from the wide-field deep u band image survey.The HI is also distributed at larger radii,implying a steeper(or not)Kennicutt-Schmidt relation for LSBGs.     

Evidence and Implications of Recent Climate Change in Northern Alaska and Other Arctic Regions

The Arctic climate is changing. Permafrost is warming, hydrological processes are changing and biological and social systems are also evolving in response to these changing conditions. Knowing how the structure and function of arctic terrestrial ecosystems are responding to recent and persistent climate change is paramount to understanding the future state of the Earth system and how humans will need to adapt. Our holistic review presents a broad array of evidence that illustrates convincingly; the Arctic is undergoing a system-wide response to an altered climatic state. New extreme and seasonal surface climatic conditions are being experienced, a range of biophysical states and processes influenced by the threshold and phase change of freezing point are being altered, hydrological and biogeochemical cycles are shifting, and more regularly human sub-systems are being affected. Importantly, the patterns, magnitude and mechanisms of change have sometimes been unpredictable or difficult to isolate due to compounding factors. In almost every discipline represented, we show how the biocomplexity of the Arctic system has highlighted and challenged a paucity of integrated scientific knowledge, the lack of sustained observational and experimental time series, and the technical and logistic constraints of researching the Arctic environment. This study supports ongoing efforts to strengthen the interdisciplinarity of arctic system science and improve the coupling of large scale experimental manipulation with sustained time series observations by incorporating and integrating novel technologies, remote sensing and modeling.     

Wind-driven changes in Southern Ocean residual circulation, ocean carbon reservoirs and atmospheric CO2

The effect of idealized wind-driven circulation changes in the Southern Ocean on atmospheric CO₂ and the ocean carbon inventory is investigated using a suite of coarse-resolution, global coupled ocean circulation and biogeochemistry experiments with parameterized eddy activity and only modest changes in surface buoyancy forcing, each experiment integrated for 5,000 years. A positive correlation is obtained between the meridional overturning or residual circulation in the Southern Ocean and atmospheric CO₂: stronger or northward-shifted westerly winds in the Southern Hemisphere result in increased residual circulation, greater upwelling of carbon-rich deep waters and oceanic outgassing, which increases atmospheric pCO₂ by ～20 μatm; weaker or southward-shifted winds lead to the opposing result. The ocean carbon inventory in our model varies through contrasting changes in the saturated, disequilibrium and biogenic (soft-tissue and carbonate) reservoirs, each varying by O(10–100) PgC, all of which contribute to the net anomaly in atmospheric CO₂. Increased residual overturning deepens the global pycnocline, warming the upper ocean and decreasing the saturated carbon reservoir. Increased upwelling of carbon- and nutrient-rich deep waters and inefficient biological activity results in subduction of unutilized nutrients into the ocean interior, decreasing the biogenic carbon reservoir of intermediate and mode waters ventilating the Northern Hemisphere, and making the disequilibrium carbon reservoir more positive in the mode waters due to the reduced residence time at the surface. Wind-induced changes in the model carbon inventory are dominated by the response of the global pycnocline, although there is an additional abyssal response when the peak westerly winds change their latitude, altering their proximity to Drake Passage and changing the depth extent of the southward return flow of the overturning: a northward shift of the westerly winds isolates dense isopycnals, allowing biogenic carbon to accumulate in the deep ocean of the Southern Hemisphere, while a southward shift shoals dense isopycnals that outcrop in the Southern Ocean and reduces the biogenic carbon store in the deep ocean.     

Evolving geographies of innovation: existing paradigms,critiques and possible alternatives

ABSTRACT

Theory development on the geographies of innovation has been very successful in incorporating the changing patterns of knowledge dynamics due to globalization, lifting the gaze beyond processes of localized learning and increasingly acknowledging the multilevel, multiscalar governance of innovation. Arguably less attention has been directed to the changing qualities and impacts of innovation as a result of globalization, notably in view of social polarization and climate change. The aim of the article is to provide suggestions for how research on the geography of innovation can be improved by engaging with a more capacious understanding of innovation and territorial development. The authors explore how socio-ecological innovation can be introduced in contemporary discussions and practices of place-based smart specialization policy. They conclude by suggesting that future research should address and interrogate (1) the rise of the foundational economy as an expression of place-based innovation, which entails new forms of co-governance, and (2) the challenge of experimentalism in the public sector, a sector that looms large in lagging regions and the places that were deemed not to matter until they took their revenge on the mainstream political system.     

Moderately and slightly siderophile element constraints on the depth and extent of melting in early Mars

The thermal history of Mars during accretion and differentiation is important for understanding some fundamental aspects of its evolution such as crust formation, mantle geochemistry, chronology, volatile loss and interior degassing, and atmospheric development. In light of data from new Martian meteorites and exploration rovers, we have made a new estimate of Martian mantle siderophile element depletions. New high pressure and temperature metal–silicate experimental partitioning data and expressions are also available. Using these new constraints, we consider the conditions under which the Martian mantle may have equilibrated with metallic liquid. The resulting conditions that best satisfy six siderophile elements—Ni, Co, W, Mo, P, and Ga—and are consistent with the solidus and liquidus of the Martian mantle phase diagram are a pressure of 14 ± 3 GPa and temperature of 2100 ± 200 K. The Martian mantle depletions of Cr and V are also consistent with metal–silicate equilibration in this pressure and temperature range if deep mantle silicate phases are also taken into account. The results are not consistent with either metal–silicate equilibrium at the surface or at the current‐day Martian core–mantle boundary. Recent measurements and modeling have concluded that deep (～17 GPa or 1350 km) mantle melting is required to explain isotopic data for Martian meteorites and the nature of differentiation into core, mantle, and crust. This is in general agreement with our estimates of the conditions of Martian core formation based on siderophile elements that result in an intermediate depth magma ocean scenario for metal–silicate equilibrium.     

Ejecta from impact craters

An important feature of impacts into Solar System bodies is the fate of crater ejecta, the near-surface material launched during the highly dynamic crater formation process. Laboratory measurements of impact crater ejecta from 18 studies are summarized. The data are examined and used to assess our understanding of how the ejecta velocity and mass distributions depend on the conditions of an impact event. The effects of impact speed on the ejecta are reasonably well understood, but the dependences on target properties such as strength and porosity are only poorly constrained. A point-source scaling model for the ejecta mass and velocity distributions is developed and fit to the data for several classes of materials distinguished by porosity.     

Another Record: Ocean Warming Continues through 2021 despite La Ni?a Conditions

The increased concentration of greenhouse gases in the atmosphere from human activities traps heat within the climate system and increases ocean heat content (O...     

The Role of Submerged Aquatic Vegetation in Structuring the Nearshore Fish Community Within an Estuary of the Southern Gulf of St. Lawrence

Artificial fertilizers are contributing to the replacement of eelgrass (Zostera marina) by sea lettuce (Ulva lactuca) in estuaries of Prince Edward Island (PEI), Canada. In this study, we found that the nearshore fish community differed between areas dominated by these two vegetations within an estuary in every month sampled (April–August). Adult northern pipefish (Syngnathus fuscus), threespine stickleback (Gasterosteus aculeatus), blackspotted stickleback (Gasterosteus wheatlandi), and Atlantic silverside (Menidia menidia) were most strongly associated with eelgrass, while mummichog (Fundulus heteroclitus), ninespine stickleback (Pungitius pungitius), and American eel (Anguilla rostrata) were often more numerous in sea lettuce. Sea lettuce stations tended to have more young-of-the-year mummichog, fourspine stickleback (Apeltes quadracus), and Gasterosteus sp. than eelgrass stations but fewer young-of-the-year northern pipefish and Atlantic silverside. Fish richness and abundance were significantly lower in the sea lettuce than eelgrass habitat during August when benthic hypoxia occurred. We conclude that the loss of eelgrass from PEI estuaries will result in significant declines in fish biodiversity.