An unconformity in the early Miocene syn-rifting succession, northern Noto Peninsula, Japan: Evidence for short-term uplifting precedent to the rapid opening of the Japan Sea

Abstract   The present paper describes the newly discovered early Miocene unconformity in the northern Noto Peninsula, on the Japan Sea side, central Japan. The unconformity marks the boundary between an early Miocene non-marine to marine succession and a more extensive, late early to early middle Miocene marine succession, and contains a time gap of an order of 1 million years or less from 18 Ma or earlier to 17 Ma. The early Miocene succession likely represents an early phase of marine transgression and initial slow rifting. The overlying early to early middle Miocene succession records the climax of the opening of the Japan Sea at ca  16 Ma with widespread, rapid subsidence of the Japan Arc. The unconformity between the two transgressive successions may represent a global sealevel fall or, more likely, crustal uplifting because no upward-shallowing or regressive facies remains between the two successions. Early Miocene unconformities that are thought to be correlative with this unconformity in the northern Noto Peninsula occur in places along the Japan Sea coast of Sakhalin and Japan. They are likely to have been produced during rifting in response to upwelling of asthenospheric mantle, although more accurate age constraints are necessary to evaluate this idea.     

The mineralogy of the Kokchetav ‘lamproite’: implications for the magma evolution

Kokchetav ‘lamproite’ occurs in the east end of Kokchetav massif and consists of phenocryst (mainly clinopyroxene) and matrix (mainly feldspar). The compositions of clinopyroxene, magnetite and biotite phenocryst were determined using wavelength dispersive spectrometry on a JEOL Super-probe 8900 electron microprobe for the purpose of revealing the process of magma evolution. Analyses revealed a core–rim variation, which is consistent with three stages of magmatic evolution: Mg-rich clinopyroxene cores (diopside) and biotite cores (phlogopite) crystallized in a deep magma chamber (stage I); Fe-rich clinopyroxene rim (salite) and biotite rim crystallized at low pressure in a shallow magma chamber (stage II); Magnetite phenocryst core also crystallized in a shallow magma chamber, and co-exists with Fe-rich clinopyroxene rim and biotite rim. The magnetite rims probably formed during magma eruption at the same time when groundmass crystallized (stage III). The calculated temperatures for ilmenite–magnetite pair range from 679 to 887°C, log fO₂ values range from −11.1 to −14.9 log units. These values represent the latest conditions of magma as ilmenite exsolution in magnetite probably occurred during magma eruption from the shallow chamber to surface.     

Diamond-bearing and diamond-free metacarbonate rocks from Kumdy–Kol in the Kokchetav Massif, northern Kazakhstan

Abstract Dolomite marble from the Kumdy–Kol area of the Kokchetav Massif contains abundant microdiamond, mainly in garnet and a few in diopside. The mineral assemblage at peak metamorphic condition consists of dolomite + diopside + garnet (+ aragonite) ± diamond. Inclusions of very low MgCO₃ calcite and almost pure calcite occur in diopside and are interpreted as aragonite and/or aragonite + dolomite. Single-phase Mg–calcite in diopside with a very high MgCO₃ component (up to 21.7 mol%) was also found in diamond-free dolomitic marble, and is interpreted as a retrograde product from aragonite + dolomite to Mg–calcite. The dolomite stability constrains the maximum pressure (P) at < 7 GPa using previous experimental data, whereas the occurrence of diamond yields the minimum peak pressure–temperature (P–T) condition at 4.2 GPa and 980 °C at X co ₂ = 0.1. The highest MgCO₃ in Mg–calcite constrains the minimum P–T condition higher than 2.5 GPa and 800 °C for the exhumation stage. As these marbles were subjected to nearly identical P–T metamorphic conditions, the appearance of diamond in some carbonate rocks was explained by high X co ₂. A low X co ₂ condition refers to high oxidized conditions and diamond (and/or graphite) becomes unstable. Difference in X co ₂ for marble from the same area suggests local heterogeneity of fluid compositions during ultrahigh-pressure metamorphism.     

SHRIMP U–Pb zircon dating of the Kinshozan Quartz Diorite from the Kanto Mountains,Japan: Implications for late Paleozoic granitic activity in Japanese Islands

The new result of SHRIMP U–Pb zircon dating of the Kinshozan Quartz Diorite from the Kanto Mountains, Japan, provides 281.5 ± 1.8 Ma. The age is 30 m.y. older than the available age of the Kinshozan Quartz Diorite obtained by hornblende K–Ar method. The new U–Pb zircon age represents the time of crystallization of the Kinshozan Quartz Diorite. The hornblende K–Ar age indicates the time that the Kinshozan Quartz Diorite cooled down to 500 °C which is the closure temperature of the systematics. Permian granites are found in small exposures in Japan, and frequently referred to as 250 Ma granites. The Kinshozan Quartz Diorite is considered as a type of the 250 Ma granites, and the age was influential in establishing a model of Paleozoic tectonic evolution for the Japanese Islands. The new age of the Kinshozan Quartz Diorite provides the opportunity to re‐examine the model. The Kinshozan Quartz Diorite and other Permian granites in the south of the Median Tectonic Line of Japan were constituents of the Paleo‐Ryoke Belt. The geochemical characteristics of the granitic rocks in the Paleo‐Ryoke Belt indicated that the granitic rocks were formed in a primitive island arc environment, and the new trace element data also support this interpretation. Examination of the available data and results of the present study suggests the late Paleozoic granitic activity in Japan as follows. At about 310–290 Ma, arc magmatism generated adakitic granites and other granites in the South Kitakami Belt. Quartz diorite and tonalites of primitive characteristic, such as the Kinshozan Quartz Diorite and granites in the Maizuru Belt appear to have been formed at the immature island arc, and accreted to the Japanese Islands at the end of Paleozoic or early Mesozoic era. During 260–240 Ma, granitic activity took place in the Hida and Maizuru Belts as a part of the Asian continent.     

Frequency–Magnitude Distribution of −3.7 ≤ M W ≤ 1 Mining-Induced Earthquakes Around a Mining Front and b Value Invariance with Post-Blast Time

We investigated frequency-magnitude distribution (FMD) of acoustic emissions (AE) occurring near an active mining front in a South African gold mine, using a catalog developed from an AE network, which is capable of detecting AEs down to M _W  ?5. When records of blasts were removed, FMDs of AEs obeyed a Gutenberg?Richter law with similar b values, not depending on post-blasting time from the initial 1-min interval through more than 30 h. This result denies a suggestion in a previous study (Richardson and Jordan Bull Seismol Soc Am, 92:1766–1782, 2002) that new fractures generated by blasting disturb the size distribution of background events, which they interpreted as slip events on existing weak planes. Our AE catalog showed that the GR law with b ～ 1.2 was valid between M _W  ?3.7 and 0 for AEs around the mining front. Further, using the mine’s seismic catalog, which covers a longer time period of the same area, we could extend the validity range of the GR law with the same b value up to M _W 1.     

Geochemical and geochronological constraints on the origin and emplacement of the Shimo-ondori diorites in Shikoku,Southwest Japan

In this study, the LA-ICP-MS zircon U–Pb dating of the Shimo-ondori diorites in the Shimanto accretionary complex of SW Japan provides ~130 Ma, representing the timing of their crystallization ages. Combined with the geological occurrence, that age clearly indicates that the diorites occur as blocks, not as intrusive rocks as suggested by previous studies. Moreover, the ages of the Shimo-ondori diorites are suggesstive that they could be influential for the estimate of the early-Cretaceous tectonic evolution for the eastern Asian margin. Their whole-rock chemical compositions show high MgO, Ni and Cr contents, and low total FeO/MgO ratios, indicating that they were crystallized from high magnesian andesite (HMA) magmas. Moreover, their TiO₂ and REE compositions suggest that they were formed by the same processes as the sanukites. And, the zircon Hf isotopic ratios (ε_Hf [~130 Ma] = +9.9 − +17.5), which is close to or slightly lower than that of the ~130 Ma depleted mantle, suggest that the wedge-mantle materials were predominantly involved in the formation of the dioritic magmas. Their geochronological and geochemical similarities of the Shimo-ondori diorites with the early Cretaceous adakites and HMAs in the eastern Asian margin suggest that they might have been formed possibly by the same slab rollback of the Izanagi plate at the early Cretaceous. After the crystallization of the Shimo-ondori diorites, they were delivered and deposited as blocks in a trench site with the surrounding sedimentary rocks of the Shimanto accretionary complex.     

How do management alternatives of fast-growing forests affect water quantity and quality in southeastern Brazil? Insights from a paired catchment experiment

Fast-growing forest plantations have been expanding in Brazil in the last 50 years, which reach productivities by over 40 m³ ha⁻¹ year⁻¹ in reduced rotation between 5 and 15 years. In the 1990s, environmental warnings about these plantations guided research projects seeking to understand their effects on water and propose forest management actions to minimize them. The assessment of forest management effects on water resources is conducted by long-term experiments in paired catchments. In this paper we present results of some studies conducted at the hydrological monitoring centre of Itatinga Experimental Forest Station, of the University of São Paulo, where hydrological monitoring began in 1987, and currently include three catchments (83–98 ha) under different forest management regimes: short-rotation Eucalyptus plantation, long-term forest plantation mosaic and native forest restoration. Results show that at similar conditions observed at study area including deep soils and good natural water regulation, hydrological effects vary according to the forest management regime adopted, increasing water consumption and making the flow regime vulnerable to intra- and inter-annual seasonality. Regarding water quality, weekly sampling results showed suspended sediments and nitrate concentrations below water quality thresholds criteria by silvicultural operations, and the effects were transient but higher concentrations of nutrients were observed in intensive management regime. In the study area, reducing the management intensity of forest plantation by increasing the rotation time, adopting forest age mosaic and avoiding the coppice technique are alternative choices that reduced water use and increased flow regulation. Different adopted forest management schemes directly affected water use, showing that in water-deficit tropical regions, management regime of fast-growing forest plantations controls water availability.     

Petrogenetic grid for ultrahigh-pressure metamorphism in the model system CaO-MgO-SiO2-CO2-H2O

Abstract Petrogenetic grids for ultrahigh-pressure (UHP) metamorphism were calculated at different X_co2 conditions in the model system CaO-MgO-SiO₂-CO₂-H₂O involving coesite (Co), diopside (Di), dolomite (Do), enstatite (En), forsterite (Fo), magnesite (Ms), quartz (Qz), talc (Tc), tremolite (Tr) using a published internally consistent thermodynamic data set. Two P-T grids at X_co2= 0.01 and 0.5 are described. In the calculated P-T grid at X_co2= 0.01, four out of 10 stable invariant points, Co-En-Ms-Tc, Co-Di-En-Tc-Tr, Co-Di-Ms-Tc-Tr and Di-En-Ms-Tc-Tr lie within the stability field of coesite. If the fluid phase has X_co2= 0.5, no invariant point is stable under UHP conditions. Some magnesite-bearing assemblages are stabilized by the following three reactions: Di + Ms = Do + Fo + CO₂, Ms + Tr = Do + Fo + CO₂+ H₂O and Ms + Tc = Fo+ CO₂+ H₂O at X_co2= 0.01 and by reaction Ms + Tc = Fo + CO₂+ H₂O together with these three at X_co2= 0.5. Ten possible UHP assemblages for mafic and ultramafic compositions at very low X_co2 conditions include the following: Co-Do-Ms, Co-Di-Ms, Co-Di-Tc, Di-Ms-Tc, Di-En-Tc-, Di-En-Ms, Co-Di-En, Di-En-Fo, Di-Fo-Ms, Di-Do-Fo. Among them, talc-bearing assemblages are restricted to X_co2 < 0.02 and their high-P limit is 31.7 kb (749°C) at X_co2= 0.01. Dolomite-magnesite-silica assemblages have large P-T stability fields even if X_co2 is as low as 0.1, and could occur in cold subduction zones with very low geothermal gradients. Reported UHP coesite-dolomite assemblage is restricted only to a calc-silicate rock interlayered with marble where X_co2 is relatively higher; no such assemblage appears for mafic and ultramafic rocks with low X_co2 evidenced by the occurrence of diopside (or omphacite) at the expense of dolomite + coesite. The effect of X_co2 on the stability of coesite-dolomite-magnesite, diopside-enstatite-magnesite, diopside-talc assemblages is examined and the occurrence of coesite-dolomite, magnesite-bearing and talc-bearing assemblages in the Dabie UHP rocks are interpreted by employing the calculated P-T grids.     

Post-seismic Effects of an M 7.2 Earthquake and Microseismicity in an Abandoned, Flooded, Deep Mine

—?An M 7.2 earthquake took place 67?km southeast of an abandoned mine containing flooded, vertical ore veins at depth of 1?km. Multidisciplinary monitoring of the unweathered country rock within the mine was carried out for a distance of about one kilometer. The M 7.2 earthquake was followed by significant post-seismic changes in strain and tilt of ～10^?6, with a self-potential of ～10?mV, and an increase in the water level in the mine of about 10?cm/day. These phenomena continued for several months before returning to pre-earthquake levels. Coseismic elastic deformations were too small to account for the observed post-seismic changes, and have different senses in strain and tilt from the observed post-seismic changes. The contractions in strain and the changes in the electric self-potential and water-elevation rate strongly suggest an increase in pore pressure. An increase in microseismic activity (M?M 7.2 earthquake.