Concentration fluctuation measurements in tracer plumes using high and low frequency response detectors

A set of tracer experiments designed to compare two concentration fluctuation detectors and measure fluctuation statistics at high frequencies is described. A detector which has been used in several previous fluctuation experiments (the TIP photoionisation detector manufactured by Photovac of Canada) is compared with another with a much higher frequency response (the flame ionisation detector — FID — made by Cambustion of the UK). Good agreement is found and results show that the signal optimization system used in previous work with the TIP provides an accurate enhancement of the instrument output, thus improving confidence in the results of previous papers. They also confirm that the TIP detector is able to resolve most of the concentration variance in most situations of interest, but not at very short range. Measurements of the high frequency end of the fluctuation spectrum using the FID show inertial-convective subrange behaviour at frequencies not resolved by the TIP, supporting earlier work. Fluctuation spectra measured very close to the source are also shown to have a characteristic +2/3 power law behaviour (when nSc (n) is plotted against n) at lower frequencies, in agreement with theoretical predictions.     

Midge- and diatom-based palaeosalinity reconstructions for Mahoney Lake, Okanagan Valley, British Columbia, Canada

Salinity fluctuations in lakes of semi-arid regions have long been recognised as indicators of palaeoclimatic change, and have provided a valuable line of evidence in palaeo-climatic reconstruction. In the present study, fossil remains of diatoms and midges were used to reconstruct salinity changes at Mahoney Lake from the early postglacial, through the early, mid and late Holocene. A transition from midges typical of a freshwater community (Protanypus, Sergentia, Heterotrissocladius, Cladopelma, Dicrotendipes) during the early postglacial, to those indicative of saline environments (Cricotopus/Orthocladius, Tanypus) occurred in the early Holocene. The midge-inferred salinity values reflected the shift from freshwater (0.031 g/L) immediately after deglaciation, to saline water (2.4 to 55.2 g/L) in subsequent periods. A less saline period was found to have occurred after 1000 yr BP, suggesting a cooler or wetter period. The diatom record indicates similar trends, with freshwater taxa (e.g.,Cyclotella bodanica var. aff.lemanica) dominating near the bottom of the core. Diatom-inferred salinities indicate that saline conditions (about 30 g/L) prevailed throughout subsequent Holocene time, although relatively fresh conditions are indicated following deposition of the Mazama Ash, and from about 1500 yr BP until the present day. Midge and diatom-inferred salinity reconstructions for Mahoney Lake compare favorably with each other, and with climate trends inferred from earlier palynological evidence. The palaeosalinity record thus contributes new data relevant to past climatic conditions, in a region where little data have previously been collected.     

Isotopic and chemical constraints on the crustal evolution and source signature of Ferrar magmas,north Victoria Land,Antarctica

Isotopic (Nd and Sr) and chemical compositions of the 177 Ma Kirkpatrick Basalt and Ferrar Dolerite from north Victoria Land, Antarctica, are examined in order to address the role of crustal assimilation and the characteristics of their mantle source. Results for the Scarab Peak chemical type (SPCT) that constitutes the flow unit capping the lava sequence [Mg-number, Mg/(Mg+Fe⁺²)=24, MgO=2.4%, SiO₂=57.1%, initial⁸⁷Sr/⁸⁶Sr=0.7087–0.7097, (ε_Nd=−4.3) conform previous reports that attribute variations in the concentrations of the more mobile elements and calculated initial⁸⁷Sr/⁸⁶Sr to mid-Cretaceous alteration and elevated δ¹⁸O to low-temperature interaction with meteoric water. The underlying lavas and the sills that are of the Mt. Fazio chemical type (MFCT) display a much wider range of both chemical and isotopic compositions (Mg-number=40–65, MgO=3.7 7.5%; SiO₂=52.6–58.3%, initial⁸⁷Sr/⁸⁶Sr=0.7087–0.7117, ε_Nd=−5.6 to −4.8). The effects of rock alteration on apparent initial⁸⁷Sr/⁸⁶Sr are demonstrated by large differences between the initial ratio of mineral separates or leached fractions and whole rocks. Cretaceous alteration produced Rb and Sr redistribution within the lava sequence that results in erroneous calculated initial⁸⁷Sr/⁸⁶Sr ratios. These effects are responsible for the large initial⁸⁷Sr/⁸⁶Sr variations previousl7 proposed which, combined with the large range in whole-rock δ¹⁸O, were purported to show very large degrees of crustal assimilation. The variations in ε_Nd are restricted and indicate much smaller degrees of assimilation. The least altered of the MFCT rocks show good chemical and isotopic correlations that can be integrated into a model involving fractionation of pyroxene and plagioclase coupled with assimilation of material similar to early Paleozoic basement. The lower⁸⁷Sr/⁸⁶Sr and higher ε_Nd of the SPCT suggest that they were derived by extensive fractionation of a more primitive, less contaminated, precursor of the MFCT. The most isotopically primitive Ferrar rocks from the region still have a high initial⁸⁷Sr/⁸⁶Sr and low initial¹⁴³Nd/¹⁴⁴Nd; this may reflect either earlier assimilation or an enriched source. The chemical and isotopic similarities, as well as the close geographic correspondence of the Ferrar Group to granitoids produced during the early Paleozoic Ross Orogeny suggest that in either case Ross-type material may have been involved in the development of the enriched isotopic signature. Editorial responsibility: I. Parsons     

Characterization of periodic variations in the GPS satellite clocks

The clock products of the International Global Navigation Satellite Systems (GNSS) Service (IGS) are used to characterize the timing performance of the GPS satellites. Using 5-min and 30-s observational samples and focusing only on the sub-daily regime, approximate power-law stochastic processes are found. The Block IIA Rb and Cs clocks obey predominantly random walk phase (or white frequency) noise processes. The Rb clocks are up to nearly an order of magnitude more stable and show a flicker phase noise component over intervals shorter than about 100 s. Due to the onboard Time Keeping System in the newer Block IIR and IIR-M satellites, their Rb clocks behave in a more complex way: as an apparent random walk phase process up to about 100 s and then changing to flicker phase up to a few thousand seconds. Superposed on this random background, periodic signals have been detected in all clock types at four harmonic frequencies, n × (2.0029 ± 0.0005) cycles per day (24 h coordinated universal time or UTC), for n = 1, 2, 3, and 4. The equivalent fundamental period is 11.9826 ± 0.0030 h, which surprisingly differs from the reported mean GPS orbital period of 11.9659 ± 0.0007 h by 60 ± 11 s. We cannot account for this apparent discrepancy but note that a clear relationship between the periodic signals and the orbital dynamics is evidenced for some satellites by modulations of the spectral amplitudes with eclipse season. All four harmonics are much smaller for the IIR and IIR-M satellites than for the older blocks. Awareness of the periodic variations can be used to improve the clock modeling, including for interpolation of tabulated IGS products for higher-rate GPS positioning and for predictions in real-time applications. This is especially true for high-accuracy uses, but could also benefit the standard GPS operational products. The observed stochastic properties of each satellite clock type are used to estimate the growth of interpolation and prediction errors with time interval.     

Oyster Predation by Black Drum Varies Spatially and Seasonally

Oyster reefs (Crassostrea virginica) supply important ecosystem services to estuarine habitats in the northern Gulf of Mexico, but little is known of the role of fish predators in controlling their structure or areal cover on soft sediments. At two sites and during fall and spring, we employed gill nets and trot lines to remove black drum (Pogonias cromis) from experimental reefs, and assessed oyster survival in comparison to control reefs. Numbers and biomass of black drum removed from reefs varied seasonally, among sites, and among removal methods. In the fall, black drum were rare at one site and abundant at the other, but did not significantly lower oyster survival on control reefs at either site. In the spring, black drum were common at both sites, and significantly lowered oyster survival on control reefs. Oysters and epizoic hooked mussels comprised roughly a third of the fishes’ diet, and oyster mortality was closely related to the percentage of drum feeding on oysters. There was little evidence of mortality from other predators of seed oysters like stone crabs or Southern oyster drills, and a repeated measures analysis of variance indicated black drum biomass was significantly depressed on experimental reefs during the experiments. Black drum thus appear to be potentially important predators on oyster reefs, but more work needs to be done on what factors explain the temporal and spatial variation in their abundance and oyster consumption.     

Quantitative Analysis of H2OComa Images Using a Multiscale MHD Model with Detailed Ion Chemistry

The observation of ions created by ionization of cometary gas, either by ground-based observations or byin situmeasurements can give us useful information about the gas production and composition of comets. However, due to the interaction of ions with the magnetized solar wind and their high chemical reactivity, it is not possible to relate measured ion densities (or column densities) directly to the parent gas densities. In order to quantitatively analyze measured ion abundances in cometary comae it is necessary to understand their dynamics and chemistry. We have developed a detailed ion–chemical network of cometary atmospheres. We include production of ions by photo- and electron impact-ionization of a background neutral atmosphere, charge exchange of solar wind ions with cometary atoms/molecules, reactions between ions and molecules, and dissociative recombination of molecular ions with thermal electrons. By combining the ion–chemical network with the three-dimensional plasma flow as computed by a new fully three-dimensional MHD model of cometary plasma environments (Gombosiet al.1996) we are able to compute the density of the major cometary ions everywhere in the coma. The input parameters for our model are the solar wind conditions (density, speed, temperature, magnetic field) and the composition and production rate of the gas. We applied our model to Comet P/Halley in early March 1986, for which the input parameters are reasonably well known. We compare the resulting column density of H₂O⁺with ground-based observations of H₂O⁺from DiSantiet al.(1990). The results of our model are in good agreement with both the spatial distribution and the absolute abundance of H₂O⁺and with their variations with the changing overall water production rate between two days. The results are encouraging that it will be possible to obtain production rates of neutral cometary constituents from observations of their ion products.     

Compact,variable sources on the Sun at 2 centimeter wavelength

Very Large Array (VLA) observations of compact transient sources on the Sun at 2 cm wavelength are presented. These sources have angular sizes of 5–25, brightness temperatures of T _B 1–3 × 10⁵ K, and lifetimes ranging between a few minutes to several hours. The emission originates in regions of diffuse plage and quiet Sun, where the photospheric magnetic fields are relatively weak (H 100 G). In some cases the 2 cm radiation may be explained as the thermal bremsstrahlung of a dense (N _e 10¹⁰ cm^-3) plasma in the transition region. For other sources, the relatively high circular polarization ( _c 40–50 %) suggests a nonthermal emission mechanism, such as the gyrosynchrotron radiation of mildly relativistic electron with a power-law spectrum.     

Denudation rates of a subequatorial orogenic belt based on estimates of sediment yields: evidence from the Paleozoic Appalachian Basin,USA

The Upper Mississippian (ca. 325 Ma) Pride Shale and Glady Fork Member in the Central Appalachian Basin comprise an upward‐coarsening, ca. 60‐m‐thick succession of prodeltaic‐delta front, interlaminated fine‐grained sandstones and mudstones gradational upwards into mouth‐bar and distributary‐channel sandstones. Analysis of laminae bundling in the Pride Shale reveals a hierarchy of tidal cycles (semi‐diurnal, fortnightly neap‐spring) and a distinct annual cyclicity resulting from seasonal fluvial discharge. These tidal rhythmites thus represent high‐resolution chronometers that can be used in basin analysis. Annual cycles average 10 cm in thickness, thus the bulk of the Pride Shale‐Glady Fork Member in any one vertical section is estimated to have accumulated in ca. 600 years. Progradational clinoforms are assumed to have had dips of 0.3–3° with a median dip of 1.7°; the latter infilled a NE‐SW oriented foreland trough up to 300 km long by 50 km wide in the relatively short time period of 90 kyr. The total volume of sediment in the Pride basin is ca. 900 km³ which, for an average sediment density of 2700 kg m^?3, equates to a total mass of ca. 2.4 × 10⁶ Mt. Thus, mass sediment load can be estimated as 27 Mt yr^?1. For a drainage basin area of 89 000 km², based on the scale of architectural channel elements and cross‐set thicknesses in the incised‐valley‐fill deposits of the underlying Princeton Formation, suspended sediment yields are estimated at ca. 310 t km^?2 yr^?1 equating to a mechanical denudation rate of ca. 0.116 mm yr^?1. Calculated sediment yields and inferred denudation rates are comparable to modern rivers such as the Po and Fly and are compatible with a provenance of significant relief and a climate characterized by seasonal, monsoonal discharge. Inferred denudation rates also are consistent with average denudation rates for the Inner Piedmont Terrane of the Appalachians based on flexural modelling. The integration of stratigraphic architectural analysis with a novel chronometric application highlights the utility of sedimentary archives as a record of Earth surface dynamics.