Geochronology of archean gneisses in the Lake Helen area,Southwestern Big Horn Mountains,Wyoming

The RbSr and UPb methods were used to study gneisses in the $\text{7}\text{1}\text{2}\text{-}\text{minute}$ Lake Helen quadrangle of the Big Horn Mountains, Wyoming. Two episodes of magmatism, deformation and metamorphism occurred during the Archean. Trondhjemitic to tonalitic orthogneisses and amphibolite of the first episode (E-1) are cut by a trondhjemite pluton and a calc-alkaline intrusive series of the second episode (E-2). The E-2 series includes hornblende-biotite quartz diorite, biotite tonalite, biotite granodiorite and biotite granite.A RbSr whole-rock isochron for E-1 gneisses indicates an age of 3007 ± 34 Ma (1 sigma) and an initial ⁸⁷Sr/⁸⁶Sr of 0.7001 ± 0.0001. UPb determination on zircon from E-1 gneisses yield a concordia intercept age of 2947 ± 50 Ma. The low initial ratio suggests that the gneisses had no significant crustal history prior to metamorphism, and that the magmas from which they formed had originated from a mafic source.A RbSr whole-rock isochron for E-2 gneisses gives an age of 2801 ± 31 Ma. The ⁸⁷Sr/⁸⁶Sr initial ration is 0.7015 ± 0.0002 and precludes the existence of the rocks for more than 150 Ma prior to metamorphism. The E-2 magmas may have originated from melting of E-1 gneisses or from a more mafic source.     

An automated precise Winkler titration for determining dissolved oxygen on board ship

An automated titration for the Winkler method is presented for measuring primary productivity in the ocean. The system is based on a microcomputer-controlled titration with potentiometric endpoint detection. By the use of 0.005-N sodium thiosulfate as a titrant and a program designed to shorten the time for measuring, the method achieves a precision of 0.04% coefficient of variation with a range of 0.01 to 0.10% for six replicates of samples at oxygen concentration of 70 to 250 M. It takes about four to five minutes to measure one sample.     

Role of the shale tectonics on the evolution of the Eastern Venezuelan Cenozoic thrust and fold belt

This paper presents a structural and stratigraphic analysis of the foreland-fold-belt of the Eastern Venezuelan Basin and the main conclusions about shale tectonic mechanisms in the area. The deformation of the foreland-fold-belt has been investigated analyzing the growth strata architecture preserved on the structure fold limbs. Three contractional episodes are proposed for the Eastern Venezuelan Basin: 1) Oligocene to middle Miocene, 2) late Miocene to Pliocene and 3) Pleistocene. The first episode produced contractional listric faults inside the shale and long displacement blind thrusts in the underlying Cretaceous units. The second episode produced the deformation of the Cenozoic strata into overlapping east-west-trending, convex northward anticlines that covers more than 200 kilometers in length and 40 kilometers wide, break-through normal faults product of a high sedimentary load that overcomes contraction and the formation of short-displacement blind thrusts in the underlying Cretaceous units. The last episode is related to an oblique compression and the formation of high angle extensional faults with dextral movement and NW-SE strike. The role of the shale tectonics in the evolution implies that shale deforms in two stages: 1) folding and 2) normal faulting of the crest of the anticline (Break through normal faulting). Folding controlled the sediment distribution during most of the Neogene strata, while the normal faulting of the anticlines represent basin potential for hydrocarbon. The best potential hydrocarbon plays in the basin are related to oblique-collision restricted basins and controlled by break-through normal faults and the presence of NW-SE strike faults that connect the HC source with the reservoirs. Results from this research imply that the role of sedimentation is fundamental for the overburden sand distribution and tectonic constrain of the folds.     

Evaluation of heterogeneity and field-scale groundwater flow regime in a leaky till aquitard

Recent work in southern Ontario, Canada, demonstrates anomalously high vertical groundwater flow velocities (>1 m/year) through a thick (as much as 60 m), sandy silt till aquitard (Northern till), previously assumed to be of very low permeability (hydraulic conductivity <10^–10 m/s). Rapid recharge is attributed to the presence of fractures and sedimentary heterogeneities within the till, but the field-scale flow regime is poorly understood. This study identifies the nature of physical groundwater pathways through the till and provides estimates of the associated groundwater fluxes. The aquitard groundwater flow system is characterized by integrating details of the outcrop and subsurface sedimentary characteristics of the till with field-based hydrogeologic investigation and numerical modeling. Outcrop and subsurface data identify a composite internal aquitard stratigraphy consisting of tabular till beds (till elements) separated by laterally continuous sheet-like sands and gravels (interbeds) and boulder pavements. Individual till elements contain sedimentary heterogeneities, including discontinuous sand and gravel lenses, vertical sand dikes, and zones of horizontal and vertical fractures. Hydrogeologic field investigations indicate a three-layer aquitard flow system, consisting of upper and lower zones of more hydraulically active and heterogeneous till separated by a middle unit of relatively lower hydraulic conductivity. Groundwater pathways and fluxes in the till were evaluated using a two-dimensional aquitard/aquifer flow model which indicates a step-wise flow mechanism whereby groundwater moves alternately downward along vertical pathways (fractures, sedimentary dikes) and laterally along horizontal sand interbeds within the till. This model is consistent with observed hydraulic-head and isotope profiles, and the presence of tritiated pore waters at various depths throughout the till. Simulations suggest that a bulk aquitard vertical hydraulic conductivity on the order of 1×10^–9 m/s is required to reproduce observed hydraulic-head and tritium profiles. Electronic Publication     

Evidence for Holocene Aeolian Activity at the Close of the Middle Bronze Age in the Eastern Carpathian Basin: Geoarchaeological Results from the Mureş River Valley,Romania

While extensive Pleistocene loess deposits have been identified across Eurasia, Holocene age loess (typically nonglaciogenic) is rarely recognized. We explore possible loess deposits in the Mureş River Valley of western Romania, providing a regional signal of increased aridity during the mid‐late Holocene. This proposed aridity may be responsible for the abandonment of Middle Bronze Age tell settlements along the major drainages of the eastern Carpathian Basin (Pannonian plain). This hypothesis centers on a proposed aeolian deposit (the “Pecica deposit”), a ca. 50–80 cm thick, relatively homogeneous, gray layer blanketing the top of the Bronze Age tell of Pecica—Şanţul Mare. Comparing the morphological, geochemical, and physical characteristics of this specific tell deposit with two representative profiles near the site containing glaciogenic calcareous loess and potential Holocene loess deposits developed in Chernozems, we find significant similarities to support this hypothesis. We then review various forms of proxy data published from elsewhere in Central and Eastern Europe suggesting a warming trend during this period. The temporal placement of the Pecica deposit is bracketed using diagnostic artifacts, radiocarbon dates, and the degree of soil development, suggesting a period of increased aridity likely occurring soon after the 17th century B.C.     

Resistivity of partially saturated Triassic Sandstone

The variation in resistivity with saturation of poorly cemented Triassic Sandstone samples from a site in the English Midlands has been measured. The measurements were obtained using an adapted four‐electrode technique, which utilizes conductive gelling agents between electrodes, avoiding the need to sputter electrodes directly on to samples – a difficult process with such friable samples. The measurements provide important information regarding the way in which resistivity varies with saturation in the Triassic Sandstone. The resulting variation in the observed resistivity versus saturation curves indicates the presence of significant pore‐scale variation between samples. Measurements have also been conducted on fully saturated samples. These indicate significant variation in the matrix conductivity between samples. The results have important implications for field‐scale monitoring of the unsaturated zone.     

Hybrid sediment gravity flow deposits – Classification, origin and significance

The deposits of subaqueous sediment gravity flows can show evidence for abrupt and/or progressive changes in flow behaviour making them hard to ascribe to a single flow type (e.g. turbidity currents, debris flows). Those showing evidence for transformation from poorly cohesive and essentially turbulent flows to increasingly cohesive deposition with suppressed turbulence ‘at a point’ are particularly common. They are here grouped as hybrid sediment gravity flow deposits and are recognised as key components in the lateral and distal reaches of many deep-water fan and basin plain sheet systems. Hybrid event beds contain up to five internal divisions: argillaceous and commonly mud clast-bearing sandstones (linked debrite, H3) overlie either banded sandstones (transitional flow deposits, H2) and/or structureless sandstones (high-density turbidity currents, H1), recording longitudinal and/or lateral heterogeneity in flow structure and the development of turbulent, transitional and laminar flow behaviour in different parts of the same flow. Many hybrid event beds are capped by a relatively thin, well-structured and graded sand–mud couplet (trailing low-density turbulent cloud H4 and mud suspension fallout H5). Progressive bed aggradation results in the deposits of the different flow components stacked vertically in the final bed. Variable vertical bed character is related to the style of up-dip flow transformations, the distance over which the flows can evolve and partition into rheological distinct sections, the extent to which different flow components mutually interact, and the rate at which the flows decelerate, reflecting position (lateral versus distal) and gradient changes. Hybrid beds may inherit their structure from the original failure, with turbidity currents outpacing debris flows from which they formed via partial flow transformation. Alternatively, they may form where sand-bearing turbidity currents erode sufficient substrate to force transformation of a section of the current to form a linked debris flow. The incorporation of mud clasts, their segregation in near-bed layers and their disintegration to produce clays that can dampen turbulence are inferred to be key steps in the generation of many hybrid flow deposits. The occurrence of such beds may therefore identify the presence of non-equilibrium slopes up-dip that were steep enough to promote significant flow incision. Where hybrid event beds dominate the entire distal fan stratigraphy, this implies either the system was continually out of grade in order to freight the flows with mud clasts and clays, or the failure mechanism and transport path repeatedly allowed transmission of components of the initial slumps distally. Where hybrid beds are restricted to sections representing fan initiation, or occur more sporadically within the fan deposits, this could indicate shorter episodes of disequilibrium, due to an initial phase of slope re-adjustment, or intermittent tectonically or gravity-driven surface deformation or supply variations. Alternatively, changes between conventional and hybrid event beds may record changes in the flow generation mechanism through time. Thus the vertical distribution of hybrid event beds may be diagnostic of the wider evolution of the fan systems that host them.