The Spačice eclogite: constraints on the P–T–t history of the Gföhl granulite terrane, Moldanubian Zone, Bohemian Massif

Summary In the Kutná Hora Complex, the Běstvina Formation, which is similar to Gf?hl granulite, contains eclogite that has escaped widespread retrograde recrystallization. The eclogite assemblage, garnet + omphacite + quartz + rutile ± plagioclase, yields an estimate for peak metamorphic conditions of 18–20 kbar and 835–935 °C, which is comparable to that determined from felsic granulite, 14–20 kbar and 900–1000 °C. Garnet in eclogite exhibits both prograde and retrograde compositional zoning, from which constraints on thermal history of the Gf?hl terrane can be derived by diffusion modelling. At 900 °C, a garnet grain of 800–1000 μm radius would homogenize in 7.5–11.7 million years, but the existence of compositional gradients on a length scale of 100–200 μm suggests that the duration of peak metamorphism may have been limited to ∼500,000 years. Diffusion modelling of retrograde zoning in garnet yields a cooling rate of 150–100 °C/m.y. for a radius of 800–1000 μm and initial temperature of 900 °C. The relatively brief duration of high-pressure/high-temperature metamorphism and rapid cooling and exhumation of the Gf?hl terrane may be a consequence of lithospheric delamination during Early Carboniferous collision of Bohemia (Teplá-Barrandia) and Moldanubia (Franke, 2000).     

U–Pb and Hf isotopic analysis of zircon in lower crustal xenoliths from the Navajo volcanic field: 1.4 Ga mafic magmatism and metamorphism beneath the Colorado Plateau

Zircon from lower crustal xenoliths erupted in the Navajo volcanic field was analyzed for U–Pb and Lu–Hf isotopic compositions to characterize the lower crust beneath the Colorado Plateau and to determine whether it was affected by ∼1.4 Ga granitic magmatism and metamorphism that profoundly affected the exposed middle crust of southwestern Laurentia. Igneous zircon in felsic xenoliths crystallized at 1.73 and 1.65 Ga, and igneous zircon in mafic xenoliths crystallized at 1.43 Ga. Most igneous zircon has unradiogenic initial Hf isotopic compositions (ɛ_Hf=+4.1–+7.8) and 1.7–1.6 Ga depleted mantle model ages, consistent with 1.7–1.6 Ga felsic protoliths being derived from “juvenile” Proterozoic crust and 1.4 Ga mafic protoliths having interacted with older crust. Metamorphic zircon grew in four pulses between 1.42 and 1.36 Ga, at least one of which was at granulite facies. Significant variability within and between xenoliths in metamorphic zircon initial Hf isotopic compositions (ɛ_Hf=−0.7 to +13.6) indicates growth from different aged sources with diverse time-integrated Lu/Hf ratios. These results show a strong link between 1.4 Ga mafic magmatism and granulite facies metamorphism in the lower crust and granitic magmatism and metamorphism in the exposed middle crust.     

Elastic properties of granulite facies rocks of Mahabalipuram, Tamil Nadu, India

Compressional and shear wave velocities and attenuation measurements have been carried out in some of the borehole samples of acidic, basic and intermediate granulites of Mahabalipuram, Tamil Nadu, India. The results have been obtained at ambient conditions using ‘time-of-flight’ pulse transmission technique at 1.0 MHz frequency. The results show linear relationships between velocity and density, and velocity and attenuation properties of the rocks. The acidic granulites show lower velocities and higher attenuation than the intermediate and basic granulites. The average values of the Poisson’s ratio of acidic, intermediate and basic granulites have been found to be 0.210, 0.241 and 0.279 respectively. The variations in velocities and attenuation in these low porosity crystalline rocks are found to be strongly influenced by their mineral composition. The laboratory velocity data (extrapolated to high pressure) of the present study and the published field velocity data from deep seismic sounding studies indicate that these granulite facies rocks may belong to mid-crustal depths only.     

Platinum-group element, Gold, Silver and Base Metal distribution in compositionally zoned sulfide droplets from the Medvezky Creek Mine, Noril’sk, Russia

Concentrations of Ag, Au, Cd, Co, Re, Zn and Platinum-group elements (PGE) have been determined in sulfide minerals from zoned sulfide droplets of the Noril’sk 1 Medvezky Creek Mine. The aims of the study were; to establish whether these elements are located in the major sulfide minerals (pentlandite, pyrrhotite, chalcopyrite and cubanite), to establish whether the elements show a preference for a particular sulfide mineral and to investigate the model, which suggests that the zonation in the droplets is caused by the crystal fractionation of monosulfide solid solution (mss). Nickel, Cu, Ag, Re, Os, Ir, Ru, Rh and Pd, were found to be largely located in the major sulfide minerals. In contrast, less than 25% of the Au, Cd, Pt and Zn in the rock was found to be present in these sulfides. Osmium, Ir, Ru, Rh and Re were found to be concentrated in pyrrhotite and pentlandite. Palladium and Co was found to be concentrated in pentlandite. Silver, Cd and Zn concentrations are highest in chalcopyrite and cubanite. Gold and platinum showed no preference for any of the major sulfide minerals. The enrichment of Os, Ir, Ru, Rh and Re in pyrrhotite and pentlandite (exsolution products of mss) and the low levels of these elements in the cubanite and chalcopyrite (exsolution products of intermediate solid solution, iss) support the mss crystal fractionation model, because Os, Ir, Ru, Rh and Re are compatible with mss. The enrichment of Ag, Cd and Zn in chalcopyrite and cubanite also supports the mss fractionation model these minerals are derived from the fractionated liquid and these elements are incompatible with mss and thus should be enriched in the fractionated liquid. Gold and Pt do not partition into either iss or mss and become sufficiently enriched in the final fractionated liquid to crystallize among the iss and mss grains as tellurides, bismithides and alloys. During pentlandite exsolution Pd appears to have diffused from the Cu-rich portion of the droplet into pentlandite.     

Planning for source water protection in Ontario

Ontario began developing a drinking water source protection planning process in 2000, after a rural community's water supply was contaminated by pathogens from agricultural runoff. An expert committee report has recommended legislating a new source protection “sphere of jurisdiction” for municipalities; however, no specific new municipal tools or authorities have been proposed as yet. This paper reports findings from an evaluation of the extent to which existing institutional arrangements for land use planning and water management facilitate or constrain source protection by municipalities. A case study of the Regional Municipality of Waterloo suggests there is the potential to link land use planning more strongly to water management through creative use of existing tools, forgoing the need for major institutional changes.