高压相变晶体化学:Ⅰ.高压下SiO_2物相氧硅离子的半径变化和迁移行为

高压下随着压力增加,氧化物及硅酸盐矿物中的阳离子会发生从配位数低的多面体向配位数高的多面体迁移的现象,这种迁移是由于阴阳离子半径的比值发生改变引起的。对SiO2在高压下形成的各种多形的氧和硅的离子半径进行计算,发现氧离子半径是随压力增加及相变的发生而逐渐缩小,但硅离子半径随压力增加及相变的发生而有明显的增大。这种现象可能是在高压下离子化合物逐渐向金属相化合物转变引起的。     

黏土岩温度-渗流-应力耦合特性试验与本构模型研究进展

高放废物处置库、垃圾填埋场等工程中常常涉及到温度场（T）、渗流场（H）和应力场（M）的耦合作用的问题。从试验和理论模型两个角度综述国内外黏土岩温度-渗流-应力耦合特性的研究进展,主要包括其传热特性、温度影响下的渗流特性、变形、强度、蠕变特性。在此基础上,重点分析了黏土岩水-热迁移模型以及热-力耦合本构模型的适应性。基于上述认识,通过试验研究了比利时Boom clay在温度作用下的强度、渗透性、蠕变性等特征。结果表明：随着温度升高,Boom clay的强度有所降低,渗透性显著增强,蠕变速率明显加快。提出了适用于Boom clay的THM耦合弹塑性损伤模型,计算结果验证了模型能合理反映温度的影响。最后,探讨了黏土岩THM耦合机理研究的不足和今后的研究方向。     

西南山区某铁路隧道口高位落石三维运动特征分析

西南山区某铁路隧道口上部广泛分布着高位危岩体,对下部隧道建(构)造物具有严重的威胁.采用Rockfall Analyst软件对该隧道上部五类不同尺寸的高位危岩体进行三维运动轨迹数值模拟,研究表明:研究区的高位危岩落石具有弹跳高度大、速度快、冲击能量高的特点;弹跳高度、运动速度与危岩落石的质量无关,冲击能量大小与落石质量...     

负温条件下激光位移传感器的标定

在使用激光位移传感器测试冻土位移中,由于测试现场环境条件恶劣,厂家给出的传感器线性度会降低,因此,需要对所有传感器在使用前应模拟使用时的环境条件重新进行标定。为验证激光位移传感器在冻土测试中的适用性,依据德国森萨帕特FT-50RLA220型激光位移传感器的结构、使用特点、技术指标,设计了由控温箱、标定支架、激光位移传感器、量块及数据采集装置组成的标定的装置,进行了不同负温条件下对激光位移传感器标定,并依据标定试验结果进行拟合参数修正,得到不同环境温度下的试验结果的线性度和迟滞特性。试验结果表明：不同的环境温度下,两个激光位移传感器与标准厂家测试曲线存在差异,不同负温条件下标定的两个激光位移传感器的拟合优度R²分别为0.999和1;线性度最大值分别为0.88%FS和0.32%FS。     

夏季不同天气背景和灌溉条件下绿洲地表辐射和能量平衡特征

利用2005年"绿洲系统能量和水分循环过程"野外观测实验(JTEX)资料,分析了夏季不同天气背景下的金塔绿洲小气候特征、辐射和能量平衡特征的日变化规律.结果表明:不同天气和土壤湿度背景下的辐射和能量平衡特征有较大差异.观测中发现有较大的能量不平衡差额,晴天时的能量亏损大于阴天的.     

河西内陆河流域水资源及其动态变化

The Qilian Mountains is the cradle of all inland rivers in the Hexi arid region. The mountain glaciers are an important water resources for this region. Changes of the mountain runoffs resulted from global climate warming will have important impacts on the development of human society and economy in the region. In this paper, the river runoffs from the Qilian Mountains and their dynamic changes are analyzed on the basis of the instrumental data of precipitation, air temperature, and discharge from the weather and hydrological stations in the study area. The results show that the annual change in the mountain runoffs is affected mainly by precipitation in the east of the region, but also by temeprature in the west of the region. There are some obvious regional differences in the influence of climatic change on surface runoffs in the Hexi region. River runoffs in the western part of the Hexi region have been increasing, whereas those in the eastern part have been decreasing. River runoffs in the central part such as the Heihe River, present a slow increasing trend, although it is not quite visible     

Effect of Shale Reservoir Characteristics on Shale Oil Movability in the Lower Third Member of the Shahejie Formation,Zhanhua Sag

To reveal the effect of shale reservoir characteristics on the movability of shale oil and its action mechanism in the lower third member of the Shahejie Formation(Es3l), samples with different features were selected and analyzed using N2 adsorption, high-pressure mercury injection capillary pressure(MICP), nuclear magnetic resonance(NMR), high-speed centrifugation, and displacement image techniques. The results show that shale pore structure characteristics control shale oil movability directly. Movable oil saturation has a positive relationship with pore volume for radius > 2 μm, as larger pores often have higher movable oil saturation, indicating that movable oil is present in relatively larger pores. The main reasons for this are as follows. The relatively smaller pores often have oil-wetting properties because of organic matter, which has an unfavorable effect on the flow of oil, while the relatively larger pores are often wetted by water, which is helpful to shale oil movability. The rich surface provided by the relatively smaller pores is beneficial to the adsorption of immovable oil. Meanwhile, the relatively larger pores create significant pore volume for movable oil. Moreover, the larger pores often have good pore connectivity. Pores and fractures are interconnected to form a complex fracture network, which provides a good permeability channel for shale oil flow. The smaller pores are mostly distributed separately;thus, they are not conducive to the flow of shale oil. The mineral composition and fabric macroscopically affect the movability of shale oil. Calcite plays an active role in shale oil movability by increasing the brittleness of shale and is more likely to form micro-cracks under the same stress background. Clay does not utilize shale oil flow because of its large specific surface area and its block effect. The bedding structure increases the large-scale storage space and improves the connectivity of pores at different scales, which is conducive to the movability of shale oil.     

不同产地绿松石无损检测及岩相结构特征研究

概述了绿松石的使用历史和产地来源。利用质子激发X射线荧光光谱（PIXE）、X射线衍射（XRD）及扫描电镜（SEM）技术对来自伊朗、湖北郧县和西藏等地的绿松石样品进行岩石矿物学特征分析，从成分组成方面探讨绿松石的呈色机理。结果显示，不同产地、不同质地绿松石的成分组成存在较大差别，但主成分含量基本一致；绿松石的颜色主要由其中CuO和Fe2O3的含量比值变化决定，比值由大至小，实现了绿松石颜色由天蓝色到绿色的转变。     

武当地块基性岩席群及其地质意义

侵位于武当地块内部的大量的板状为基性侵入体近年来一直被认为是800Ma左右发生的扬子古大陆裂解的重要依据。然而作者在武当地块北缘与西南部所做的1：5万地质填图以及相应的构造学和同位素年代学研究表明，它们与武当地块顺层伸展滑脱构造主滑脱面之顺层韧性一韧性变形带有密切的空间关系，是被褶皱了的岩席群。最新获得的岩体单颗粒锆石U－Pb年龄为401－407Ma，结合已有的地球化学研究成果，并考虑到邻区同时代碱性岩浆的侵位，作者认为，这套基性岩群代表了泥盆纪时南秦岭地区曾发生过大规模的上地幔岩浆的底侵作用，并因此导致南秦岭上部地壳的伸展减薄。     

FLAC 3D 强度折减理论在边坡稳定分析中的应用

FLAC3D 是岩土工程中广泛应用的软件。本文主要介绍强度折减理论的基本原理,利用基于强度折减法的FLAC3D 软件,对某高速公路K377 + 230 ～ K377 + 520 段滑坡体进行数值模拟。计算边坡在自重作用达到初始化平衡状态时,边坡的横向与竖直方向的应力与位移,分析出边坡的破坏机制为牵引式滑坡,通过强度折减理论计算出边坡的稳定系数为0. 97,由剪切应变增量云图确定边坡的滑动面。