Improved in situ gamma-ray transmission densitometer for marine sediments

The first-generation University of Illinois gamma-ray transmission densitometer, designed for the in situ measurement of sediment bulk density, was modified by incorporating in the detector probe (1) an Americium-241 alpha particle pulser and an anti-walk gain stabilization control to maintain better temperature stability and (2) a small power supply and a IC preamplifier to eliminate the need for a high-voltage coaxial cable between the detector and external signal conditioning electronics package. This second-generation Lehigh University system has been successfully deployed since 1971 in routine use from ships and submersibles in the Atlantic and Pacific Oceans and the Gulf of Mexico. Results are presented of system operations to (1) measure bulk density over the range of 1.2–1.8 Mg/m³ in the Hudson Canyon, (2) penetrate 1.9 m into the seafloor in the San Diego trough and, (3) be lowered to a water depth of 3.6 km in the Gulf of Mexico.     

Spectrophotometric pH measurement in estuaries using thymol blue and m-cresol purple

The conditional acid dissociation constants (pK_a′) of two sulfonephthalein dyes, thymol blue (TB) and m-cresol purple (mCP), were assessed throughout the estuarine salinity range (0<S<40) using a tris/tris–HCl buffer and spectrophotometric measurement. The salinity dependence of the pK_a′ of both dyes was fitted to the equations (25 °C, total proton pH scale, mol kg soln⁻¹):

The estimated accuracy of pH measurements using these calculated pK_a′ values is considered to be comparable to that possible with careful use of a glass electrode (±0.01 pH unit) but spectrophotometric measurements in an estuary have the significant advantage that it is not necessary to calibrate an electrode at different salinities. pH was measured in an estuary over a tidal cycle with a precision of ±0.0005 pH unit at high (S>30) salinity, and ±0.002 pH unit at low (S<5) salinity. The pH increased rapidly in the lower salinity ranges (0<S<15) but less rapidly at higher salinities.     

Spectrophotometric determination of pH in seawater off Taiaroa Head,Otago, New Zealand: Full-spectrum modelling and prediction of pCO2 levels

Accurate measurement of seawater pH has long been sought by marine chemists (for example: [Dickson, A.G. 1993a. The measurement of sea water pH. Marine Chemistry, 44, 131–142, Dickson, A.G. 1993b. pH buffers for sea water media based on the total hydrogen ion concentration scale. Deep-Sea Research, 40, 107–118; Zhang, 1996; Tapp, M., Hunter, K.A., Currie, K. and Macaskill, B. 2000. Apparatus of continuous-flow underway spectrophotometric measurement of surface water pH. Marine Chemistry 72(2–4), 193–202; Friis, K., Koetzinger, A., Wallace, D.W.R. 2004. Spectrophotometric pH measurement in the ocean: Requirements, design and testing of an autonomous charge-coupled device detector system. Limnology and Oceanography: Methods 2, 126–136]. Recently, such attempts have taken on greater significance as anthropogenic carbon dioxide emissions may create rapidly changing oceanic pH. Spectrophotometric techniques have been accepted generally as the best for determination of seawater pH. Here we report a new technique using thymol blue as the indicator dye and fitting the entire spectrum from 400 to 900 nm rather than measuring the absorbance values at only two or three points in the spectrum. This full-spectrum modelling enables a reduction in signal to noise over other techniques. In the laboratory, we find with seawater samples a pH precision increase of five-fold “within” a sample and seven-fold “between” samples when comparing the full spectrum to the three-point method of analysis [Zhang, H., Byrne, R.H. 1996. Spectrophotometric pH measurements of surface seawater at in-situ conditions: absorbance and protonation behaviour of thymol blue. Marine Chemistry 52, 17–25].     

Book reviews

REGIONAL GEOGRAPHY: Current Developments and Future Prospects edited by R. J. Johnston, J Hauer and G. A. Hoekveld. 14 × 22 cm, xiii and 216 pages. Routledge: London 1990 (ISBN 0 415 05247 5) $A89.95 (hard).

THE MAKING OF THE AMERICAN LANDSCAPE edited by M. P. Conzen. 19 × 25 cm, xvi and 433 pages. Unwin Hyman: Boston 1990 (ISBN 0 04 917010 4) $A59.95 (soft).

EASTERN EUROPE: An Historical Geography 1815–1945 by D. Turnock. 14 × 22 cm, ix and 357 pages. Routledge: London 1989 (ISBN 0 415 01269 4) $A115.00 (hard), distributed by the Law Book Co.

THE HUMAN GEOGRAPHY OF EASTERN EUROPE by D. Turnock. 14 × 22 cm, xii and 345 pages. Routledge: London 1989 (ISBN 0 415 00469 1) $A105.00 (hard), distributed by the Law Book Co.

A HISTORY OF THE PACIFIC ISLANDS by I. C. Campbell. 14 × 21 cm, 239 pages. University of Queensland Press: St Lucia 1990 (ISBN 0 7022 2291 7) $A34.95 (soft).

THE CORPORATE FIRM IN A CHANGING WORLD ECONOMY: Case Studies in the Geography of Enterprise edited by M. de Smidt and E. Wev‐er. 14 × 23 cm, xiv and 247 pages. Routledge: London 1990 (ISBN 0 415 03497 3) $A105.00 (hard).

THE CAPITALIST CITY: Global Restructuring and Community Politics by M. P. Smith and J. R. Feagin. 15 × 23 cm, 393 pages. Basil Black‐well: Oxford 1988 (ISBN 0 631 15182 6) £35 (hard).

CONFLICT AND CHANGE IN THE COUNTRYSIDE: Rural Society, Economy and Planning in the Developed World by G. M. Robinson. 15 × 23 cm, xxvi and 482 pages. Belhaven Press: London 1990 (ISBN 1 85293 043 8) £40.00 (hard); (ISBN 1 85293 044 6) £14.95 (soft).

ENVIRONMENTAL SCIENCE (Collins Reference Dictionary) by G. Jones, A. Robertson, J. Forbes and G. Hollier. 13 × 20 cm, vi and 473 pages. Collins: London 1990 (ISBN 0 00 434348 4) £5.95 (soft).

THE HUMAN IMPACT ON THE NATURAL ENVIRONMENT (Third Edition) by A. Goudie. 17 × 24 cm, xi and 388 pages. Blackwell: Oxford 1990 (ISBN 0 631 16164 3) $A39.95 (soft).

PATTERNS OF LIFE: Biogeography of a Changing World by H. W. Mielke. 19 × 24 cm, xiv and 370 pages. Unwin Hyman: London 1989 (ISBN 0 04 574032 1).     

The observed limb effect in Fraunhofer lines,I

The absolute limb effect is presented for Fei lines 3767 and 3969; for five Tii lines of multiplet 42 near 4535 and one Tiii line at 4534; two lines of Mgi, 4571 and 5172; two lines of Baii at 5854 and 6497. The scattered light of the McMath solar telescope is illustrated by several figures but not applied to the limb-effect observations. It is suggested that the supergravity shift at the limb is the result of scattering of the atoms in anisotropic velocity field.Operated by the Association of Universities for Research in Astronomy, Inc. (AURA) under cooperative agreement with the National Science Foundation.     

Crustal structure across the Grand Banks–Newfoundland Basin Continental Margin – II. Results from a seismic reflection profile

New multichannel seismic reflection data were collected over a 565 km transect covering the non-volcanic rifted margin of the central eastern Grand Banks and the Newfoundland Basin in the northwestern Atlantic. Three major crustal zones are interpreted from west to east over the seaward 350 km of the profile: (1) continental crust; (2) transitional basement and (3) oceanic crust. Continental crust thins over a wide zone (∼160 km) by forming a large rift basin (Carson Basin) and seaward fault block, together with a series of smaller fault blocks eastwards beneath the Salar and Newfoundland basins. Analysis of selected previous reflection profiles (Lithoprobe 85-4, 85-2 and Conrad NB-1) indicates that prominent landward-dipping reflections observed under the continental slope are a regional phenomenon. They define the landward edge of a deep serpentinized mantle layer, which underlies both extended continental crust and transitional basement. The 80-km-wide transitional basement is defined landwards by a basement high that may consist of serpentinized peridotite and seawards by a pair of basement highs of unknown crustal origin. Flat and unreflective transitional basement most likely is exhumed, serpentinized mantle, although our results do not exclude the possibility of anomalously thinned oceanic crust. A Moho reflection below interpreted oceanic crust is first observed landwards of magnetic anomaly M4, 230 km from the shelf break. Extrapolation of ages from chron M0 to the edge of interpreted oceanic crust suggests that the onset of seafloor spreading was ∼138 Ma (Valanginian) in the south (southern Newfoundland Basin) to ∼125 Ma (Barremian–Aptian boundary) in the north (Flemish Cap), comparable to those proposed for the conjugate margins.