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21.
22.
Molybdenum disulfide (MoS2), a layered transition-metal dichalcogenide, has been of special importance to the research community of geochemistry, materials
and environmental chemistry, and geotechnical engineering. Understanding the oxidation behavior and charge-transfer mechanisms
in MoS2 is important to gain better insight into the degradation of this mineral in the environment. In addition, understanding the
insertion of metals into molybdenite and evaluation of charge-transfer mechanism and dynamics is important to utilize these
minerals in technological applications. Furthermore, a detailed investigation of thermal oxidation behavior and metal-insertion
will provide a basis to further explore and model the mechanism of adsorption of metal ions onto geomedia. 相似文献
23.
Several studies have suggested that geostatistical techniques could be employed to reduce overall transactions costs associated
with contracting for soil C credits by increasing the efficacy of sampling protocols used to measure C-credits. In this paper,
we show how information about the range of spatial autocorrelation can be used in a measurement scheme to reduce the size
of the confidence intervals that bound estimates of the mean number of C-credits generated per hectare. A tighter confidence
interval around the mean number of C-credits sequestered could increase producer payments for each hectare enrolled in a contract
to supply C-credits. An empirical application to dry land cropping systems in three regions of Montana shows that information
about the spatial autocorrelation exhibited by soil C could be extremely valuable for reducing transactions costs associated
with contracts for C-credits but the benefits are not uniform across all regions or cropping systems. Accounting for spatial
autocorrelation greatly reduced the standard errors and narrowed the confidence intervals associated with sample estimates
of the mean number of C-credits produced per hectare. For the payment mechanism considered in this paper, tighter confidence
intervals around the mean number of C-credits created per hectare enrolled could increase producer payments by more than 100
percent under a C-contract. 相似文献
24.
A Parameterization of Dry Thermals and Shallow Cumuli for Mesoscale Numerical Weather Prediction 总被引:2,自引:1,他引:2
Julien Pergaud Valéry Masson Sylvie Malardel Fleur Couvreux 《Boundary-Layer Meteorology》2009,132(1):83-106
For numerical weather prediction models and models resolving deep convection, shallow convective ascents are subgrid processes
that are not parameterized by classical local turbulent schemes. The mass flux formulation of convective mixing is now largely
accepted as an efficient approach for parameterizing the contribution of larger plumes in convective dry and cloudy boundary
layers. We propose a new formulation of the EDMF scheme (for Eddy Diffusivity\Mass Flux) based on a single updraft that improves
the representation of dry thermals and shallow convective clouds and conserves a correct representation of stratocumulus in
mesoscale models. The definition of entrainment and detrainment in the dry part of the updraft is original, and is specified
as proportional to the ratio of buoyancy to vertical velocity. In the cloudy part of the updraft, the classical buoyancy sorting
approach is chosen. The main closure of the scheme is based on the mass flux near the surface, which is proportional to the
sub-cloud layer convective velocity scale w
*. The link with the prognostic grid-scale cloud content and cloud cover and the projection on the non- conservative variables
is processed by the cloud scheme. The validation of this new formulation using large-eddy simulations focused on showing the
robustness of the scheme to represent three different boundary layer regimes. For dry convective cases, this parameterization
enables a correct representation of the countergradient zone where the mass flux part represents the top entrainment (IHOP
case). It can also handle the diurnal cycle of boundary-layer cumulus clouds (EUROCS\ARM) and conserve a realistic evolution
of stratocumulus (EUROCS\FIRE). 相似文献
25.
In this study, the variation of radio refractivity with respect to temperature and moisture is analyzed. Also, the effects of vertical gradients in temperature and moisture on the propagation paths of electromagnetic waves of weather radar are examined for several sites across the United States using several years of sounding data from the National Weather Service. The ray path is important for identifying storm characteristics and for properly using the radar data in initializing numerical weather prediction models. It is found that during the warm season the radio refractivity gradient is more sensitive to moisture gradients than to temperature gradients. Ray paths from the commonly accepted vertical ray path model are compared to a ray path computed from a stepwise ray tracing algorithm using data from actual soundings. For the sample of about 16 000 soundings examined, we find that only a small fraction of the ray paths diverge significantly from those calculated using a ray path model based on the US Standard Atmosphere. While the problem of ray dueting in the presence of a temperature inversion is fairly well known, we identify the presence of a strong vertical moisture gradient as the culprit in the majority of the cases where significant deviations occurred. 相似文献
26.
Veli‐Pekka Salonen Julien Moreau Outi Hyttinen Kari O. Eskola 《Boreas: An International Journal of Quaternary Research》2014,43(3):627-638
Finnish Lapland is known as an area where numerous sites with sediments from Pleistocene glacial and interglacial periods occur. Recent sedimentological observations and dating call for reinterpretation of the record, which shows a complicated Mid‐Weichselian ice‐sheet evolution within the ice‐divide zone. Here, a large, previously unstudied section from a former Hannukainen iron mine was investigated sedimentologically and dated with optically stimulated luminescence (OSL). Ten sedimentary units were identified displaying a variety of depositional environments (glacial, glaciolacustrine, fluvial and aeolian). They are all – except for the lowermost, deeply weathered till – interpreted to be of Mid‐ or Late Weichselian/Holocene age. Five OSL samples from fluvial sediments give ages ranging from 55 to 35 ka, indicating two MIS 3 ice‐free intervals of unknown duration. The Mid‐Weichselian interstadial was interrupted by a re‐advance event, which occurred later than 35 ka and caused glaciotectonic deformation, folding and stacking of older sediments. This new evidence emphasizes the importance of the Kolari area when unravelling the complex Late Pleistocene glacial history of northern Finland and adjacent regions. 相似文献
27.
Segmentation and kinematics of the North America‐Caribbean plate boundary offshore Hispaniola 下载免费PDF全文
Sylvie Leroy Nadine Ellouz‐Zimmermann Jordane Corbeau Frédérique Rolandone Bernard Mercier de Lépinay Bertrand Meyer Roberte Momplaisir José‐Luis Granja Bruña Anne Battani Céline Baurion Evgueni Burov Valérie Clouard Rémy Deschamps Christian Gorini Youri Hamon Manfred Lafosse Jottin Leonel Laetitia Le Pourhiet Pilar Llanes Estrada Nicolas Loget Francis Lucazeau Daniel Pillot Jeffrey Poort Kevin R. Tankoo José‐Luis Cuevas José‐Fernando Alcaide Claude Jean Poix Alfonso Muñoz‐Martin Serge Mitton Yamil Rodriguez Julien Schmitz Leonardo Seeber Andres Carbo‐Gorosabel Santiago Muñoz 《地学学报》2015,27(6):467-478
We explored the submarine portions of the Enriquillo–Plantain Garden Fault zone (EPGFZ) and the Septentrional–Oriente Fault zone (SOFZ) along the Northern Caribbean plate boundary using high‐resolution multibeam echo‐sounding and shallow seismic reflection. The bathymetric data shed light on poorly documented or previously unknown submarine fault zones running over 200 km between Haiti and Jamaica (EPGFZ) and 300 km between the Dominican Republic and Cuba (SOFZ). The primary plate‐boundary structures are a series of strike‐slip fault segments associated with pressure ridges, restraining bends, step overs and dogleg offsets indicating very active tectonics. Several distinct segments 50–100 km long cut across pre‐existing structures inherited from former tectonic regimes or bypass recent morphologies formed under the current strike‐slip regime. Along the most recent trace of the SOFZ, we measured a strike‐slip offset of 16.5 km, which indicates steady activity for the past ~1.8 Ma if its current GPS‐derived motion of 9.8 ± 2 mm a?1 has remained stable during the entire Quaternary. 相似文献
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29.
Keith E. Schilling Philip W. Gassman Catherine L. Kling Todd Campbell Manoj K. Jha Calvin F. Wolter Jeffrey G. Arnold 《水文研究》2014,28(8):3314-3325
Effects of agricultural land management practices on surface runoff are evident at local scales, but evidence for watershed‐scale impacts is limited. In this study, we used the Soil and Water Assessment Tool model to assess changes in downstream flood risks under different land uses for the large, intensely agricultural, Raccoon River watershed in Iowa. We first developed a baseline model for flood risk based on current land use and typical weather patterns and then simulated the effects of varying levels of increased perennials on the landscape under the same weather patterns. Results suggest that land use changes in the Raccoon River could reduce the likelihood of flood events, decreasing both the number of flood events and the frequency of severe floods. The duration of flood events were not substantially affected by land use change in our assessment. The greatest flood risk reduction was associated with converting all cropland to perennial vegetation, but we found that converting half of the land to perennial vegetation or extended rotations (and leaving the remaining area in cropland) could also have major effects on reducing downstream flooding potential. We discuss the potential costs of adopting the land use change in the watershed to illustrate the scale of subsidies required to induce large‐scale conversion to perennially based systems needed for flood risk reduction. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
30.