Amino acid analyses of Antarctic CM2 meteorites using liquid chromatography‐time of flight‐mass spectrometry

Abstract— Amino acid analyses of the Antarctic CM2 chondrites Allan Hills (ALH) 83100 and Lewis Cliff (LEW) 90500 using liquid chromatography‐time of flight‐mass spectrometry (LC‐ToF‐MS) coupled with UV fluorescence detection revealed that these carbonaceous meteorites contain a suite of indigenous amino acids not present in Antarctic ice. Several amino acids were detected in ALH 83100, including glycine, alanine, β‐alanine, γ‐amino‐n‐butyric acid (γ‐ABA), and α‐aminoisobutyric acid (AIB) with concentrations ranging from 250 to 340 parts per billion (ppb). In contrast to ALH 83100, the CM2 meteorites LEW 90500 and Murchison had a much higher total abundance of these amino acids (440–3200 ppb). In addition, ALH 83100 was found to have lower abundances of the α‐dialkyl amino acids AIB and isovaline than LEW 90500 and Murchison. There are three possible explanations for the depleted amino acid content in ALH 83100: 1) amino acid leaching from ALH 83100 during exposure to Antarctic ice meltwater, 2) a higher degree of aqueous alteration on the ALH 83100 parent body, or 3) ALH 83100 originated on a chemically distinct parent body from the other two CM2 meteorites. The high relative abundance of ?‐amino‐n‐caproic acid (EACA) in the ALH 83100 meteorite as well as the Antarctic ice indicates that Nylon‐6 contamination from the Antarctic sample storage bags may have occurred during collection.     

Opening angles, Lorentz factors and confinement of X-ray binary jets

We present a collation of the available data on the opening angles of jets in X-ray binaries, which in most cases are small (≲10°). Under the assumption of no confinement, we calculate the Lorentz factors required to produce such small opening angles via the transverse relativistic Doppler effect. The derived Lorentz factors, which are in most cases lower limits, are found to be large, with a mean >10, comparable to those estimated for active galactic nuclei (AGN) and much higher than the commonly assumed values for X-ray binaries of 2–5. Jet power constraints do not, in most cases, rule out such high Lorentz factors. The upper limits on the opening angles show no evidence for smaller Lorentz factors in the steady jets of Cygnus X-1 and GRS 1915+105. In those sources in which deceleration has been observed (notably  XTE J1550−564  and Cygnus X-3), some confinement of the jets must be occurring, and we briefly discuss possible confinement mechanisms. It is however possible that all the jets could be confined, in which case the requirement for high bulk Lorentz factors can be relaxed.     

Statistical description of the radiation field in a homogeneous medium of finite optical thickness

The problem of finding statistical averages which characterize the radiation field in a semi-infinite atmosphere has been discussed by the author in a series of papers. In this paper some of the results obtained there are generalized to media of finite optical thickness. The average number of scattering events undergone by a photon during its random walk in an atmosphere and the average time required for this are determined. Three different types of averages are considered, depending on the photon characteristics over which the averages are taken. Special attention is devoted to the asymptotic behavior of these quantities for media with large optical depths taking the influence of continuum absorption into account. __________ Translated from Astrofizika, Vol. 49, No. 2, pp. 263–275 (May 2006).     

The HNCO ring in the Sgr B2 region

The large-scale structure associated with the 2′N HNCO peak in Sgr B2 [Minh, Y.C., Haikala, L., Hjalmarson, Å., Irvine, W.M., 1998. ApJ 498, 261 (Paper I)] has been investigated. A ring-like morphology of the HNCO emission has been found; this structure may be colliding with the Principal Cloud of Sgr B2. This “HNCO Ring” appears to be centered at (l,b) = (0.7°,−0.07°), with a radius of 5 pc and a total mass of 1.0 × 10⁵ to 1.6 × 10⁶ M. The expansion velocity of the Ring is estimated to be 30–40 km s⁻¹, which gives an expansion time scale of 1.5 × 10⁵ year. The morphology suggests that collision between the Ring and the Principal Cloud may be triggering the massive star formation in the Sgr B2 cloud sequentially, with the latest star formation taking place at the 2′N position. The chemistry related to HNCO is not certain yet, but if it forms mainly via reaction with the evaporated OCN⁻ from icy grain mantles, the observed enhancement of the HNCO abundance can be understood as resulting from shocks associated with the collision between the Principal Cloud and the expanding HNCO Ring.     

Effect of signal contamination in matched-filter detection of the signal on a cluttered background

To derive a matched filter for detecting a weak target signal in a hyperspectral image, an estimate of the band-to-band covariance of the target-free background scene is required. We investigate the effects of including some of the target signal in the background scene. Although the covariance is contaminated by the presence of a target signal (there is increased variance in the direction of the target signature), we find that the matched filter is not necessarily affected. In fact, if the variation in plume strength is strictly uncorrelated with the variation in background spectra, the matched filter and its signal-to-clutter ratio (SCR) performance will not be impaired. While there is little a priori reason to expect significant correlation between the plume and the background, there usually is some residual correlation, and this correlation leads to a suppressing effect that limits the SCR obtainable even for strong plumes. These effects are described and quantified analytically, and the crucial role of this correlation is illustrated with some numerical examples using simulated plumes superimposed on real hyperspectral imagery. In one example, we observe an order-of-magnitude loss in SCR for a matched filter based on the contaminated covariance.