Non-local memory effects of the electromotive force by fluid motion with helicity and two-dimensional periodicity

In mean-field dynamo theory, the electromotive force term 〈u′ × B′〉 due to small-scale fields connects the small-scale magnetic field with the large-scale field. This term is usually approximated as the α-effect, assumed to be instantaneous in time and local in space. However, the approximation is valid only when the magnetic Reynolds number Rm is much less than unity, and is inappropriate when Rm ? 1, which is the condition satisfied in the Earth's core or solar convection zone. We introduce a function φ _qr as a non-local and non-instantaneous generalization of the usual α-effect and examine its behaviour as a function of Rm in the range 1/64 ≤ Rm ≤ 10 for a kinematic dynamo model. We use the flow of G.O. Roberts 1972 Roberts, GO. 1972. Dynamo action of fluid motions with two-dimensional periodicity. Phil. Trans. Roy. Soc. London Ser. A, 271: 411–454. [Crossref], [Web of Science ®] , [Google Scholar] (Phil, Trans. Roy. Soc. London Ser. A, 1972, 271, 411–454), which is steady and has non-zero helicities and two-dimensional periodicity. As a result, we identify three regions in Rm space according to the behaviour of the function φ _qr : (i) Rm ? 1/4, where the function φ _qr is local and instantaneous and can be approximated by the traditional α and β effects, (ii) 1/4 ? Rm ? 4, where the deviation from the traditional α and β effects increases and non-localness and non-instantaneousness increase, and (iii) Rm ? 4, where boundary layers develop fully and non-localness and non-instantaneousness are prominent. We show that the non-local memory effect for Rm ? 4 strongly affects the dynamo action and explains an observed augmentation of the growth rate in the dispersion relation. The results imply that the non-local memory effect of the electromotive force should be important in the geodynamo or the solar dynamo.     

Distribution of nitrous oxide dissolved in water masses in the eastern subtropical North Pacific and its origin inferred from isotopomer analysis

N₂O concentration and its isotopomer ratios were measured over a wide area from San Diego to Honolulu in the eastern subtropical North Pacific (ESNP). Waters in the study area had an N₂O maximum (38.2–50.5 nmol kg^?1) at 600–1000 m depth, which is similar to the profiles obtained previously in other areas in the North Pacific. We separated the seawater into five water masses (two for the surface layer, two for the middle layer, and one for the deep layer) and deduced N₂O production–consumption mechanisms in each water body by use of N₂O isotopomer ratios. The results showed that the mechanisms differ slightly among water masses. In the “coastal” surface layer, N₂O is produced by nitrification (NH₂OH oxidation). In the “open ocean” surface layer, it is produced mainly by nitrifier denitrification and to a lesser extent by nitrification under substrate-limited conditions. In both “upwelling” and “open ocean” middle layers it is produced mainly by denitrification and to a lesser extent by nitrifier denitrification. It is also partly reduced. In the deep layer, it is produced predominantly by denitrification with partial reduction. In this way, isotopomers aid elucidation of production–consumption mechanisms of N₂O in the sea even though the mechanisms cannot always be ascertained.     

中国老挝跨境生物多样性保护区的林地变化(英文)

This paper analyzed forest land use change in Trans-Boundary Laos-China Biodiversity Conservation Area which is called Namha National Biodiversity Conservation Areas (Namha NBCAs), with 1992 and 2002 TM (ETM). Based on GIS and statistical methods, the intensity, state index of land use change and transfer matrix were used to study spatiotemporal land use change in the region. The results showed that the area of forest land decreased greatly, also the area of bamboo and grassland decreased. The other way round, the area of unstocked forest, slash and burn and rice paddy land increased. As a whole, the intensity of forest land change was higher, but others were lower. From the transfer matrix, most of the forest land changed into unstocked forest and urban area, some to slash and burn. The grassland and bamboo were mainly transferred to forest and unstocked forest. The unstocked forest land mostly came from forest land and grassland. It was showed there were three main causes of the land use change namely: opium poppy cultivation, rubber plantation and also ecotourism activities and finally some policies were developed in order to address the land use change in the study areas.     

Adsorption of tributyltin by tributyltin resistant marine Pseudoalteromonas sp. cells

The isolate, Pesudoalteromonas sp. TBT1, could grow to overcome the toxicity of tributyltin chloride (TBTCl) up to 30 microM in the absence of Cl(-) in the medium until the cells reached an exponential phase of growth. The viability, however, was reduced after the cells reached a stationary phase. The degradation products, such as dibutyltin (DBT) and monobutyltin (MBT), were not detected in the growth medium, indicating that the isolate has no ability to degrade TBT into less toxic DBT and MBT. Up to about 10(7.5) TBT molecules were adsorbed by a single cell. The observation of morphological changes with an electron microscope showed that the cell surface became wrinkled after exposure to the lethal concentration of 10 mM TBTCl. These results indicate that the resistance of the isolate toward the toxicity of TBTCl is not related to the unique cell surface, which seems to play an important role in preventing the diffusion of TBTCl into the cytoplasm.     

Adsorption of tributyltin by tributyltin resistant marine Pseudoalteromonas sp. cells

The isolate, Pesudoalteromonas sp. TBT1, could grow to overcome the toxicity of tributyltin chloride (TBTCl) up to 30 μM in the absence of Cl⁻ in the medium until the cells reached an exponential phase of growth. The viability, however, was reduced after the cells reached a stationary phase. The degradation products, such as dibutyltin (DBT) and monobutyltin (MBT), were not detected in the growth medium, indicating that the isolate has no ability to degrade TBT into less toxic DBT and MBT. Up to about 10^7.5 TBT molecules were adsorbed by a single cell. The observation of morphological changes with an electron microscope showed that the cell surface became wrinkled after exposure to the lethal concentration of 10 mM TBTCl. These results indicate that the resistance of the isolate toward the toxicity of TBTCl is not related to the unique cell surface, which seems to play an important role in preventing the diffusion of TBTCl into the cytoplasm.     

Interactions of uranium with bacteria and kaolinite clay

We assessed the accumulation of uranium (VI) by a bacterium, Bacillus subtilis, suspended in a slurry of kaolinite clay, to elucidate the role of microbes on the mobility of U(VI). Various mixtures of bacteria and the koalinite were exposed to solutions of 8 × 10^− 6 M- and 4 × 10^− 4 M-U(VI) in 0.01 M NaCl at pH 4.7. After 48 h, the mixtures were separated from the solutions by centrifugation, and treated with a 1 M CH₃COOK for 24 h to determine the associations of U within the mixture. The mixture exposed to 4 × 10^− 4 M U was analyzed by transmission electron microscope (TEM) equipped with EDS. The accumulation of U by the mixture increased with an increase in the amount of B. subtilis cells present at both U concentrations. Treatment of kaolinite with CH₃COOK, removed approximately 80% of the associated uranium. However, in the presence of B. subtilis the amount of U removed was much less. TEM–EDS analysis confirmed that most of the U removed from solution was associated with B. subtilis. XANES analysis of the oxidation state of uranium associated with B. subtilis, kaolinite, and with the mixture containing both revealed that it was present as U(VI). These results suggest that the bacteria have a higher affinity for U than the kaolinite clay mineral under the experimental conditions tested, and that they can immobilize significant amount of uranium.     

Chemistry and Sulfur Isotopes of the Chert-Clastic Sequence Surrounding the Kajika Massive Sulfide Ores at the Ashio Copper Mine, Ashio Terrane, Central Japan

Abstract. Chemical and sulfur isotopic compositions were obtained for a series of rocks within the chert‐clastic sequence surrounding the Kajika massive sulfide ore horizon at Shibukawasawa in the Ashio copper‐mining district, Ashio Terrane, central Japan. The sequence is lithologically classified into three units: chert, siliceous shale with basic volcanics, and sandstone‐shale, in ascending stratigraphic order. The Kajika ore horizon corresponds to the lowermost part of the unit that contains siliceous shale with basic volcanics. The rocks around the Kajika ore horizon are enriched in P₂O₅ (max. 0.22 %), Ba (max. 2400 ppm), Cu (595 ppm), V (323 ppm), Pb (168 ppm), Zn (124 ppm), and Mo (24 ppm) in siliceous shale; and Ba (4220 ppm), Zr (974 ppm), Cr (718 ppm), Ni (492 ppm), V (362 ppm), Zn (232 ppm), Nb (231 ppm), and Co (71 ppm) in the basic volcanics. The siliceous shale is enriched in a number of redox‐sensitive elements such as Cu, V, Pb, Zn, and Mo, which are known to be enriched in black shale and anoxic and hydrothermal sediments. The δ³⁴S values of sulfides in the chert and sandstone‐shale lie in the range of 0±2 %, and those in the siliceous shale range from ‐5 to ‐14 %. The measured δ³⁴S values in the basic volcanics are ‐0.3, ‐2.7, and ‐31.5 %. These heavier δ³⁴S signatures (around 0 %) recorded throughout the sequence indicate that the rocks formed under anoxic bottom‐water conditions. Slightly lighter δ³⁴S values recorded in siliceous shale might reflect significant mixing of sulfides that formed by sulfate‐reducing bacteria in an overlying oxic environment. The long‐term duration of anoxic conditions indicated by the heavier δ³⁴S signature is considered to have played an important role in protecting the Kajika sulfide ores from oxidative decomposition and preserving the ores in sedimentary accumulations.