Chemical and mineralogical compositions of two grains recovered from asteroid Itokawa

Two silicate grains (RB‐QD04‐0049 and RA‐QD02‐0064, whose estimated masses are 0.050 μg and 0.048 μg, respectively) recovered from the asteroid Itokawa by the Hayabusa spacecraft were studied for their mineralogical characteristics by synchrotron X‐ray diffraction and synchrotron X‐ray microtomography and further analyzed for their bulk chemical compositions by instrumental neutron activation analysis (INAA). According to X‐ray tomography, RB‐QD004‐0049 is composed of olivine, high‐Ca pyroxene, plagioclase, Ca‐phosphate, and troilite, whereas RA‐QD002‐0064 entirely consists of olivine. INAA data are consistent with these mineral compositions except for rare earth elements (REEs). Although the grain RB‐QD004‐0049 contains measurable REEs, which seems to be consistent with the presence of Ca‐phosphate, their abundances are anomalously high. Very low abundance of Co implies less than 0.1 mass% of metals in these two grains by calculation, which is in contrast to the result for the previously analyzed grain RA‐QD02‐0049 (Ebihara et al., 2011). FeO/Sc ratios of the grains fall within the range of those for ordinary chondrite olivines, implying that these grains are extraterrestrial in origin. FeO/MnO ratios also confirm this conclusion and further suggest that the Hayabusa grains analyzed in this study are similar to material found in LL chondrites rather than CK chondrites although olivines from LL and CK chondrites have similar Fa# (molar% of Fe relative to [Fe+Mg] in olivine) (~30) to those of the Hayabusa grains including the two grains analyzed in this study.     

Energy balance above a boreal coniferous forest: a difference in turbulent fluxes between snow‐covered and snow‐free canopies

To evaluate the interactive effects of snow and forest on turbulent fluxes between the forest surface and the atmosphere, the surface energy balance above a forest was measured by the eddy correlation method during the winter of 1995–1996. The forest was a young coniferous plantation comprised of spruce and fir. The study site, in Sapporo, northern Japan, had heavy and frequent snowfalls and the canopy was frequently covered with snow during the study period. A comparison of the observed energy balance above the forest for periods with and without a snow‐covered canopy and an analysis using a single‐source model gave the following results: during daytime when the canopy was covered with snow, the upward latent heat flux was large, about 80% of the net radiation, and the sensible heat flux was positive but small. On the other hand, during daytime when the canopy was dry and free from snow, the sensible heat flux was dominant and the latent heat flux was minor, about 10% of the net radiation. To explain this difference of energy partition between snow‐covered and snow‐free conditions, not only differences in temperature but also differences in the bulk transfer coefficients for latent heat flux were necessary in the model. Therefore, the high evaporation rate from the snow‐covered canopy can be attributed largely to the high moisture availability of the canopy surface. Evaporation from the forest during a 60‐day period in midwinter was estimated on a daily basis as net radiation minus sensible heat flux. The overall average evaporation during the 60‐day period was 0·6 mm day⁻¹, which is larger than that from open snow fields. Copyright © 1999 John Wiley & Sons, Ltd.     

Siderophile element characteristics of acapulcoite–lodranites and winonaites: Implications for the early differentiation processes of their parent bodies

We have studied magnetic fractions of five acapulcoites, three lodranites, and two winonaites to investigate chemical compositions of their precursor materials and metallic partial melting processes occurring on their parent bodies. One winonaite metal is similar in composition to low Au, low Ni IAB iron subgroup, indicating genetic relationship between them. Magnetic fractions of chondrule‐bearing acapulcoite and winonaite have intermediate chemical compositions of metals between H chondrites and EL chondrites. This fact indicates that the precursor materials of acapulcoite–lodranites and winonaites were similar to H and/or EL chondrites in chemical compositions. Magnetic fractions in acapulcoite–lodranites have a large variety of chemical compositions. Most of them show enrichments of W, Re, Ir, Pt, Mo, and Rh, and one of them shows clear depletion in Re and Ir relative to those of chondrule‐bearing acapulcoite. Chemical compositional variations among acapulcoite–lodranite metals cannot be explained by a single Fe‐Ni‐S partial melting event, but a two‐step partial melting model can explain it.     

Crystallization temperature determination of Itokawa particles by plagioclase thermometry with X‐ray diffraction data obtained by a high‐resolution synchrotron Gandolfi camera

The crystallization temperatures of Itokawa surface particles recovered by the space probe Hayabusa were estimated by a plagioclase geothermometer using sodic plagioclase triclinicity. The Δ131‐index required for the thermometer, which is the difference in X‐ray diffraction peak positions between the 131 and 11 reflections of plagioclase, was obtained by a high‐resolution synchrotron Gandolfi camera developed for the third generation synchrotron radiation beamline, BL15XU at SPring‐8. Crystallization temperatures were successfully determined from the Δ131‐indices for four particles. The observed plagioclase crystallization temperatures were in a range from 655 to 660 °C. The temperatures indicate crystallization temperatures of plagioclases in the process of prograde metamorphism before the peak metamorphic stage.     

Measurements of Rare Earth Element and Other Element Mass Fractions in Environmental Reference Materials (NIST SRM 1646a,NIST SRM 1400, IAEA‐395 and IAEA‐450) by INAA,ICP‐AES and ICP‐MS

INAA, ICP‐AES and ICP‐MS were used to elementally characterise four environmental reference materials – NIST SRM 1646a (Estuarine Sediment), NIST SRM 1400 (Bone Ash), IAEA‐395 (Urban Dust) and IAEA‐450 (Algae). An analytical scheme consisting of the three methods was first applied to NIST SRM 1646a to validate the methodology because it has been extensively analysed and has certified values for many elements. With repeated analyses of NIST SRM 1646a, the accuracy and measurement repeatability of the data obtained were evaluated based on two statistical calculations (zeta‐score and Horwitz ratio) and were observed to be good enough for the analytical scheme to be applied to similar sorts of environmental/geochemical samples. Applying the same approach to NIST SRM 1400, IAEA‐395 and IAEA‐450, enabled mass fractions of 29, 38 and 28 elements to be determined, respectively. Among these results, the data for rare earth elements are of particular interest, not only for IAEA‐450 but also for the other three reference samples. The data for Pr, Gd, Dy, Ho, Er and Tm in NIST SRM 1646a are newly reported in this study. By using small test portions (< 100 mg) for NIST SRM 1646a and IAEA‐395, and recommended minimum amounts for NIST SRM 1400 and IAEA‐450, sample homogeneity was evaluated.     

Morphology,structure and flow phases in soil pipes developing in forested hillslopes underlain by a Quaternary sand–gravel formation,Hokkaido, northern main island in Japan

Preferential flow pathways, such as soil pipes, are usually present in the soil of slopes. Subsurface flow through the soil pipes affects the subsurface drainage system and is responsible for sediment removal from slopes. However, a record of the inner structure of soil pipes has rarely been reported for slopes. A fibrescope examination of the morphology and flow phases in soil pipes in hillslopes underlain by a Quaternary sand–gravel formation provided the following information: the main pores of the soil pipes ran mostly parallel with the slope gradient; the cross‐sections of the soil pipes were approximately circular; and occurred on a few occasions; with some triple junctions being present. In addition, both full flow and partly full‐depth conditions occurred simultaneously in the soil pipe. The full flow condition has long been used in hydrological studies to model the pipe flow mechanism. Both the full flow condition and the partly full‐depth condition, however, must be examined closely in order to evaluate the subsurface hydrology in heterogeneous soil and the hydrogeomorphological processes of subsurface hydraulic erosion. Copyright © 2000 John Wiley & Sons, Ltd.     

Trace metals in Japanese eel Anguilla japonica in relation to ecological migratory types and growth stages

In order to understand the metal concentrations in Japanese eel Anguilla japonica, nine elements were analyzed in the livers of different migratory types of eels collected from Tokushima region (south Japan). Migratory types were defined by examining the Sr:Ca ratio in otoliths. The results showed that there were significant differences in V, Cr, Cd, and Pb concentrations among the migratory types. Mature-sea-eels show a higher risk of metal accumulation than other migratory types of eels, and the concentrations of Mn, Cu, and Zn in mature eels were significantly higher than those in immature eels. The study suggests that the eel liver is a valuable bioindicator for trace metals; however, when using the eel as a bioindicator to reveal the pollutants in aquatic systems, life history analysis should be carried out for accurate interpretation of the results.