Behavior of manganese in aqua-benthic environment in the Hiro Bay

The horizontal and vertical distributions of manganese in sea water, interstitial water and sediments in the Hiro Bay, Seto Inland Sea, Japan, have been investigated. The outflow from a pulp mill is the primary source of manganese in this bay. The industrial waste water contained 0.19 mg l^–1 of manganese, mostly in a dissolved form. This manganese diffused out both horizontally and vertically into the surrounding sea water. The content of manganese in the liquid and solid phases in the sediments, however, are inverse with that in the sea water; namely the lowest concentration of manganese in the sediments was observed at the station near the outfall and manganese concentration increased with the distance from the outfall.     

Seismological features of island arc crust as inferred from recent seismic expeditions in Japan

Crustal studies within the Japanese islands have provided important constraints on the physical properties and deformation styles of the island arc crust. The upper crust in the Japanese islands has a significant heterogeneity characterized by large velocity variation (5.5–6.1 km/s) and high seismic attenuation (Qp=100–400 for 5–15 Hz). The lateral velocity change sometimes occurs at major tectonic lines. In many cases of recent refraction/wide-angle reflection profiles, a “middle crust” with a velocity of 6.2–6.5 km/s is found in a depth range of 5–15 km. Most shallow microearthquakes are concentrated in the upper/middle crust. The velocity in the lower crust is estimated to be 6.6–7.0 km/s. The lower crust often involves a highly reflective zone with less seismicity, indicating its ductile rheology. The uppermost mantle is characterized by a low Pn velocity of 7.5–7.9 km/s. Several observations on PmP phase indicate that the Moho is not a sharp boundary with a distinct velocity contrast, but forms a transition zone from the upper mantle to the lower crust. Recent seismic reflection experiments revealed ongoing crustal deformations within the Japanese islands. A clear image of crustal delamination obtained for an arc–arc collision zone in central Hokkaido provides an important key for the evolution process from island arc to more felsic continental crust. In northern Honshu, a major fault system with listric geometry, which was formed by Miocene back arc spreading, was successfully mapped down to 12–15 km.     

Safety Management Based on Detection of Possible Rock Bursts by AE Monitoring during Tunnel Excavation

Summary. As underground development continues at great depths, the danger of rock bursts will inevitably increase. It is important to consider countermeasures for avoiding rock bursts in underground work. In Japan, rock bursts have actually been experienced during construction of several tunnels, including the Kan-etsu tunnel construction project, during which many rock bursts were observed. Stress analysis of tunnels is performed based on initial stress measurements in the base rock. In addition, AE measurement has been adopted in construction management, allowing safer excavation. Collective analysis of the data obtained has been shown to be effective for safety control during excavation of hard base rock. In this research, initial stress measurements in base rock, secondary stress analysis around a tunnel, and AE measurements are examined. Based on the results of this analysis, it is clear that the generation of rock bursts is related to the presence of geological discontinuities.     

Determination of U–Pb Ages for Young Zircons using Laser Ablation‐ICP‐Mass Spectrometry Coupled with an Ion Detection Attenuator Device

We have developed new analytical procedures to measure precise and accurate ²³⁸U–²⁰⁶Pb and ²³⁵U–²⁰⁷Pb ages for young (~ 1 Ma) zircons using laser ablation‐ICP‐mass spectrometry. For young zircons, both careful correction for the background counts and analysis of very small Pb/U ratios (i.e., ²⁰⁶Pb/²³⁸U < 0.00016 and ²⁰⁷Pb/²³⁵U < 0.0001 for 1 Ma zircons) are highly desired. For the correction of the background, the contribution of the background signal intensities for the analytes, especially for the residual signal intensities for ²⁰⁶Pb and ²⁰⁷Pb, was defined through laser ablation of synthesised zircons (ablation blank) containing negligible Pb. The measured signal intensities for ²⁰²Hg, ²⁰⁶Pb and ²⁰⁷Pb signals obtained by the ablation blank were slightly higher than those obtained by data acquisition without laser ablation (gas blank). For the wider dynamic range measurements on Pb/U ratios, an attenuator device for the ion detection system was employed to extend the capability to monitor high‐intensity signals (i.e., > 3 Mcps). Through the attenuator device, the ion currents were reduced to 1/450 of the signal intensity without the attenuator. Because the switching time for the attenuator was shorter than 1 ms, signal intensities for only specific isotopes could be reduced. With attenuation of the ²³⁸U signal, counting statistics on ²⁰⁶Pb and ²⁰⁷Pb isotopes could be improved and counting loss on the ²³⁸U signal could be minimised. To demonstrate the reliability of this new analytical technique, ²³⁸U–²⁰⁶Pb and ²³⁵U–²⁰⁷Pb ages for three young zircon samples (collected from Osaka Group Pink Volcanic Ash, Kirigamine and Bishop Tuff) were measured. The data presented here demonstrate clearly that the present technique could become a major analytical tool for in situ U–Pb age determination of young zircons (~ 1 Ma).     

Age gap between the intrusion of gneissose granitoids and regional high‐temperature metamorphism in the Ryoke belt (Mikawa area), central Japan

The relationships between the intrusion of gneissose granitoids and the attainment of regional high‐T conditions recorded in metamorphic rocks from the Ryoke belt of the Mikawa area, central Japan, are explored. Seven gneissose granitoid samples (tonalite, granodiorite, granite) were collected from three distinct plutonic bodies that are mapped as the so‐called “Older Ryoke granitoids.” Based on bulk‐rock compositions and U–Pb zircon ages obtained by laser ablation inductively coupled plasma mass spectrometry, the analyzed granitoids can be separated into two groups. Gneissose granitoids from the northern part of the area give weighted mean ²⁰⁶Pb/²³⁸U ages of 99 ±1 Ma (two samples) and 95 ±1 Ma (one sample), whereas those from the southern part yield 81 ±1 Ma (two samples) and 78–77 ±1 Ma (two samples). Regional comparisons allow correlation of the northern granitoids (99–95 Ma) with the Kiyosaki granodiorite, and mostly with the Kamihara tonalite found to the east. The southern granitoids are tentatively renamed as “78–75 Ma (Hbl)?Bt granite” and “81–75 Ma Hbl?Bt tonalite” (Hbl, hornblende; Bt, biotite). and seem to be broadly coeval members of the same magmatic suite. With respect to available age data, no gneissose granitoid from the Mikawa area shows a U–Pb zircon age which matches that of high‐T metamorphism (ca 87 Ma). The southern gneissose granitoids (81–75 Ma), although they occur in the highest‐grade metamorphic zone, do not seem to represent the heat source which produced the metamorphic field gradient with a low dP/dT slope.     

Geochemistry of natural chromium occurrence in a sandstone aquifer in Bauru Basin, São Paulo State, Brazil

Anomalous concentrations of Cr(VI) occur in groundwaters of the Adamantina Aquifer, in a large region in the western state of São Paulo, sometimes exceeding the potability limit (0.05 mg L⁻¹). To identify the possible geochemical reactions responsible for the occurrence of Cr in groundwater in Urânia, borehole rock samples were collected in order to carry out mineralogical and chemical analyses. In addition, multilevel monitoring wells were installed and groundwater samples were analyzed. Analyses of the borehole rock samples show the occurrence of a geochemical anomaly of Cr in the quartzose sandstones (average concentrations of 221 ppm). Chrome-diopside is one of the main minerals contributing to this anomaly, having an average Cr content of 1505 ppm. Sequential extraction experiments indicated weakly adsorbed Cr in the order of 0.54 ppm, and this quantity is enough to provide the Cr concentrations observed in groundwater. Groundwaters from the monitoring wells proved to be stratified, with the highest concentrations of Cr(VI) (0.13 mg L⁻¹) being associated with high redox and pH values (over 10) and high concentrations of Na. Geochemical reactions that may explain the release of Cr from the solid phase to groundwater involve the release of Cr(III) from minerals (like chrome-diopside and Cr-Fe hydroxide), followed by oxidation of Cr(III) to Cr(VI), probably related to the reduction of Mn oxides present in the aquifer. Then cation exchange occurs and dissolution of carbonates which increases the pH of groundwater, resulting in the desorption and mobilization of Cr(VI) into groundwater.     

Characteristics of ChgH–GFP transgenic medaka lines, an in vivo estrogenic compound detection system

We previously reported the characteristics of a ChgH–GFP transgenic medaka line that indicates estrogenic compound pollution in environmental water by the green fluorescence of their liver. Recently, we established four more lines. In this study, the characteristics of the five transgenic medaka lines were investigated. The intensity of reporter gene expression varied among transgenic lines and generally correlated well with the amount of integrated transgene in each line. Line-specific ectopic expression was also observed. However, the sensitivity to 17-β estradiol did not differ among transgenic lines. Three transgenic lines are considered to be suitable as bio-indicators of estrogenic activity, due to the ease of observing green fluorescence in their livers. The transgenic lines can also detect the estrogenic activity of testosterone and 17-β trenbolone at the nominal concentration of 30 and 100 μg/l, respectively.     

Repeating earthquake activities associated with the Philippine Sea plate subduction in the Kanto district, central Japan: A new plate configuration revealed by interplate aseismic slips

We detect repeating earthquakes associated with the Philippine Sea plate subduction to reveal the plate configuration. In the Kanto district, we find 140 repeating earthquake groups with 428 events by waveform similarity analysis. Most repeating earthquakes in the eastern part of the Kanto district occur with a regular time interval. They have thrust-type focal mechanisms and are distributed near the upper surface of the Philippine Sea plate. These observations indicate that the repeating earthquakes there occur as a repetition of ruptures on the isolated patches distributed on the plate boundary owing to the concentration of stress caused by aseismic slips in the surrounding areas. This shows that the distributions of repeating earthquakes suggest the aseismic slips in the surrounding areas of small patches. We determine spatial distributions of repeating earthquakes in the eastern part of the Kanto district and find that they correspond to the upper boundary of the Philippine Sea plate, that is, the upper boundary of the oceanic crust layer of the Philippine Sea plate. The plate geometry around Choshi is newly constrained by repeating earthquake data and a rather flat geometry in the eastern part of the Kanto district is revealed. The obtained geometry suggests uplift of the Philippine Sea plate due to the collision with the Pacific plate beneath Choshi.Repeating earthquakes in the western part of the Kanto district have extremely shorter recurrence times, and their focal mechanisms are not of the thrust types. These repeating earthquakes are classified as “burst type” activity and likely to occur on the preexistent fault planes which are distributed around the “collision zone” between the Philippine Sea plate and the inland plate. The variation among the repeating earthquake activities in the Kanto district indicates that regular repetition of repeating earthquakes is possible only on the plate boundary with a smooth and simple geometry.     

Deep seismic reflection profiling across the Ou Backbone range, northern Honshu Island, Japan

Knowledge of the crustal structure, especially the geometry of seismogenic faults, is key to understanding active tectonic processes and assessing the size and frequency of future earthquakes. To reveal the relationship between crustal structure and earthquake activity in northern Honshu Island, common midpoint (CMP) deep reflection profiling and earthquake observations by densely deployed seismic stations were carried out across the active reverse faults that bound the Ou Backbone range. The 40-km-long CMP profiles portray a relatively simple fault geometry within the seismogenic layer. The reverse faults merge at a midcrustal detachment just below the base of the seismogenic layer, producing a pop-up structure that forms the Ou Backbone range. The top of the reflective middle to lower crust (4.5 s in travel time (TWT)) nearly coincides with the bottom of seismogenic layer. The P-wave velocity structure and surface geology suggest that the bounding faults are Miocene normal faults that have been reactivated as reverse faults.     

U–Pb ages of zircons from metamorphic rocks in the upper sequence of the Hidaka Metamorphic Belt,Hokkaido, Japan: Identification of two metamorphic events and implications for regional tectonics

The Hidaka Metamorphic Belt is a well-known example of island-arc crustal section, in which metamorphic grade increases westwards from unmetamorphosed sediment up to granulite facies. It is divided into lower (granulite to amphibolite facies) and upper (amphibolite to greenschist facies) metamorphic sequences. The metamorphic age of the belt was considered to be ~55 Ma, based on Rb – Sr whole-rock isochron ages for granulites and related S-type tonalities. However, zircons from the granulites in the lower sequence yield U – Pb ages of ~21 – 19 Ma, and a preliminary report on zircons from pelitic gneiss in the upper sequence gives a U – Pb age of ~40 Ma. In this paper we provide new zircon U – Pb ages from two pelitic gneisses in the upper sequence to assess the metamorphic age and also the maximum depositional age of the sedimentary protolith. The weighted mean ²⁰⁶Pb/²³⁸U ages from a biotite gneiss in the central area of the belt yield 39.6 ± 0.9 Ma for newly grown metamorphic rims and 53.1 ± 0.9 Ma for the youngest detrital cores. The ages of zircons from a cordierite–biotite gneiss in the southern area are 35.9 ± 0.7 Ma for metamorphic rims and 46.5 ± 2.8 Ma for the youngest detrital cores. These results indicate that metamorphism of the upper sequence took place at ~40 – 36 Ma, and that the sedimentary protolith was deposited after ~53 – 47 Ma. These metamorphic ages are consistent with the reported ages of ~37–36 Ma plutonic rocks in the upper sequence, but contrast with the ~21–19 Ma ages of metamorphic and plutonic rocks in the lower sequence. Therefore, we conclude that the upper and lower metamorphic sequences developed independently but coupled with each other before ~19 Ma as a result of dextral reverse tectonic movement.