Phase separation,fluid mixing,and origin of the greisens and potassic episyenite associated with the Água Boa pluton,Pitinga tin province,Amazonian Craton,Brazil

Based on petrographical data, three types of greisen have been characterized at the western border of Água Boa pluton: siderophyllite–topaz–quartz greisen (greisen 1), fluorite–phengite–quartz greisen (greisen 2) and quartz–chlorite–phengite greisen (greisen 3). Episyenites were also identified.Two fluids of independent origin interacted with the same protolith – a hornblende-biotite alkali feldspar granite – and produced both the greisens and potassic episyenite: (1) an acid, low-salinity (4–12 wt.% NaCl eq.), F-rich, relatively hot (400–350 °C) reduced aqueous-carbonic fluid (CH₄–H₂O–NaCl–FeCl₂ ± KCl), which by immiscibility gave rise to fluid IA (aqueous) and IC (carbonic); and (2) a lower salinity (2–4 wt.% NaCl eq.) and temperature (200–150 °C) aqueous fluid (H₂O–NaCl), which was responsible for all dilution processes. Fluid 1 seems to have had a magmatic-hydrothermal origin, while fluid 2 is probably surface-derived (meteoric water?). An alkaline, F-poorer and diluted equivalent of fluid IA was interpreted to have caused the episyenitization of the granite host rock as well as the formation of phengite-rich greisen 3. The continuos interaction of this fluid with the potassic episyenite produced a moderate- to high-salinity (20–24 wt.% NaCl eq.), low-temperature (200–100 °C) fluid (H₂O–NaCl–CaCl₂ ± KCl), leading to the formation of chlorite-rich zone of greisen 3 and late silicification of potassic episyenite.In the greisen 1, decreasing F-activity and increasing oxygen fugacity, as the system cooled down, favored the formation of a topaz-rich inner zone, which grades into a siderophyllite-rich zone outwardly. Greisen 2 was formed under more oxidizing conditions by fluids poorer in F than those trapped in the siderophyllite-rich zone.The oxidation of aqueous-carbonic fluid took place at three distinct stages: (i) below the FMQ buffer; (ii) between the FMQ and NNO buffers; and (iii) above the NNO buffer.The dissolution cavities generated during the episyenitization process increased the permeability of the altered rocks, resulting in an increase of the fluid/rock ratios at the potassic episyenite and greisen 3 sites.All these fluids were trapped under pressure conditions of <1.0 kbar, representing shallow crustal levels and are consistent with those that have been estimated for the Pitinga tin–granites.The oxygen fugacity, F-activity gradients and salinity variations that occurred during the cooling of the hydrothermal system, in addition to differences in permeability, were important factors in the formation of distinct greisens. They not only controlled the fluid compositional changes, but also caused the cassiterite and sulfide precipitation at the greisen sites.     

Ridge collision and in situ greenstones in accretionary complexes: An example from the Late Cretaceous Ryukyu Islands and southwest Japan margin

Abstract Mélange units containing greenstones are common throughout the Cretaceous-Miocene Shimanto Supergroup in the Ryukyu Is and southwest Japan. Most greenstones in the accretionary complex originated in oceanic spreading ridges and seamounts, and they formed far from the convergent margin. Some mélange-like units in the supergroup, however, contain greenstones that were extruded upon and intruded into unconsolidated fine-grained terrigenous clastic sediments. It is inferred that eruption of the in situ greenstones resulted from igneous activity in the trench area. Geochemical signatures indicate that the greenstone protoliths were similar to mafic lavas generated at spreading ridges. Fossil ages of the strata containing in situ greenstones become younger over a distance of 1300 km eastward from Amami-Oshima (Cenomanian-Turonian) in the Ryukyu Is to central Japan (Late Maestrichtian-earliest Paleocene), implying that a site of igneous activity in the trench area migrated eastward along the Ryukyu Is and southwest Japan margin. Plate reconstructions of the northwest Pacific Ocean suggest the presence of the Kula-Pacific ridge near Late Cretaceous to early Paleogene Japan. In this context, it is suggested that the greenstones formed in response to Kula-Pacific ridge-forearc collision.
Ancient ridge-forearc collisions are best recognized by the presence of mid-ocean ridge basalt (MORB) extruded on sediments inferred to have accumulated in the trench area. Diachronous occurrences of the strata associated with these MORB in an orogenic belt are useful for documenting the ridge collision through time.     

Generation of unsaturated and aromatic hydrocarbons by thermal alteration of young kerogen

Monounsaturated, monoaromatic and polyaromatic hydrocarbons generated by artificial thermal alteration of young marine (Tanner basin, offshore California) kerogen were studied by computerized GC-MS. Their relative amounts changed with temperature (150–410°C) and time (5–120 hr) of heating as follows: Monounsaturates → Monoaromatics → Polyaromatics. Distribution of alkyl homologs of phenanthrene also changed with increasing degree of thermal alteration. These results are in agreement with those observed for crude oils and shales.     

Interstadial coral reef terraces and relative sea-level changes during marine oxygen isotope stages 3–4, Kikai Island, central Ryukyus, Japan

Coral reef terraces are one of the best recorders of relative sea-level changes during the last glacial cycle. Thus far, knowledge of relative sea-level record based on coral reefs during the marine Oxygen Isotope Stage (OIS) 3 has been limited to studies of the Huon Peninsula, Papua New Guinea. High-precision a α-spectrometric ²³⁰Th/²³⁴U dating demonstrated an offlapping sequence of five coral reef complexes, ages of which are 66, 64, 62, 55 and 52 ka, in the northern part of Kikai Island, central Ryukyus of Japan. Interstadial reefs, characterized by deepening-upward sequences of coral assemblages, recorded three hemicycles from transgression to highstand at 52, 62, and 66 ka, during which these reefs were drowned. These highstands in the relative sea-level record can be correlated with the eustatic record reconstructed from the Huon reef terraces and with the interstadials 14, 18, and 19 of the GISP 2 oxygen isotope record. This consistency confirms the Huon sea-level record of OIS 3 and implies that the eustatic sea level responded to the millennial-scale climate changes even during the glacial period of OIS 4.     

The influence of intense rainfall on the activity of large-scale crystalline schist landslides in Shikoku Island, Japan

Many large landslides in the crystalline schist region of Shikoku Island, Japan, are susceptible to intense rainfall. Through the use of on-site monitoring systems, the activity of landslides and their meteorological triggers can be assessed. Continuous high-intensity rainfall was found to play a key role in provoking landslide movement. This paper investigates the influence of intense rainfall on the activity of crystalline schist landslides by examining rainfall and displacement of four typical landslides. By defining and calculating the effective rainfall and the relative landslide displacement, the relationship between intense rainfall and rainfall-induced landslide movement was analysed. Results indicate that the intense rainfall-induced landslide movement can be correlated with the effective rainfall. From these results, two rainfall thresholds were identified for the landslide risk management of Shikoku Island.     

Fluid inclusion and stable isotope (O, H, C, and S) constraints on the genesis of the Serrinha gold deposit, Gurupi Belt, northern Brazil

The Serrinha gold deposit of the Gurupi Belt, northern Brazil, belongs to the class of orogenic gold deposits. The deposit is hosted in highly strained graphitic schist belonging to a Paleoproterozoic (∼2,160 Ma) metavolcano-sedimentary sequence. The ore-zones are up to 11 m thick, parallel to the regional NW–SE schistosity, and characterized by quartz-carbonate-sulfide veinlets and minor disseminations. Textural and structural data indicate that mineralization was syn- to late-tectonic and postmetamorphic. Fluid inclusion studies identified early CO₂ (CH₄-N₂) and CO₂ (CH₄-N₂)-H₂O-NaCl inclusions that show highly variable phase ratios, CO₂ homogenization, and total homogenization temperatures both to liquid and vapor, interpreted as the product of fluid immiscibility under fluctuating pressure conditions, more or less associated with postentrapment modifications. The ore-bearing fluid typically has 18–33mol% of CO₂, up to 4mol% of N₂, and less than 2mol% of CH₄ and displays moderate to high densities with salinity around 4.5wt% NaCl equiv. Mineralization occurred around 310 to 335°C and 1.3 to 3.0 kbar, based on fluid inclusion homogenization temperatures and oxygen isotope thermometry with estimated oxygen fugacity indicating relatively reduced conditions. Stable isotope data on quartz, carbonate, and fluid inclusions suggest that veins formed from fluids with δ¹⁸O_H2O and δD_H2O (310–335°C) values of +6.2 to +8.4‰ and −19 to −80‰, respectively, which might be metamorphic and/or magmatic and/or mantle-derived. The carbon isotope composition (δ¹³C) varies from −14.2 to −15.7‰ in carbonates; it is −17.6‰ in fluid inclusion CO₂ and −23.6‰ in graphite from the host rock. The δ³⁴S values of pyrite are −2.6 to −7.9‰. The strongly to moderately negative carbon isotope composition of the carbonates and inclusion fluid CO₂ reflects variable contribution of organic carbon to an originally heavier fluid (magmatic, metamorphic, or mantle-derived) at the site of deposition and sulfur isotopes indicate some oxidation of the originally reduced fluid. The deposition of gold is interpreted to have occurred mainly in response to phase separation and fluid-rock interactions such as CO₂ removal and desulfidation reactions that provoked variations in the fluid pH and redox conditions.     

K-Ar dating studies of Ashigawa and Tokuwa granodiorite bodies and plutonic geochronology in the South Fossa Magna, central Japan

Abstract K-Ar age studies in the Ashigawa and the southern part of the Tokuwa granodioritic bodies, which consist of the southern part of the Kofu plutonic complex, revealed that they formed between 12 and 9 Ma. Quite a narrow range of ages obtained from the Ashigawa southernmost part of the Tokuwa pluton implies that they cooled rapidly. The southern part of the Tokuwa pluton, as a whole, shows a systematic age distribution with a decrease in age to the north. Compilation of currently available plutonic ages in the South Fossa Magna suggests that the plutonic activities occurred three times in this region. Episodic activity like this could be argued in relation to the tectonic development of this region.     

Miocene intra-arc bending at an arc-arc collision zone, central Japan

Abstract Recent paleomagnetic studies are reviewed in an effort to clarify the relationship between the intra-arc deformation of central Japan and the collision tectonics of the Izu-Bonin Arc. The cusp structure of the pre-Neogene terranes of central Japan, called the Kanto Syntaxis, suggests a collisional origin with the Izu-Bonin Arc. The paleomagnetic results and newly obtained radiometric ages of the Kanto Mountains revealed the Miocene rotational history of the east wing of the Kanto Syntaxis. More than 90° clockwise rotation of the Kanto Mountains took place after deposition of the Miocene Chichibu Basin (planktonic foraminiferal zone of N.8: 16.6–15.2 Ma). After synthesizing the paleomagnetic data of the Japanese Islands and collision tectonics of central Japan, it appears that approximately a half rotation (40–50°) probably occurred at ca 15 Ma in association with the rapid rotation of Southwest Japan. The remainder (50-40°) continued until 6 Ma, resulting in the sharp bent structure of the pre-Neogene accretionary complexes (Kanto Syntaxis). The latter rotation seems to have been caused by the collision of the Izu-Bonin Arc on the northwestward migrating Philippine Sea Plate.