Stoichiometric control of crystal/liquid single-component partition coefficients

Single-component (e.g., single-element) partition coefficients for silicate melts and the minerals that crystallize from them typically show large variations with temperature and melt composition. It is shown that, in particular cases, these variations can be calculated from two-component distribution coefficients that are practically constants, given the structural formula of the mineral and the melt composition.     

What dynamics drive future wind scenarios for coastal upwelling off Peru and Chile?

The dynamics of the Peru–Chile upwelling system (PCUS) are primarily driven by alongshore wind stress and curl, like in other eastern boundary upwelling systems. Previous studies have suggested that upwelling-favorable winds would increase under climate change, due to an enhancement of the thermally-driven cross-shore pressure gradient. Using an atmospheric model on a stretched grid with increased horizontal resolution in the PCUS, a dynamical downscaling of climate scenarios from a global coupled general circulation model (CGCM) is performed to investigate the processes leading to sea-surface wind changes. Downscaled winds associated with present climate show reasonably good agreement with climatological observations. Downscaled winds under climate change show a strengthening off central Chile south of 35°S (at 30°S–35°S) in austral summer (winter) and a weakening elsewhere. An alongshore momentum balance shows that the wind slowdown (strengthening) off Peru and northern Chile (off central Chile) is associated with a decrease (an increase) in the alongshore pressure gradient. Whereas the strengthening off Chile is likely due to the poleward displacement and intensification of the South Pacific Anticyclone, the slowdown off Peru may be associated with increased precipitation over the tropics and associated convective anomalies, as suggested by a vorticity budget analysis. On the other hand, an increase in the land–sea temperature difference is not found to drive similar changes in the cross-shore pressure gradient. Results from another atmospheric model with distinct CGCM forcing and climate scenarios suggest that projected wind changes off Peru are sensitive to concurrent changes in sea surface temperature and rainfall.     

Anomalously large seismic amplifications in the seafloor area off the Kii peninsula

Seismic wave amplifications were investigated using strong-motion data obtained from the ground’s surface (K-net) on the Kii peninsula (southwestern Japan) and from the network of twenty seismic stations on the seafloor (DONET) located off the peninsula near the Nankai trough. Observed seismograms show that seismic signals at DONET stations are significantly larger than those at K-net stations, independent of epicentral distances. In order to investigate the cause of such amplifications, seismic wavefields for local events were simulated using the finite-difference method, in which a realistic 3D velocity structure in and around the peninsula was incorporated. Our simulation results demonstrate that seismic waves are significantly amplified at DONET stations in relation to the presence of underlying low-velocity sediment layers with a total thickness of up to 10 km. Our simulations also show considerable variations in the degree of amplification among DONET stations, which is attributed to differences in the thickness of the sediment layers. The degree of amplification is relatively low at stations above thin sediment layers near the trough axis, but seismic signals are much more amplified at stations closer to the Kii peninsula, where sediment layers are thicker than those at the trough axis. Simulation results are consistent with observations. This study, based on seafloor observations and simulations, indicates that because seismic signals are amplified due to the ocean-specific structures, the magnitude of earthquakes would be overestimated if procedures applied to data observed at land stations are used without corrections.     

An index for tropical temperate troughs over southern Africa

Strong cases of the tropical temperate troughs (TTT) that are responsible for the most of the summer rainfall over subtropical southern Africa are analyzed. An index for identifying the TTT is introduced for the first time using anomalies of outgoing longwave radiation (OLR) and the wind. The TTT is associated with a ridge-trough-ridge wave-like structure in the lower troposphere over southern Africa and the adjoining Indian Ocean. Therefore, the index considers physical processes that occur over southern Africa, adjoining the Atlantic and Indian Oceans to depict the variability of the TTT events. Unusually strong TTT events are identified when the standard deviations of the TTT indices defined by the OLR and wind anomalies in the selected regions are above 1.5 and 0.5 respectively. After applying this criterion and filtering out consecutive events, 55 TTT events are identified during the study period of December–January–February seasons from 1980–1981 to 2009–2010. From the composite analyses of those 55 events, it is found that the TTTs evolve with suppressed (enhanced) convection over the southwest Indian Ocean adjacent to Madagascar (southern Africa). The suppressed convection is, in turn, found to be associated with the enhanced convection around Sumatra in the southeast tropical Indian Ocean. This may explain why more TTT events occur in La Niña years as compared to El Niño years. Time evolution of the canonical TTT event shows that it starts 3 days prior to the mature phase of the event, suggesting possible predictability. After reaching a matured state, the system moves east toward the Indian Ocean and decays within the subsequent couple of days. In addition, the intertropical convergence zone (ITCZ) structure changes over Southern Africa/Madagascar during the TTT event and remains similar to climatology over other regions. The results indicate that the continental part of the ITCZ intensifies prior to the TTT event and then spreads southward following the mid-latitude influence during and after the event.     

Non-ENSO interannual rainfall variability in central Chile during austral winter

The first principal component (PC1) of seasonal rainfall anomalies in central Chile during winter (June–August) is used to analyze the circulation anomalies related to wet and dry conditions, when near-normal or neutral SST anomalies are observed in the equatorial Pacific, i.e., during non-ENSO conditions. Eight wet and eight dry winter seasons were defined as the upper and lower terciles of PC1 for 24 non-ENSO winters in the period 1958–2000. Unlike the single process attributed to ENSO, during non-ENSO winter seasons, there are several sources triggering or modifying the propagation of the stationary waves that impact the rainfall regime in central Chile. Unfortunately, the multiple processes that seem to be involved in the modulation of the interannual rainfall variability in central Chile, as seen in this work, limit the predictability of rainfall during non-ENSO conditions.     

Partitioning Eddy-Covariance Methane Fluxes from a Shallow Lake into Diffusive and Ebullitive Fluxes

Methane (\(\mathrm {CH}_{4}\)) is known to be emitted from lakes to the atmosphere via processes such as diffusion and ebullition (i.e., bubble emission). We developed a practical method for partitioning eddy-covariance \(\mathrm {CH}_{4}\) fluxes from a shallow lake into diffusive and ebullitive fluxes using a wavelet analysis based on local scalar similarity between the \(\mathrm {CH}_{4}\) concentration and other reference scalars, such as the air temperature or water vapour concentration, in the wavelet time-scale domain, with the hypothesis that similar and dissimilar fluctuation components are related to diffusive and ebullitive \(\mathrm {CH}_{4}\) fluxes, respectively. Our method is applied to approximately two weeks of data obtained at a shallow mid-latitude lake. The partitioned diffusive flux has a physically sound relationship with wind speed, supporting the validity of the method. The ratio of the diffusive flux to the total flux is typically 0.11 with flow from an area of steady bubble emission, but otherwise 0.36. Further validation is required using a larger dataset and data from other lakes. The proposed method can be easily applied to historical data because it requires only 10-Hz data of \(\mathrm {CH}_{4}\) concentration and other reference scalars, along with an empirical parameter.     

Mineralogical and Geochemical Characteristics of the Utanobori Gold Deposit in Northern Hokkaido,Japan

The Utanobori gold deposit is a low‐sulfidation, epithermal vein‐type deposit located in northern Hokkaido, Japan. The deposit is hosted by conglomerate, sandstone, and tuff of the Middle to Late Miocene Esashi Formation. These rocks were hydrothermally altered. Silica sinters and quartz‐adularia veins are common in the deposit. The quartz‐adularia veins either contain a ginguro band, which corresponds to the main gold‐bearing vein (Type 1 Veins), or do not contain a ginguro band but contain minor adularia (Type 2 Veins). Type 1 Veins are divided into three stages with 12–14 substages. Ore minerals identified include electrum, naumannite, chlorargyrite, bromargyrite, an unidentified Fe‐Sb mineral, and an Fe‐(Sb)‐As mineral. These ore minerals formed in the main mineralization stages I (bands I‐b and I‐d) and II (band II‐a). Scanning electron microscopy with cathodoluminescence images show that cathodoluminescence‐dark microcrystalline quartz exhibiting colloform (ghost‐sphere) texture is closely associated with ore minerals in the Type 1 Vein and Type 2 Vein, and the Al and K contents of such quartz are commonly >1000 ppm. This indicates that the ore minerals were crystallized from alkaline, silica‐saturated fluids at temperatures <200°C, which initially deposited amorphous silica that was recrystallized to microcrystalline quartz. The average Au content of electrum is 52.5 at% Au (n = 10), 65.7 at% Au (n = 20), and 55.5 at% Au (n = 5) in bands I‐b, I‐d, and II‐a, respectively, of Type 1 Veins. The δ³⁴S_CDT values of two fine‐grained disseminated pyrites in the altered conglomerate and bedded tuff in the argillic altered zone are ?4.3 and ?4.2‰. Ar‐Ar dating on adularia yielded 13.6 ± 0.06 Ma, 13.6 ± 0.07 Ma, and 13.6 ± 0.06 Ma for the stages I, II, and III of the Type 1 Vein, respectively. K‐Ar ages determined on adularia in the silica sinter and on whole‐rock of glassy rhyolite of the Esashi Formation are 15.0 ± 0.4 Ma and 14.6 ± 0.4 Ma, respectively. These radiometric ages indicate that silica sinter associated with the rhyolitic volcanic rocks formed prior to the main gold mineralization.     

Characterization of drying-induced deformation behaviour of Opalinus Clay and tuff in no-stress regime

The drying-induced deformation behaviour of Opalinus Clay and tuff, which are being investigated under international and local collaborative projects for nuclear waste disposal in Switzerland and Japan, was investigated under a no-stress condition in the laboratory to evaluate their generic susceptibility to the formation of excavation damaged zone. The cylindrical core samples of Opalinus Clay and tuff were prepared to a one-dimensional drying condition and submitted to an uncontrolled laboratory environment. The strain evolution, evaporative water loss and environmental entities, such as temperature and relative humidity, were recorded simultaneously and quasi-continuously. It was observed that the drying phase induced significant strain magnitude and damage in Opalinus Clay samples, which was evidenced by the formation of hairy cracks on the surface parallel to the bedding. On the contrary, the strain occurrences in tuff samples were relatively insignificant, and no tendency of cracking was observed. In addition, the quasi-continuous availability of volumetric strains was further used in poroelastic relation for the estimation of capillary suction evolution. The calculated results were validated with pore size distributions obtained from mercury intrusion porosimetry.     

Overprinting porphyry‐type veinlets on the intrusive rocks and phreatomagmatic breccias in the Southwest prospect,southwestern Sto. Tomas II (Philex), Baguio District,Philippines

The Southwest prospect is located at the southwestern periphery of the Sto. Tomas II porphyry copper–gold deposit in the Baguio District, northwestern Luzon, Philippines. The Southwest prospect hosts a copper‐gold mineralization related to a complex of porphyry intrusions, breccia facies, and overlapping porphyry‐type veinlets emplaced within the basement Pugo metavolcanics rocks and conglomerates of the Zigzag Formation. The occurrences of porphyry‐type veinlets and potassic alteration hosted in the complex are thought to be indications of the presence of blind porphyry deposits within the Sto. Tomas II vicinity. The complex is composed of at least four broadly mineralogically similar dioritic intrusive rocks that vary in texture and alteration type and intensity. These intrusions were accompanied with at least five breccia facies that were formed by the explosive brecciation, induced by the magmatic–hydrothermal processes and phreatomagmatic activities during the emplacement of the various intrusions. Hydrothermal alteration assemblages consisting of potassic, chlorite–magnetite, propylitic and sericite–chlorite alteration, and contemporaneous veinlet types were developed on the host rocks. Elevated copper and gold grades correspond to (a) chalcopyrite–bornite assemblage in the potassic alteration in the syn‐mineralization early‐mineralization diorite (EMD) and contemporaneous veinlets and (b) chalcopyrite‐rich mineralization associated with the chalcopyrite–magnetite–chlorite–actinolite±sericite veinlets contemporaneous with the chlorite–magnetite alteration. Erratic remarkable concentrations of gold were also present in the late‐mineralization Late Diorite (LD). High X_Mg of calcic amphiboles (>0.60) in the intrusive rocks indicate that the magmas have been oxidizing since the early stages of crystallization, while a gap in the composition of Al between the rim and the cores of the calcic amphiboles in the EMD and LD indicate decompression at some point during the crystallization of these intrusive rocks. Fluid inclusion microthermometry suggests the trapping of immiscible fluids that formed the potassic alteration, associated ore mineralization, and sheeted quartz veinlets. The corresponding formation conditions of the shallower and deeper quartz veinlets were estimated at pressures of 50 and 30 MPa and temperatures of 554 and 436°C at depths of 1.9 and 1.1 km. Temperature data from the chlorite indicate that the chalcopyrite‐rich mineralization associated with the chlorite–magnetite alteration was formed at a much lower temperature (ca. 290°C) than the potassic alteration. Evidence from the vein offsetting matrix suggests multiple intrusions within the EMD, despite the K‐Ar ages of the potassic alteration in EMD and hornblende in the LD of about the same age at 3.5 ± 0.3 Ma. The K‐Ar age of the potassic alteration was likely to be thermally reset as a result of the overprinting hydrothermal alteration. The constrained K‐Ar ages also indicate earlier formed intrusive rocks in the Southwest prospect, possibly coeval to the earliest “dark diorite” intrusion in the Sto. Tomas II deposit. In addition, the range of δ³⁴S of sulfide minerals from +1.8‰ to +5.1‰ in the Southwest prospect closely overlaps with the rest of the porphyry copper and epithermal deposits in the Sto. Tomas II deposit and its vicinity. This indicates that the sulfides may have formed from a homogeneous source of the porphyry copper deposits and epithermal deposits in the Sto. Tomas II orebody and its vicinity. The evidence presented in this work proves that the porphyry copper‐type veinlets and the adjacent potassic alteration in the Southwest prospect are formed earlier and at a shallower level in contrast with the other porphyry deposits in the Baguio District.     

Asia-Pacific mussel watch: monitoring contamination of persistent organochlorine compounds in coastal waters of Asian countries

Contamination of persistent organochlorines (OCs) such as PCBs (polychlorinated biphenyls), DDT and its metabolites (DDTs), HCH (hexachlorocyclohexane) isomers (HCHs), chlordane compounds (CHLs), and HCB (hexachlorobenzene) were examined in mussels collected from coastal waters of Asian countries such as Cambodia, China, Hong Kong, India, Indonesia, Japan, Korea, Malaysia, Philippines, Far East Russia, Singapore, and Vietnam in 1994, 1997, 1998, 1999, and 2001 to elucidate the contamination status, distribution and possible pollution sources and to assess the risks on aquatic organisms and human. OCs were detected in all mussels collected from all the sampling sites investigated. Considerable residue levels of p,p(')-DDT and alpha-HCH were found in mussels and the concentrations of DDTs and HCHs found in mussels from Asian developing countries were higher than those in developed nations suggesting present usage of DDTs and HCHs along the coastal waters of Asian developing countries. On the other hand, lower concentrations of PCBs detected in mussels from Asian developing countries than those in developed countries indicate that PCBs contamination in mussels is strongly related to industrial and activities. To our knowledge, this is a first comprehensive report on monitoring OCs pollution in the Asia-Pacific region.