Simulating Stable Isotope Ratios in Plumes of Groundwater Pollutants with BIOSCREEN‐AT‐ISO

BIOSCREEN is a well‐known simple tool for evaluating the transport of dissolved contaminants in groundwater, ideal for rapid screening and teaching. This work extends the BIOSCREEN model for the calculation of stable isotope ratios in contaminants. A three‐dimensional exact solution of the reactive transport from a patch source, accounting for fractionation by first‐order decay and/or sorption, is used. The results match those from a previously published isotope model but are much simpler to obtain. Two different isotopes may be computed, and dual isotope plots can be viewed. The dual isotope assessment is a rapidly emerging new approach for identifying process mechanisms in aquifers. Furthermore, deviations of isotope ratios at specific reactive positions with respect to “bulk” ratios in the whole compound can be simulated. This model is named BIOSCREEN‐AT‐ISO and will be downloadable from the journal homepage.     

Growth of filamentous fungi in a surface-sealed woody substratum buried in salt-marsh sediments

Balsa wood panels were sealed to prevent oxygen diffusion from aerobic zones and buried in a North Carolina salt marsh to determine whether filamentous fungi could invade them despite the resulting anoxia. Results were similar to those of a previous study which had employed unsealed panels and suggest that fungi involved either are facultative microaerophiles or capable of translocating sufficient oxygen through their hyphae to permit growth into oxygen-deficient soil strata.     

Enzymatic and cellular responses in relation to body burden of PAHs in bivalve molluscs: A case study with chronic levels of North Sea and Barents Sea dispersed oil

Mytilus edulis and Chlamys islandica were exposed to nominal dispersed crude oil concentrations in the range 0.015–0.25 mg/l for one month. Five biomarkers (enzymatic and cellular responses) were analysed together with bioaccumulation of PAHs at the end of exposure. In both species, PAH tissue residues reflected the exposure concentration measured in the water and lipophylicity determined the bioaccumulation levels. Oil caused biomarker responses in both species but more significant alterations in exposed C. islandica were observed. The relationships between exposure levels and enzymatic responses were apparently complex. The integrated biomarker response related against the exposure levels was U-shaped in both species and no correlation with total PAH body burden was found. For the monitoring of chronic offshore discharges, dose- and time-related events should be evaluated in the selection of biomarkers to apply. From this study, cellular damages appear more fitted than enzymatic responses, transient and more complex to interpret.     

Speleothems as high-resolution paleoenvironment archives: Records from northeastern China

The isotopic compositions of oxygen and carbon and trace concentrations of magnesium and strontium in speleothems formed in limestone caves respond to climate changes outside the caves. Measurements of these properties on a stalagmite from Shihua Cave near Beijing, China, allowed reconstruction of the regional changes in precipitation, temperature and nature of vegetation. Over the last ∼ 500 years, there were fourteen precipitation cycles with a periodicity of 30–40 years, which may well reflect fluctuations in the strength of the East Asian summer monsoons reaching northeastern China. Relative to the mean temperature of this time interval, the period 1620–1900 AD was cold and periods 1520–1620 and 1900–1994 were warm. Over the last ∼ 3000-years, about eight wet/cool-dry/warm climatic cycles of 300–400 years duration occurred, the latest wet/cool half cycle corresponding to the Little Ice Age. The δ¹³C record registers the anthropogenic activities of fossil fuel CO₂ combustion in recent decades and regional deforestation between 13 and 16 centuries when Beijing was bustling with palatial constructions and being developed into the world’s most populated city.     

Change in the magnetic properties of bituminous coal intruded by an igneous dike, Dutch Creek Mine, Pitkin County, Colorado

Magnetization measurements have been made on natural coke–coal samples collected at various distances from a felsic porphyry dike in a coal seam in Dutch Creek Mine, Colorado to help characterize the nature and distribution of the iron-bearing phases. The magnetization passes through a maximum at the coke-to-coal transition about 31 cm from the dike contact. The magnetic measurements support the geochemical data indicating that magmatic fluids along with a high-temperature gas pulse moved into the coal bed. Interaction of the magmatic fluids with the coal diminished the reducing power of the thermal gas pulse from the dike to a point about 24 cm into the coal. The hot reducing gas penetrated further and produced a high temperature (400–525°C) zone (at about 31 cm) just ahead of the magmatic fluids. Metallic iron found in this zone is the principal cause of the observed high magnetization. Beyond this zone, the temperature was too low to alter the coal significantly.     

GSPP a general surface representation module designed for geodesy

GSPP is a computer program system which has been developed for the purposes of automatically determining and representing gravity field surfaces like the geoid, the field of gravity anomalies or deviations of the vertical at prescribed altitude, etc. The system processes gravity field information given by a heterogeneous set of linear functionals of the anomalous potential superimposed by noise, and provides automatically gravity field surfaces in terms of profiles, contour maps and/or 3-dimensional representations. The solution is generally based on least-squares collocation; for a homogeneous data set, a simple weighted average interpolation is available as well. Based on the given data, surface function values at the grid points of a regular rectangular grid are predicted. The representation of the surfaces is smooth using bicubic spline functions. GSPP has a control unit which performs all necessary decision processes and such reduces the user’s decision making to a minimum. The system has been designed for geodetic purposes only; however, because of its versatility and flexibility it presents itself also for applications in other geosciences.     

Change detection of the coastal zone east of the Nile Delta using remote sensing

The coastal zone of the Nile Delta is a promising area for energy resources and industrial activities. It also contains important wetland ecosystems. This coastal area witnessed several changes during the last century. A set of four satellite images from the multi-spectral scanner (MSS), thematic mapper (TM) and Systeme Pour l’Observation de la Terre (SPOT) sensors were utilized in order to estimate the spatio-temporal changes that occurred in the coastal zone between Damietta Nile branch and Port-Said between 1973 and 2007. Image processing applied in this study included geometric rectification; atmospheric correction; on-screen shoreline digitizing of the 1973 (MSS) and 2007 (SPOT) images for tracking the shoreline position between Damietta promontory and Port-Said; and water index approach for quantifying Manzala lagoon surface area change using 1973 (MSS), 1984 (TM) and 2003 (TM) images. Results showed that coastal erosion was severe near Damietta promontory and decreased eastward, however, accretion was observed near Port-Said. About 50% of the coastal strip was under erosion and 13% was under accretion. In addition, a remarkable decline (34.5%) of the Manzala lagoon surface area was estimated. These changes were attributed mainly to the control of the River Nile flooding and the land use change by anthropogenic activities.     

Interrelationship between geochemical elements of sediment and groundwater at Samrak Park Delta of Nakdong River Basin in Korea: multivariate statistical analyses and artificial neural network approaches

This research was conducted at Samrak Park Delta of Nakdong River Basin in Busan Metropolitan City, Korea. The main objective of this study was to evaluate the interrelationship of geochemical elements in sediments and groundwater through multivariate statistical analyses and a multilayer perceptron artificial neural network model. The mean concentrations of chemical elements were Si (46%), Fe (16.9%), Al (15.7%), K (7.5%) and Ca (4.5%) in sediments, and Na (8650 mg/L), Mg (999 mg/L), Ca (432 mg/L), K (293 mg/L) and Cl (17,640 mg/L) in groundwater, respectively. The principal component analysis produced 3 kinds of factors with the variances of 63.37, 27.02 and 9.62%, respectively. It is suggested that the chemical components of sediments and groundwater were mainly originated from source rocks and seawater intrusion, with the minor impacts of irrigation and industry. Cluster analysis also showed that chemical elements were mainly controlled by the natural geogenic sources and seawater intrusion. Multilayer perceptron of artificial neural network (ANN) presented the good interrelationship between sediment and groundwater. The determination coefficients (R ²) between ANN predicted values and observed values in groundwater showed the high values of 0.61–0.97 except Mg, Mn and Sr. It is revealed that the chemical components of sediment and groundwater were derived from local geological origin and from the minor impact of anthropogenic sources. Multivariate analyses and ANN contributed to the identification of the mutual relationship between the geochemical elements of sediment and those of groundwater.     

Fluctuations of floods of the River Morava (Czech Republic) in the 1691–2009 period: interactions of natural and anthropogenic factors

Abstract

Floods from the middle part of the River Morava (eastern Czech Republic) are considered over the course of the past three centuries, the study being based on data derived from documentary evidence (1691–1880), measured peak water stages, H_k (1881–1920) and peak discharges, Q_k (1916–2009), evaluated with respect to their N-year return period (H_N and Q_N ). Changes in land use and water management (water reservoirs, channel modifications) are discussed, as are factors influencing runoff conditions in the Morava catchment. Decadal synthesis of flood series identifies the highest flood activity in the decades of 1911–1920 and 1961–1970 (11 floods each), 1831–1840, 1891–1900, 1901–1910 and 1931–1940 (10 floods each). Uncertainty in this series is related to some incompleteness of documentary data in the pre-1881 period. Very low flood frequency occurred in the 1990s–2000s, although the most disastrous floods were recorded in this particular period (July 1997 at Q ₁₀₀ and March/April 2006 at Q ₂₀–Q ₅₀). Changes in flood frequency correspond partly to long-term changes in temperature and precipitation patterns.

Citation Brázdil, R., ?ezní?ková, L., Valá?ek, H., Havlí?ek, M., Dobrovolný, P., Soukalová, E., ?ehánek, T. & Skokanová, H. (2011) Fluctuations of floods of the River Morava (Czech Republic) in the 1691–2009 period: interactions of natural and anthropogenic factors. Hydrol. Sci. J. 56(3), 468–485.