Organic geochemistry of DSDP Site 467, offshore California,Middle Miocene to Lower Pliocene strata

Results of the analyses of twenty-three samples from the Middle Miocene to Lower Pliocene strata from DSDP Site 467, offshore California, are presented. The analyses were performed with the aim of determining the origin of the organic matter, the stratigraphic section's hydrocarbon generation potential and extent of organic diagenesis. Organic carbon contents are an order of magnitude greater than those typically found in deep sea sediments, suggesting an anoxic depositional environment and elevated levels of primary productivity. Hydrocarbon generation potentials are above average for most samples. The results of elemental analyses indicate that the kerogens are primarily composed of type II organic matter and are thermally immature. Analysis of the bitumen fractions confirms that the samples are immature. In cores from 541 to 614 meters, the gas chromatograms of the C₁₅₊ non-aromatic hydrocarbon fractions are dominated by a single peak which was identified as 17α(H), 18α(H), 21β(H)-28, 30-bisnorhopane. This interval is the same area in which the highest degrees of anoxia are observed as reflected by the lowest pristane/phytane ratios. This correlation may have some implications with regard to the origin of the bisnorhopane and its possible use as an indicator of anoxic depositional conditions within thermally immature sediments.     

Characteristics of sea-cliff erosion induced by a strong winter storm in the eastern Mediterranean

Changes in sea-cliff morphologies along the 30-km-long Sharon Escarpment segment of Israel's weakly cemented Mediterranean eolianite cliff line were analyzed to gain quantitative insights into erosion characteristics associated with a high-energy winter storm (10–20 year return interval). Ground-based repeat LiDAR measurements at five sites along the cliff line captured perturbations of cliff stability by basal wave scouring during the storm, subsequent post-storm gravity-driven slope failures in the cliff face above, and return of the system to transient stability within several months. Post-storm erosion, which amounted to 70% of the total volume of cliff erosion documented, resulted in dramatic local effects of up to 8 m of cliff-top retreat. And yet, at the larger scale of the 30-km cliff line examined, erosion during the storm and the year that followed affected less than 4% of the cliff length and does not appear to be above the average cliff-length annual erosion implied by previously published decadal-scale retreat rates along this sea cliff. Our results do not support a direct association between strong storm events and elevated erosion and retreat at the cliff-line scale.     

Statistics of extremes in climate change

This editorial essay concerns the use (or lack thereof) of the statistics of extremes in climate change research. So far, the statistical theory of extreme values has been primarily applied to climate under the assumption of stationarity. How this theory can be applied in the context of climate change, including implications for the analysis of the economic impacts of extremes, is described. Future research challenges include the statistical modeling of complex extreme events, such as heat waves, and taking into account spatial dependence in the statistical modeling of extremes for fields of climate observations or of numerical model output. Addressing these challenges will require increased collaboration between climate scientists and statisticians.     

From mass‐wasting to slope stabilization – putting constrains on a tectonically induced transition in slope erosion mode: a case study in the Judea Hills,Israel

Calcrete‐coated remnants of landslide debris and alluvial deposits are exposed along the presently stable hillslopes of the Soreq drainage, Judea Hills, Israel. These remnants indicate that a transition from landslide‐dominated terrain to dissolution‐controlled hillslope erosion had occurred. This transition possibly occurred due to the significant decrease in tectonic uplift during the late Cenozoic. The study area is characterized by sub‐humid Mediterranean climate. The drainage hillslopes are typically mantled by thick calcrete crusts overlying Upper Cretaceous marine carbonate rocks. Using TT‐OSL dating of aeolian quartz grains incorporated in the calcrete which cements an ancient landslide deposit, we conclude that incision of ~100 m occurred from 1056 ± 262 to 688 ± 86 ka due to ~0·3° westward tilt of the region; such incision invoked high frequency of landslide activity in the drainage. The ages of a younger landslide remnant, alluvial terrace, and alluvial fan, all situated only a few meters above the present level of the active streambed, range between 688 ± 86 ka and 244 ± 25 ka and indicate that since 688 ± 86 the Soreq base level had stabilized and that landslide activity decreased significantly by the middle Pleistocene. Copyright © 2012 John Wiley & Sons, Ltd.     

Bacterioplankton responses to iron enrichment during the SAGE experiment

We studied the microbial food web in the upper 100 m of the water column in iron-limited sub-Antarctic HNLC waters south-east of New Zealand in the SAGE experiment in 2004, with focus on bacterioplankton. Samples were collected daily from inside and outside the iron enriched patch. Short term enrichment experiments were conducted on board in 4 L polycarbonate bottles with water outside the iron enriched patch to study single and combined effects of micronutrient additions on microbial food web. Low bacterial growth was recorded in the study area with community turnover times of 50 h or more during the study period. Measurements of bacterial standing stocks and production rates in the study show minor responses to the large scale iron enrichment, with increase in rates and stocks after the first enrichment and at the end of the study period after the third iron enrichment when solar radiation increased and wind mixing decreased. The average daily bacterial production rates were 31.5 and 33.7 mgCm⁻² d⁻¹ for the OUT and IN stations, respectively; thus overall there was not a significant difference between the control and the iron-enriched patch. In the bottle experiments bacterial thymidine incorporation showed responses to single iron and silicic acid enrichments and a major growth response to the combined iron and sucrose enrichments. Phytoplankton chlorophyll-a showed clear stimulation by single additions of iron and silicic acid and silicic acid enhanced the iron impact. Cobalt additions had no effect on bacteria growth and a negative effect on phytoplankton growth. Low bacterial in situ growth rates and the enrichment experiments suggest that bacteria are co-limited by iron and carbon, and that bacterial iron uptake is dependent on carbon supply by the food web. With the high iron quota (??mol Fe mol C⁻¹) bacteria may scavenge considerable amounts of the excess iron, and thus influence the relative importance of the microbial food web as a carbon sink.     

Using chemical and microbiological indicators to track the impacts from the land application of treated municipal wastewater and other sources on groundwater quality in a karstic springs basin

Multiple chemical constituents (nutrients; N, O, H, C stable isotopes; 64 organic wastewater compounds, 16 pharmaceutical compounds) and microbiological indicators were used to assess the impact on groundwater quality from the land application of approximately 9.5 million liters per day of treated municipal sewage effluent to a sprayfield in the 960-km² Ichetucknee Springs basin, northern Florida. Enriched stable isotope signatures (δ¹⁸O and δ²H) were found in water from the effluent reservoir and a sprayfield monitoring well (MW-7) due to evaporation; however, groundwater samples downgradient from the sprayfield have δ¹⁸O and δ²H concentrations that represented recharge of meteoric water. Boron and chloride concentrations also were elevated in water from the sprayfield effluent reservoir and MW-7, but concentrations in groundwater decreased substantially with distance downgradient to background levels in the springs (about 12 km) and indicated at least a tenfold dilution factor. Nitrate-nitrogen isotope (δ¹⁵N–NO₃) values above 10 ‰ in most water samples were indicative of organic nitrogen sources except Blue Hole Spring (δ¹⁵N–NO₃ = 4.6–4.9 ‰), which indicated an inorganic source of nitrogen (fertilizers). The detection of low concentrations the insect repellent N,N-diethyl-metatoluamide (DEET), and other organic compounds associated with domestic wastewater in Devil’s Eye Spring indicated that leakage from a nearby septic tank drainfield likely has occurred. Elevated levels of fecal coliforms and enterococci were found in Blue Hole Spring during higher flow conditions, which likely resulted from hydraulic connections to upgradient sinkholes and are consistent with previoius dye-trace studies. Enteroviruses were not detected in the sprayfield effluent reservoir, but were found in low concentrations in water samples from a downgradient well and Blue Hole Spring during high-flow conditions indicating a human wastewater source. The Upper Floridan aquifer in the Ichetucknee Springs basin is highly vulnerable to contamination from multiple anthropogenic sources throughout the springs basin.     

The vortex tube and the tornado

Summary When votex flow is induced in a stream of gas, as in the Ranque-Hilsch tube, the temperature of the axial portion of the vortex is lowered while the temperature of the peripheral portion is raised. The principle of conservation of angular momentum appears to control the conversion of hat to mechanical energy. A similar mechanism may account for some characteristics of tornadoes.     

The behavior of lithium and its isotopes in oilfield brines: evidence from the Heletz-Kokhav field, Israel

Twenty-four brine samples from the Heletz-Kokhav oilfield, Israel, have been analyzed for chemical composition and Li isotope ratios. The chemical composition of the brines, together with geological evidence, suggests derivation from (Messinian) seawater by evaporation that proceeded well into the gypsum stability field but failed to reach the stage of halite crystallization. The present salinity of the samples (18-47 g Cl/L) was achieved by dilution of the original evaporitic brine by local fresh waters. Like brines from other sedimentary basins, the Li/Cl ratios in the Heletz-Kokhav samples show a prominent Li enrichment (five-fold to eight-fold) relative to modern seawater. The isotopic ratios of Li, expressed in the δ ⁶Li notation, vary from −26.3 to −17.9‰, all values being significantly higher than that of modern seawater (−32‰) irrespective of their corresponding Li concentration (1.0-2.3 mg/L). The isotopic composition of Li and the Li/Cl ratio in the oilfield brines were acquired in two stages: (a) The original evaporated seawater gained isotopically light Li during the diagenetic interaction between the interstitial Messinian brine and the basin sediments. A parent brine with an elevated Li/Cl ratio was formed. The brine was later diluted in the oilfields. (b) The δ ⁶Li values of the final brines were determined during epigenetic interaction with the Heletz-Kokhav aquifer rocks. At the same time, the Li/Cl ratio inherited from stage (a) remained largely unchanged. This work represents the first use of lithium isotopic composition to elucidate the origin and evolution of formation waters in sedimentary basins.     

Rock fall hazard along the railway corridor to Jerusalem,Israel, in the Soreq and Refaim valleys

We evaluate rock fall hazard along the railway corridor to Jerusalem, Israel, in the Soreq and Refaim valleys. For the purpose, we use a combination of historical information on past rock fall events, field surveys aided by the interpretation of aerial photographs, and numerical rock fall modeling. Historical information indicates that on July 11, 1927 an m _L 6.2 Dead-Sea transform earthquake caused rock falls in the studied area. The seismically induced rock falls damaged the railway tracks. Field observations revealed that the source area for the 1927 failures was located in the Aminadav formation, at the contact with the Moza formation. At the stratigraphic contact, rock blocks 10⁰–10¹ m³ in size are formed as a result of tensile stresses and associated fracturing in the dolomite of the Aminadav formation, combined with continuous creep of the blocks on the marl of the underlying Moza formation. We use topographical, geological, and geomorphological information to calibrate a three-dimensional numerical simulation of rock falls in the studied area. We use the results of the numerical modeling, and additional independent information, to assess rock fall hazard and the associated risk in the Soreq and Refaim valleys. Results indicate that in the studied area, rock fall risk to the railway line to Jerusalem is due primarily to Dead-Sea transform earthquakes, with m _L  > 6. We identify nine sections of the railway line where rock fall risk exists, for a total length of 2.5 km. We further note that seismically induced rock falls can produce damage to the road network in the studied area, make it difficult or impossible for earthquake casualties to reach hospitals in Jerusalem. We conclude offering recommendations on how to mitigate the risk posed by earthquake-induced rock falls in the studied area.