Patterns and drivers of asteroid abundances and assemblages on the continental margin of Atlantic Canada

Although continental shelf and slope environments typically exhibit high epifaunal biomass and have been subjected to increasing fishing pressure, ecological information on assemblages of non‐commercial invertebrate species from subtidal and bathyal areas remains limited. Sea stars (Echinodermata: Asteroidea), which are known to influence communities through their feeding habits, have received less attention than structural taxa such as corals and sponges. To better understand the ecological roles of asteroids on continental shelves, we investigated ~30 species and assessed their distributions and co‐occurrence with other benthic invertebrates on the shelf and slope of Eastern Canada. Using fisheries data and in situ video footage, we compiled a large dataset covering ~600,000 km² that included over 350,000 individual asteroid records (37–2243 m depth). Multivariate analyses revealed geographically distinct asteroid assemblages, with a maximal overall density at 400–500 m and the highest diversity at 500–700 m. The most abundant and densely occurring species was Ctenodiscus crispatus. We found that asteroids associate with corals, sponges, bivalves, and other echinoderms, and that depth and substrate influence these assemblages. We identified species likely to affect coexisting organisms by their burrowing behavior that can disrupt epi‐ and infauna (C. crispatus) and through predation on ecologically important corals (Hippasteria phrygiana). In addition to providing baseline distribution and ecological information for many bathyal asteroid species in the Northwest Atlantic, this work highlights the abundance and diversified roles of asteroids within continental shelf and slope ecosystems.     

Mapping groundwater discharge to a coastal lagoon using combined spatial airborne thermal imaging,radon (222Rn) and multiple physicochemical variables

Coastal lagoons are significant wetland environments found on coastlines throughout the world. Groundwater seepage may be a key component of lagoon water balances, though only a few studies have investigated large (>100 km²) coastal lagoons. In this study, we combined airborne thermal infrared imagery with continuous measurements of radon (²²²Rn—a natural groundwater tracer), conductivity, water temperature and dissolved oxygen to map groundwater seepage to a large coastal lagoon in New Zealand. We found evidence of seepage along the margins of the lagoon but not away from the margins. Our findings confirmed previously known seepage zones and identified new potential locations of groundwater inflow. Both point source and diffuse seepage occurred on the western and northwestern margins of the lagoon and parallel to the barrier between the lagoon and sea. These observations imply geologic controls on seepage. The combination of remote sensing and in-situ radon measurements allowed us to effectively map groundwater discharge areas across the entire lagoon. Combined, broad-scale qualitative methods built confidence in our interpretation of groundwater discharge locations in a large, dynamic coastal lagoon.     

Environmental fate of fungicides and other current-use pesticides in a central California estuary

The current study documents the fate of current-use pesticides in an agriculturally-dominated central California coastal estuary by focusing on the occurrence in water, sediment and tissue of resident aquatic organisms. Three fungicides (azoxystrobin, boscalid, and pyraclostrobin), one herbicide (propyzamide) and two organophosphate insecticides (chlorpyrifos and diazinon) were detected frequently. Dissolved pesticide concentrations in the estuary corresponded to the timing of application while bed sediment pesticide concentrations correlated with the distance from potential sources. Fungicides and insecticides were detected frequently in fish and invertebrates collected near the mouth of the estuary and the contaminant profiles differed from the sediment and water collected. This is the first study to document the occurrence of many current-use pesticides, including fungicides, in tissue. Limited information is available on the uptake, accumulation and effects of current-use pesticides on non-target organisms. Additional data are needed to understand the impacts of pesticides, especially in small agriculturally-dominated estuaries.     

Comparison of radar and gauge precipitation data in watershed models across varying spatial and temporal scales

Precipitation is a key control on watershed hydrologic modelling output, with errors in rainfall propagating through subsequent stages of water quantity and quality analysis. Most watershed models incorporate precipitation data from rain gauges; higher‐resolution data sources are available, but they are associated with greater computational requirements and expertise. Here, we investigate whether the Multisensor Precipitation Estimator (MPE or Stage IV Next‐Generation Radar) data improve the accuracy of streamflow simulations using the Soil and Water Assessment Tool (SWAT), compared with rain gauge data. Simulated flows from 2002 to 2010 at five timesteps were compared with observed flows for four nested subwatersheds of the Neuse River basin in North Carolina (21‐, 203‐, 2979‐, and 10 100‐km² watershed area), using a multi‐objective function, informal likelihood‐weighted calibration approach. Across watersheds and timesteps, total gauge precipitation was greater than radar precipitation, but radar data showed a conditional bias of higher rainfall estimates during large events (>25–50 mm/day). Model parameterization differed between calibrations with the two datasets, despite the fact that all watershed characteristics were the same across simulation scenarios. This underscores the importance of linking calibration parameters to realistic processes. SWAT simulations with both datasets underestimated median and low flows, whereas radar‐based simulations were more accurate than gauge‐based simulations for high flows. At coarser timesteps, differences were less pronounced. Our results suggest that modelling efforts in watersheds with poor rain gauge coverage can be improved with MPE radar data, especially at short timesteps. Published 2013. This article is a U.S. Government work and is in the public domain in the USA.     

Barrier island response to late Holocene climate events, North Carolina, USA

The Outer Banks barrier islands of North Carolina, USA, contain a geologic record of inlet activity that extends from ca. 2200 cal yr BP to the present, and can be used as a proxy for storm activity. Optically stimulated luminescence (OSL) dating (26 samples) of inlet-fill and flood tide delta deposits, recognized in cores and geophysical data, provides the basis for understanding the chronology of storm impacts and comparison to other paleoclimate proxy data. OSL ages of historical inlet fill compare favorably to historical documentation of inlet activity, providing confidence in the technique. Comparison suggests that the Medieval Warm Period (MWP) and Little Ice Age (LIA) were both characterized by elevated storm conditions as indicated by much greater inlet activity relative to today. Given present understanding of atmospheric circulation patterns and sea-surface temperatures during the MWP and LIA, we suggest that increased inlet activity during the MWP responded to intensified hurricane impacts, while elevated inlet activity during the LIA was in response to increased nor'easter activity. A general decrease in storminess at mid-latitudes in the North Atlantic over the last 300 yr has allowed the system to evolve into a more continuous barrier with few inlets.     

Urban vulnerability to temperature-related hazards: A meta-analysis and meta-knowledge approach

Research on urban vulnerability has grown considerably during recent years, yet consists primarily of case studies based on conflicting theories and paradigms. Assessing urban vulnerability is also generally considered to be context-dependent. We argue, however, that it is possible to identify some common patterns of vulnerability across urban centers and research paradigms and these commonalities hold potential for the development of a common set of tools to enhance response capacity within multiple contexts. To test this idea we conduct an analysis of 54 papers on urban vulnerability to temperature-related hazards, covering 222 urban areas in all regions of the world. The originality of this effort is in the combination of a standard metaanalysis with a meta-knowledge approach that allows us not only to integrate and summarize results across many studies, but also to identify trends in the literature and examine differences in methodology, theoretical frameworks and causation narratives and thereby to compare “apples to oranges.” We find that the vast majority of papers examining urban vulnerability to temperature-related hazards come from an urban vulnerability as impact approach, and cities from middle and low income countries are understudied. One of the challenges facing scholarship on urban vulnerability is to supplement the emphasis on disciplinary boxes (e.g., temperature–mortality relationships) with an interdisciplinary and integrated approach to adaptive capacity and structural drivers of differences in vulnerability.     

Overbank block-and-ash flow deposits and the impact of valley-derived, unconfined flows on populated areas at Merapi volcano, Java, Indonesia

Merapi, an andesitic volcanic complex in Central Java, is one of the most frequently erupting volcanoes in Indonesia and poses a permanent threat to the surrounding population of over 1 million people. With frequently recurring volcanic activity, the sixty or so reported eruptions since the mid-1500s have caused ~7,000 fatalities and destroyed numerous villages in the region. In June 2006, an eruption affected the densely populated area on the volcano’s southern and south-eastern flanks for the first time in almost a century. The resultant block-and-ash flows (BAFs) travelled down an incised river valley (Kali Gendol) to a distance of 7 km from the source, breaking out of the main channel at four main locations. Unconfined (overbank) BAFs were generated, which covered the interfluve regions on either side of the main valley and buried buildings and other infrastructure features in the village of Kaliadem, situated on the western bank of the Gendol valley ~5 km from the summit of Merapi. Using traditional volcanological field-based methods and non-invasive, high-resolution ground-penetrating radar techniques, the morphology and internal architecture of these overbank deposits were studied in detail in order to evaluate the destructive impact of these flows in a local context. The results show that complex, local-scale variations in flow dynamics and deposit architectures are apparent and that BAFs are capable of transporting significant numbers of large blocks (>1–2 m) out of the valley confines. We propose a conceptual model for the escape of these channelised BAFs onto the interfluvial terrace at Kaliadem and show, through a stratigraphic analysis of the pyroclastic successions underlying the village and adjacent areas on the volcano’s southern flank, that the area has been affected repeatedly by overbank BAFs and explosive eruptions over the past few 100 years (and more).     

Geochemistry and hydrology of perched groundwater springs: assessing elevated uranium concentrations at Pigeon Spring relative to nearby Pigeon Mine,Arizona (USA)

The processes that affect water chemistry as the water flows from recharge areas through breccia-pipe uranium deposits in the Grand Canyon region of the southwestern United States are not well understood. Pigeon Spring had elevated uranium in 1982 (44 μg/L), compared to other perched springs (2.7–18 μg/L), prior to mining operations at the nearby Pigeon Mine. Perched groundwater springs in an area around the Pigeon Mine were sampled between 2009 and 2015 and compared with material from the Pigeon Mine to better understand the geochemistry and hydrology of the area. Two general groups of perched groundwater springs were identified from this study; one group is characterized by calcium sulfate type water, low uranium activity ratio ²³⁴U/²³⁸U (UAR) values, and a mixture of water with some component of modern water, and the other group by calcium-magnesium sulfate type water, higher UAR values, and radiocarbon ages indicating recharge on the order of several thousand years ago. Multivariate statistical principal components analysis of Pigeon Mine and spring samples indicate Cu, Pb, As, Mn, and Cd concentrations distinguished mining-related leachates from perched groundwater springs. The groundwater potentiometric surface indicates that perched groundwater at Pigeon Mine would likely flow toward the northwest away from Pigeon Spring. The geochemical analysis of the water, sediment and rock samples collected from the Snake Gulch area indicate that the elevated uranium at Pigeon Spring is likely related to a natural source of uranium upgradient from the spring and not likely related to the Pigeon Mine.     

Measurement and calculation of OH reactivity at a United Kingdom coastal site

Measurements of OH reactivity were made at the Weybourne Atmospheric Observatory on the North Norfolk coast, UK in May 2004. A wide range of supporting species was also measured concurrently as part of the TORCH-2 field campaign, allowing a detailed study of the OH oxidation chemistry to be carried out. Measurements were made in a variety of air masses, with the 3 most prevalent being air from the Atlantic that arrived at the site from over mainland UK in a South Westerly direction, and much cleaner Northerly air that originated over the far North Sea or Arctic, passed over the North Sea and arrived at the site from a North/North Easterly direction. Direct OH reactivity measurements were made on 6 days during the campaign and with influence of 2 of the 3 air masses prevalent during the study period. The average, minimum and maximum measured OH reactivity are: 4.9, 1.3 and 9.7 respectively. The measured OH reactivity was compared to key OH sinks such as NO₂ and CO and a general positive correlation was observed. OH reactivity (k′) was then calculated using the full range of OH sinks species that were measured (including >30 NMHCs) and their pseudo first order rate constants for reaction with OH. For much of the measurement period there is a significant difference between the measured and calculated k′, with an average value of k′_meas- k′_calc?=?1.9 s^-1, indicative of unmeasured OH sinks. A zero-dimensional box model containing a subset of the Master Chemical Mechanism was used to calculate the OH reactivity more accurately. The simultaneously measured trace species were used as inputs to the model and their oxidative degradation was described by a chemical mechanism containing ~5,000 species. The extra OH sinks species produced by the model, resulted in an improvement in the agreement between k′_meas and k′_calc, however the averaged missing OH reactivity across the entire measurement period remained at 1.4 s^-1. Speculation is made as to the source of this missing reactivity, including reference to studies showing that a potentially large number of high molecular weight aromatic species could be unmeasured by standard instrumentation.     

Transient impacts of Little Ice Age glacier expansion on sedimentation processes at glacier-dammed Iceberg Lake, southcentral Alaska

Iceberg Lake, a glacier-dammed proglacial lake in southern Alaska, contains a 1,500+ year varve record complicated by a history of episodic lake-level changes associated with fluctuations in ice-dam thickness and position. To better understand the basinwide glaciolacustrine response to late Holocene climate variability, we collected five cores from two areas in the lake, including a previously unexamined deepwater area distal from inlet streams. Based on eight AMS ¹⁴C dates, and correlations among our cores and previously documented outcrops, we describe ~1,000?years of stratigraphy from each area. Deposition at both areas was dominated by fine-grained varves, but cores from the distal area uniquely contain coarser deposits, including rhythmites and graded sand beds, that we attribute to deposition of a subaqueous outwash fan-delta between ~1250 and 1650 AD. We attribute this event to thickening of the impounding glacier and consequent incursion of the glacier margin, and an associated lateral moraine, into the lake. This result suggests an early onset of the Little Ice Age (LIA) glacial advance in this region. Changes in basinwide circulation and sedimentation associated with this event probably caused minor thickening of varves used previously to reconstruct summer temperatures, reducing sensitivity of that record to early LIA cooling. The basinwide impact of this event illustrates the potentially significant spatial and temporal variability of lacustrine sedimentary processes in dynamic glacial landscapes.