Experimental Study of Factors Controlling Sorption of Heavy Metals on Ariake Clay and Implication for Practice

A series of batch tests have been presented to investigate the effects of solid-solution contact time, solid:solution ratio, and pH of solution on sorption of Cd²⁺ and Pb²⁺ on Ariake clay from Kyushu region of Japan. The results show that, among the three investigated factors, solid:solution ratio (SD/SN) seems to be the crucial controlling factor. The Freundlich sorption parameters determined from the batch tests were applied to a typical field landfill in which the Ariake clay was used as soil barrier. The impacts of the landfill were assessed by numerical analysis. Based on the analysis result, the significance of selecting proper solid:solution ratio for determining sorption parameters from batch test has been discussed.     

Physical and elastic properties of marine sediments off Bombay,India

Abstract

Keeping in view the paucity of information as to the nature of the marine sediments from the continental shelf adjoining the Indian subcontinent, a number of shallow seismic surveys were carried out, nearshore and offshore Bombay between 18°45'N and 21°00'N. Representative core samples preserving their natural state were also retrieved from the region in the water depths ranging from 5 to 70 m for the determination of physical properties in the laboratory. Data on the physical, acoustic, and elastic properties of the sediment cores are reported for the first time. Useful individual least‐squares relations are presented for acoustic impedance, reflection coefficient, and bulk modulus against density; for the dependence of rigidity and bulk moduli on the constrained modulus; for the association between impedance and field sediment velocity against P‐velocity; and for rigidity against Poisson's ratio. Results indicate that the bulk modulus and Young's modulus are higher for silty clay and clayey silt samples than for the clay samples. Similarly, the acoustic impedance, reflection coefficient, and constrained modulus of silty clay and clayey silt are also higher than clay. The results are found to be comparable to the North Atlantic and Bay of Bengal sediments.     

Acoustic Monitoring of Gas Emission Processes in the Arctic Shelf Seas

Oceanology - The emission of natural gas from the seafloor to the surface in shelf areas of the Arctic seas is of increasing interest among researchers. Recently, various types of acoustic...     

Robust diagnostic modeling of the Japan Sea circulation

The Japan Sea circulation is numerically modeled with robust diagnostic terms included. The general features are nearly the same as previous prognostic models though small differences appear in local current fields, and agree with most of existing observation results. This model, however, seems to be more successful than prognostic ones in that the overshooting of the East Korean Warm Current, a northward western boundary current, is much reduced and the North Korean Cold Current, a southward western boundary current, is more enhanced. Based on the model results, discussions are made about the large convective structure and the global kinetic energy budget of the Japan Sea circulation.     

High-resolution well-log derived dielectric properties of gas-hydrate-bearing sediments, Mount Elbert Gas Hydrate Stratigraphic Test Well, Alaska North Slope

A dielectric logging tool, electromagnetic propagation tool (EPT), was deployed in 2007 in the BPXA-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well (Mount Elbert Well), North Slope, Alaska. The measured dielectric properties in the Mount Elbert well, combined with density log measurements, result in a vertical high-resolution (cm-scale) estimate of gas hydrate saturation. Two hydrate-bearing sand reservoirs about 20 m thick were identified using the EPT log and exhibited gas-hydrate saturation estimates ranging from 45% to 85%. In hydrate-bearing zones where variation of hole size and oil-based mud invasion are minimal, EPT-based gas hydrate saturation estimates on average agree well with lower vertical resolution estimates from the nuclear magnetic resonance logs; however, saturation and porosity estimates based on EPT logs are not reliable in intervals with substantial variations in borehole diameter and oil-based invasion.EPT log interpretation reveals many thin-bedded layers at various depths, both above and below the thick continuous hydrate occurrences, which range from 30-cm to about 1-m thick. Such thin layers are not indicated in other well logs, or from the visual observation of core, with the exception of the image log recorded by the oil-base microimager. We also observe that EPT dielectric measurements can be used to accurately detect fine-scale changes in lithology and pore fluid properties of hydrate-bearing sediments where variation of hole size is minimal. EPT measurements may thus provide high-resolution in-situ hydrate saturation estimates for comparison and calibration with laboratory analysis.     

A review of the equations used to predict the velocity distribution within a ship’s propeller jet

Predicting the velocity within the ship’s propeller jet is the initial step to investigate the scouring made by the propeller jet. Albertson et al. (1950) suggested the investigation of a submerged jet can be undertaken through observation of the plain water jet from an orifice. The plain water jet investigation of Albertson et al. (1950) was based on the axial momentum theory. This has been the basis of all subsequent work with propeller jets. In reality, the velocity characteristic of a ship’s propeller jet is more complicated than a plain water jet. Fuehrer and Römisch (1977), Blaauw and van de Kaa (1978), Berger et al. (1981), Verhey (1983) and Hamill (1987) have carried out investigations using physical model. Current paper reviews the state-of-art of the equations used to predict the time-averaged axial, tangential and radial components of velocity within the zone of flow establishment and the zone of established flow of a ship’s propeller jet.     

Nonlinear transfer function modelling of beach morphology at Duck,North Carolina

This paper presents a simple nonlinear data-based modelling approach for predicting the beach profile volume at Duck, North Carolina, USA. The state-dependent parameter form of the general transfer function (SDP TF) model is used to describe nonlinearity influencing these morphological data in two case examples. Case 1 investigates the nonlinearity associated with the dependency of wave forcing on the preceding beach volume. Case 2 investigates the ability to model the variables within the well-known diffusion equation for beach volume using this data-based approach. The results of this study show that the SDP TF approach can be used successfully to develop statistically robust models for describing nonlinearity in beach morphological systems. Furthermore, these models are shown to predict the beach volumes over both short (1 month ahead) and long (2 years ahead) time periods, and thus show great potential for practical applications in coastal zone management and engineering.     

Thermodynamic characterization of boltwoodite and uranophane: Enthalpy of formation and aqueous solubility

Boltwoodite and uranophane are uranyl silicates common in oxidized zones of uranium ore deposits. An understanding of processes that impact uranium transport in the environment, especially pertaining to the distribution of uranium between solid phases and aqueous solutions, ultimately requires determination of thermodynamic parameters for such crystalline materials. We measured formation enthalpies of synthetic boltwoodites, K(UO₂)(HSiO₄)·H₂O and Na(UO₂)(HSiO₄)·H₂O, and uranophane, Ca(UO₂)₂(HSiO₄)₂·5H₂O, by high temperature oxide melt solution calorimetry. We also studied the aqueous solubility of these phases from both saturated and undersaturated conditions at a variety of pH. The combined data permit the determination of standard enthalpies, entropies and Gibbs free energies of formation for each phase and analysis of its potential geological impact from a thermodynamic point of view.     

绿潮迁移过程中环境要素与浒苔藻体生物学特征的相关性分析

浒苔(Ulva prolifera)引起的大规模绿潮起源于黄海南部,在向北迁移过程中生物量迅速扩增,在海州湾附近(35°N左右)迅速增加达到峰值.在绿潮漂浮迁移过程中,海水表层温度、溶解无机氮(dissolved inorganic nitrogen,DIN)和磷酸盐(PO43--P)变化显著.本文以迁移过程中的浒苔为...     

小兴安岭东段晚古生代花岗岩体的厘定及其地质意义

通过LA-ICP-MS锆石U-Pb定年和岩石地球化学分析,研究了小白金河岩体的形成年代和地球化学特征。结果表明,小白金河岩体形成于261.7±3.8Ma,为中二叠世末期的侵入体。岩体具有高Si O2、K2O和ALK,低Ca O、Al2O3和Ti O2的特征;具有强烈的负Eu异常;强烈亏损Sr、Ti、V、P等高场强元素,富集K、Rb、Th等大离子亲石元素。研究表明,小白金河岩体属于A型花岗岩,形成于晚古生代弧后裂陷环境。