Geochemistry of the Upper Neoproterozoic and Lower Cambrian siliciclastic rocks and U-Pb dating on detrital zircons in the Central Iberian Zone,Spain

Sandstones and shales from the Upper Neoproterozoic (UN) succession in the Central Iberian Zone (CIZ) show parallel REE patterns and relatively restricted and similar ranges and average values of some element ratios such as Al₂O₃/TiO₂, Ti/Nb, Eu/Eu*, (La/Yb)n, (Gd/Yb)n and Th/U. This remarkable geochemical homogeneity for related medium- and fine-grained rocks is unusual, and strongly suggests a recycled source area. However, the Lower Cambrian (LC) equivalent rocks are, in general terms, geochemically less mature, more heterogeneous and more fractionated. Their average REE patterns are practically coincident, probably as a consequence of REE redistribution related to the reworking of sediments during a stage of sea level fall in Lower Cambrian times. Ti and Zr abundances, chemical index of alteration (CIA) values and element ratios such as Al₂O₃/TiO₂, K/Rb, Ti/Nb and Rb/Zr can be used for discriminating purposes between the UN and LC siliciclastic rocks. Detrital zircons from a UN and a LC sandstone display morphological differences. However, U-Pb data are discordant and cannot be interpreted in a straightforward manner. Nevertheless, age data are compatible with a model in which the continent of Gondwana would have supplied zircons, showing a bimodal age distribution, in variable proportions to the respective sandstone units.     

Present-day and future precipitation in the Baltic Sea region as simulated in a suite of regional climate models

Here we investigate simulated changes in the precipitation climate over the Baltic Sea and surrounding land areas for the period 2071–2100 as compared to 1961–1990. We analyze precipitation in 10 regional climate models taking part in the European PRUDENCE project. Forced by the same global driving climate model, the mean of the regional climate model simulations captures the observed climatological precipitation over the Baltic Sea runoff land area to within 15% in each month, while single regional models have errors up to 25%. In the future climate, the precipitation is projected to increase in the Baltic Sea area, especially during winter. During summer increased precipitation in the north is contrasted with a decrease in the south of this region. Over the Baltic Sea itself the future change in the seasonal cycle of precipitation is markedly different in the regional climate model simulations. We show that the sea surface temperatures have a profound impact on the simulated hydrological cycle over the Baltic Sea. The driving global climate model used in the common experiment projects a very strong regional increase in summertime sea surface temperature, leading to a significant increase in precipitation. In addition to the common experiment some regional models have been forced by either a different set of Baltic Sea surface temperatures, lateral boundary conditions from another global climate model, a different emission scenario, or different initial conditions. We make use of the large number of experiments in the PRUDENCE project, providing an ensemble consisting of more than 25 realizations of climate change, to illustrate sources of uncertainties in climate change projections.     

An intercomparison of regional climate simulations for Europe: assessing uncertainties in model projections

Ten regional climate models (RCM) have been integrated with the standard forcings of the PRUDENCE experiment: IPCC-SRES A2 radiative forcing and Hadley Centre boundary conditions. The response over Europe, calculated as the difference between the 2071–2100 and the 1961–1990 means can be viewed as an expected value about which various uncertainties exist. Uncertainties are measured here by variance in eight sub-European boxes. Four sources of uncertainty can be evaluated with the material provided by the PRUDENCE project. Sampling uncertainty is due to the fact that the model climate is estimated as an average over a finite number of years (30). Model uncertainty is due to the fact that the models use different techniques to discretize the equations and to represent sub-grid effects. Radiative uncertainty is due to the fact that IPCC-SRES A2 is merely one hypothesis. Some RCMs have been run with another scenario of greenhouse gas concentration (IPCC-SRES B2). Boundary uncertainty is due to the fact that the regional models have been run under the constraint of the same global model. Some RCMs have been run with other boundary forcings. The contribution of the different sources varies according to the field, the region and the season, but the role of boundary forcing is generally greater than the role of the RCM, in particular for temperature. Maps of minimum expected 2m temperature and precipitation responses for the IPCC-A2 scenario show that, despite the above mentioned uncertainties, the signal from the PRUDENCE ensemble is significant.     

Evaluation of Simultaneous Analyte Leaching/Vapour Phase Introduction for Direct Osmium Isotope Ratio Measurements in Solid Samples by Double-Focusing Sector Field ICP-MS

The analytical performance of a method for Os isotope ratio measurement by double‐focusing, sector field ICP‐MS (ICP‐SFMS) was evaluated. The method is based on several optimised, concurrent processes: Os extraction from samples in hot concentrated nitric acid; separation of Os from the digest solution by the formation of volatile osmium tetroxide accelerated by continuous hydrogen peroxide addition; transport of analyte vapour by an oxygen flow into the ICP; and isotopic determination by ICP‐SFMS. Due to the very efficient utilisation of analyte (approaching 0.5‰), Os isotope ratio measurement could be performed at low pg levels. Combined with an ability to process sample sizes up to 2 g (up to 50 g if the organic matrix of biological or botanical samples is eliminated by ashing), materials with Os concentrations in the low, or even sub pg g^?1 range could be determined by this method. Given that two complete digestion/distillation systems were available for interchangeable use, throughputs of up to fifteen samples per 8 hour shift could be achieved. The method precision, evaluated as the long‐term reproducibility of ¹⁸⁷ Os/¹⁸⁸Os ratio measurements in a commercial Os reference sample containing 0.5 ng Os, was 0.16% relative standard deviation (RSD, 1s). The method has been applied to perform replicate ¹⁸⁷ Os/¹⁸⁸ Os ratio measurements on a suite of fifty reference materials of various origins and matrix compositions, with Os concentrations varying from < 0.1 pg g^?1 to > 100 ng g^?1, yielding an average precision of 3% RSD. Though none of the materials tested are certified for Os content or Os isotope composition, comparison of the obtained data with published Os isotope information for similar sample types revealed close agreement between the two. The method can also be used for the simultaneous, semi‐quantitative determination of Os concentrations.     

Silica fume stabilization of an expansive clay subgrade and the effect of silica fume-stabilised soil cushion on its CBR

ABSTRACT

Expansive soil subgrades, which are subjected to dual swell-shrink problem consequent upon absorption and evaporation of water, need to be improved by chemical stabilization or compacted cushion or geosynthetic reinforcement in order that pavements constructed over them are even, stable and safe. This paper presents extensive experimental data on plasticity, free swell index (FSI) and compaction characteristics of a highly swelling expansive clay stabilized with varying silica fume contents. In another series of tests on a laterite soil to be used as a cushion over the expansive clay subgrade, plasticity properties, compaction characteristics and strength characteristics were determined at varied silica fume contents. Further, CBR of the expansive clay subgrade was determined in the laboratory stabilizing it with varied silica fume contents and providing a cushion of 50 mm thickness of silica fume-stabilized lateritic soil. Liquid limit (LL), plasticity index (PI) and free swell index (FSI) of the expansive clay decreased with increasing silica fume contents. The compaction and strength characteristics of both the soils improved with silica fume stabilization. The CBR of the expansive clay provided with silica fume-stabilized cushion improved significantly.     

Mobility of Al, Co, Cr, Cu, Fe, Mn, Ni and V in sulphide-bearing fine-grained sediments exposed to atmospheric O2: an experimental study

 The major aim was to increase our knowledge on the behaviour of Al, Co, Cr, Cu, Fe, Mn, Ni and V in sulphide-bearing fine-grained sediments exposed to atmospheric oxygen. Samples of this type of sediment collected in a previous investigation at eight sites in western Finland were digested in HClO₄-HNO₃-HCl-HF at 200  °C and in HCl:HNO₃:H₂O at 95  °C (aqua regia), and subjected to extractions with ammonium acetate and hydrogen peroxide. Metals and S in the leachates were determined with ICP-AES. The results of the chemical analyses are compared with previously reported experimental data. The concentrations of Al and Fe in the sulphide-bearing fine-grained sediments are about 7% and 5%, respectively. Of the trace metals studied, Mn is most abundant followed in decreasing order by V>Cr>Ni>Cu>Co. On oxidation of the sediments, high proportions of Co, Mn and Ni, intermediate proportions of Cu but low proportions of Fe, Al, Cr and V are released. The extent of the release of a metal on oxidation is controlled either by (1) the level to which the pH of the sediments drops on oxidation (Al, Cu, Cr, V), (2) the amount of the metal associated with easily reduced phases (metal sulphides) in the sediments (Ni, Co) or (3) the sum of the amount associated with reduced phases and adsorbed on soil compounds (Mn). No control of the release of Fe on oxidation of the sediments was identified. Based on the results of the study it is argued that artificial drainage and the subsequent oxidation of sulphide-bearing sediments will result in extensive leaching of Co, Mn and Ni, moderate leaching of Cu and limited leaching of Cr and V into drainages. The major elements, Fe and Al, have the potential to be mobilised and leached in large amounts, though the proportions mobilised/leached will remain low. It is suggested that the identification of sulphide-bearing sediments with a high potential of metal release should be based on determination of metals in easily mobilised reduced compounds (dissolved e.g. in H₂O₂) and of the level to which the pH of the sediments drops on oxidation. Received: 16 October 1997 · Accepted: 9 March 1998     

О ВЗАИМОДЕЙСТВИИ МЕЖДУ ВЫСОТНЫМИ АТМОСФЕРНЫМИ ВИХРЯМИ И НАЗЕМНЫМ ТЕЧЕНИЕМ

Summary It is shown that non-divergent vortices may induce, as a result of the resonance effect, a rapid surface development.     

ТЕОРИЯ ВОЗНИКНОВЕНИЯ КВАЗИДВУХЛЕТНЕГО ЦИКЛА В АТМОСФЕРЕ

a aamaa ¶rt;uaua mu ¶rt;n nauuu a mu mu u ¶rt;uau uma am. m muu mam, m au¶rt;mu u au uuu am a mnuuu nau ¶rt;au. a a mu na an¶rt; aumuu mum ama, m am um m nu¶rt;u au u uu au¶rt;m ua.     

Geothermal investigations in the Bohus granite area in southwestern Sweden

Heat generation and heat flow were determined for the Bohus granite massif in western Sweden. This is the start of a major program concerning geothermal energy in Sweden. Neutron activation analyses, temperature measurements, thermal conductivity measurements have been carried out. As was expected the result, 76 mW m⁻², shows that even old Precambrian shields locally exhibit much higher values than normal.     

Arsenopyrite and sphalerite as T-P indicators in sulfide ores from northern Sweden

The compositions of arsenopyrite and sphalerite from five Swedish metamorphosed Cu, Zn-sulfide deposits are related to T and P, according to the methods described by Kretschmar and Scott (1976) and Scott (1973). The As/S ratio of arsenopyrite indicates an equilibrium temperature around 400°C for all the deposits studied, whereas the sphalerite barometer shows pressures between 5 and 7 kb. The mineral assemblages of the bedrocks indicate a similar temperature but a lower pressure. A constant fs2 is probably only effective over distances of millimetres or a few centimetres in the samples studied. The fs2 has always been lower in the surrounding rocks than in the ores as indicated by a higher As/S in arsenopyrite, more FeS in sphalerites and the absence of pyrite.