The Hatton Bank continental margin—I. Shallow structure from two-ship expanding spread seismic profiles

Summary. The Hatton Bank passive continental margin exhibits thick seaward dipping reflector sequences which consist of basalts extruded during rifting between Greenland and Rockall Plateau. Multichannel seismic reflection profiling across the margin reveals three reflector wedges with a maximum thickness near 7 km, extending from beneath the upper continental slope to the deep ocean basin. We present results of the velocity structure within the dipping reflector sequences at eight locations across the margin, interpreted by synthetic seismogram modelling a set of multichannel expanding spread profiles parallel to the margin. At the top of some reflector sequences, we observe a series of 100 m thick high- and low-velocity zones, which are interpreted as basalt flows alternating with sediments or weathered and rubble layers. At the profile locations, the base of the dipping reflectors correlates with P -wave velocities near 6.5 km s⁻¹. However, elsewhere the reflectors appear to extend significantly deeper than the inferred 6.5 km s⁻¹ velocity contour, indicating that the velocity structure may not be controlled solely by lithological boundaries but also by metamorphic effects. Shear-waves were observed on two lines, permitting the calculation of Poisson's ratio. The decrease in Poisson's ratio from 0.28 to near 0.25 in the upper 5 km of crust may also indicate the effect of metamorphism on seismic properties, or alternatively may be explained by crack closure under load.     

Gravity studies of the Rockall and Exmouth Plateaux using SEASAT altimetry

Abstract SEASAT altimetric measurements are used to determine the gravity anomalies across two passive continental margins: the western margin of the Rockall Plateau, UK, and the Exmouth Plateau off north-west Australia. The small gravity anomalies observed over the starved western margin of the Rockall Plateau require the existence of a major density contrast within the crust, as well as the Moho, and show that the elastic thickness is less than 5 km at the time of rifting. The gravity anomaly over the Exmouth Plateau is compared with the gravity anomaly calculated from the sediment loading of a thin elastic plate, taking account of the variation in crustal thickness. This comparison shows that the Exmouth Plateau also has a small effective elastic thickness of 5 km, even for loads emplaced between 60 and 120 Myr after rifting. Elastic thicknesses of about 5 km have also been reported for other sedimentary basins, and are to be expected if the rheological properties of the crust and mantle depend on the ratio of the present temperature to the melting temperature. Flexural effects are therefore likely to be of minor importance in sedimentary basins.     

Thermochronology of the Yidun Arc, central eastern Tibetan Plateau: constraints from Ar/Ar K-feldspar and apatite fission track data

Four K-feldspar samples from the Yidun Arc, eastern Tibetan Plateau, were analysed by the ⁴⁰Ar/³⁹Ar method with the aim of recovering information on their thermal history using multiple diffusion domain (MDD) theory. Arrhenius plots for each of the samples reveal low retentivity early in the heating experiments, a property that is attributed to their recrystallised nature. This low argon retentivity appears to violate the MDD assumption that volume diffusion is the only mechanism for argon transport within the crystals, thus the thermal histories derived from these analyses are considered suspect. Nevertheless, the age spectra themselves suggest that the majority of samples had cooled below 200 °C prior to the Eocene collision of India with Asia. Thermal history modelling from apatite fission track analyses from the same and nearby samples shows slow cooling through the apatite fission track partial annealing zone during the Cenozoic in samples from the high elevation, low relief areas of the Yidun Arc, while samples from the major Jinsha River valley show rapid cooling through the partial annealing zone beginning in the Miocene. These results suggest that significant Cenozoic denudation has been localised and that most parts of the Yidun Arc have experienced very little denudation during the Cenozoic.     

Oceanic crustal structure—Mid-Atlantic Ridge at 45° N

Summary. We present a velocity—depth model for the crust beneath the Mid-Atlantic Ridge at 45° N which is derived from a comparison of waveforms corresponding to observed and synthetic seismograms. The model which best fits the observations includes a high-velocity layer at the base of the crust (layer 3B) and a velocity gradient in the upper mantle. These results are in agreement with other recent seismic studies on the Mid-Atlantic Ridge and indicate that the velocity structure is more complex than that obtained from travel-time analysis. There is no evidence for a low-velocity zone at the base of the crust.     

Transfer and distribution of lead in the asteroid Asterias rubens following ingestion of contaminated food: a radiotracer study

A radiotracer technique using 210Pb was applied to quantify the transfer and distribution of lead in the asteroid Asterias rubens following a single ingestion of radio-labelled mussels under controlled laboratory conditions. Approximately 50% of the 210Pb accumulated by mussels in their soft tissues from seawater was transferred to the asteroid through the food pathway resulting in a transfer factor less than unity. Loss kinetics of 210Pb in the asteroid were best described by a two-component exponential model. A. rubens eliminated 56% +/- 5% of the ingested 210Pb in a few days while the remaining fraction (42% +/- 5%), was absorbed and eliminated very slowly. Following ingestion, 210Pb was accumulated in the pyloric caeca and the body wall with little radioisotope found in the coelomic fluid. Lead-210 was then transferred to the organic matrix of the body wall through the general body cavity via the coelomic fluid, and then to the skeleton. In this way, lead appears to be progressively eliminated from the organic matrix of the body wall while it is efficiently trapped in the calcite skeleton. The sequestration and retention of lead in the skeleton is considered as a detoxification process, but it also prevents lead transfer to higher trophic levels of the marine food chain since the skeleton is not digested by higher consumers. In addition, the skeleton of asteroids can be regarded as a bioindicator of long-term dietary lead contamination.     

Effects of PCBs on reactive oxygen species (ROS) production by the immune cells of Paracentrotus lividus (Echinodermata)

The impact of four PCB congeners: 3,3',4,4'-tetrachlorobiphenyl (IUPAC congener #77), 3,3',4,4',5-pentachlorobiphenyl (IUPAC #126), 2,2',4,4',5,5'-hexachlorobiphenyl (IUPAC #153) and 3,3',4,4',5,5'-hexachlorobiphenyl (IUPAC #169) was investigated on the reactive oxygen species (ROS) production by coelomocytes of the echinoid Paracentrotus lividus, an important species in marine benthic ecosystems. PCBs were found to increase ROS production and to delay the time of peak production. These effects were stronger on bacteria-stimulated cells and were congener-specific: coplanar congeners (#77, 126 and 169) had more effect than the non-coplanar PCB #153. Among coplanar congeners, PCB #169 showed dose-dependent effects whereas PCB #77 and 126 were more toxic at high and low doses, respectively. The relative immunotoxicity of the different PCB congeners is discussed in the light of their structural properties and biological affinities.     

Biota: sediment partitioning of aluminium smelter related PAHs and pulp mill related diterpenes by intertidal clams at Kitimat, British Columbia

The question of polycyclic aromatic hydrocarbon (PAH) bioavailability and its relationship to specific PAH sources with different PAH binding characteristics is an important one, because bioavailability drives PAH accumulation in biota and ultimately the biochemical responses to the PAH contaminants. The industrial harbour at Kitimat (British Columbia, Canada) provides an ideal location to study the bioavailability and bioaccumulation of sediment hydrocarbons to low trophic level biota. Samples of soft shell clams (Mya arenaria) and intertidal sediment collected from multiple sites over six years at various distances from an aluminium smelter and a pulp and paper mill were analysed for 106 PAHs, plant diterpenes and other aromatic fraction hydrocarbons. Interpretation using PAH source ratios and multivariate data analysis reveals six principal hydrocarbon sources: PAHs in coke, pitch and emissions from anode combustion from the aluminium smelter, vascular plant terpenes and aromatised terpenes from the pulp and paper mill, petroleum PAHs from shipping and other anthropogenic activities and PAHs from natural plant detritus. Harbour sediments predominantly contain either pitch or pyrogenic PAHs from the smelter, while clams predominantly contain plant derived PAHs and diterpenes from the adjacent pulp mill. PAHs from the smelter have low bioavailability to clams (Biota-Sediment Accumulation Factors; BSAFs <1 for pitch and coke; <10 for anode combustion, decreasing to ∼0.1 for the mass 300 and 302 PAHs), possibly due to binding to pitch or soot carbon matrices. Decreases in PAH isomer ratios between sediments and clams likely reflect a combination of variation in uptake kinetics of petroleum PAHs and compound specific metabolism, with the importance of petroleum PAHs decreasing with increasing molecular weight. Plant derived compounds exhibit little natural bioaccumulation at reference sites, but unsaturated and aromatised diterpenes released from resins by industrial pulping processes are readily accumulated by the clams (BSAFs >500). Thus while most of the smelter associated PAHs in sediments may not be bioavailable to benthic organisms, the plant terpenes (including retene, totarol, ferruginol, manool, dehydroabietane and other plant terpenes that form the chemical defence mechanism of conifers) released by pulp mills are bioavailable and possess demonstrated toxic properties. The large scale release of plant terpenes by some of the many pulp mills located in British Columbia and elsewhere represents a largely undocumented risk to aquatic biota.     

Dynamics of particle flux and carbon export in the northwestern Mediterranean Sea: A two decade time-series study at the DYFAMED site

The DYFAMED time-series station, located in the open Ligurian Sea, is one of the few pluriannual flux programs in the world and the longest in the Mediterranean Sea. The trap data series is one of only three multi-decadal data sets in existence, and it provides flux information for an environment that is distinct from the other long-term data sets. At DYFAMED, downward fluxes of particles, carbon and other major elements have been regularly measured with sediment traps since 1986 at fixed depths of 200 and 1000 m. An overview is presented of the main trends of particle and carbon fluxes observed during the period 1988–2005, period when the mooring was located on the northern side of the Ligurian Sea. In spite of considerable interannual variability, fluxes displayed a marked seasonal pattern with the highest fluxes occurring during winter and spring and lowest fluxes throughout the stratified season (summer–autumn). Organic carbon fluxes measured at both depths were highly variable over time, ranging from 0.3 to 59.9 (mean 6.8) mg C m⁻² d⁻¹ at 200 m, and from 0.2 to 37.1 (mean 4.3) mg C m⁻² d⁻¹ at 1000 m. Mass fluxes were maximal in winter, whereas carbon fluxes were maximal in late spring. Reasonably good agreement existed between particle fluxes at both depths over the years, indicating a relatively efficient and rapid transport of particles from the upper ocean to the deep sea. However, during certain periods mass flux increased with depth suggesting lateral inputs of particles that by-pass the upper trap. Since 1999, the system has apparently shifted towards an increasing occurrence of extreme flux events in response to more vigorous mixing of the water column during the winter months. Although annual mass fluxes have increased in the last years, mean POC fluxes have not substantially changed over time, due mainly to lower carbon contents of the sinking particles during maxima of mass flux.     

Large-scale dynamics have greater role than thermodynamics in driving precipitation extremes over India

Climate Dynamics - The changing characteristics of precipitation extremes under global warming have recently received tremendous attention, yet the mechanisms are still insufficiently understood....