Making ends meet, in the household and on the planet

Policy-making in relation to sustainable development is usually at the national (or, in relation to climate change, the global) level, yet the consumption it seeks to modify takes place at the household level. If households all ‘made ends meet’ in the same way then the much-relied upon notion of per capita consumption would be valid and we could rely on ‘top-down’ modelling to guide policy. Cultural Theory, however, predicts that there are five socially viable ways of making ends meet, and that all of them will be found (in varying proportions) within any nation. This prediction has been tested on a sample of 220 British households and shown to be well supported. Top-down modelling, it is argued, has to give way to a constructive interplay between the reflexive policy-maker and a plurally responsive citizenry. This revised version was published online in August 2006 with corrections to the Cover Date.     

Authigenic albite in carbonate rocks – a tracer for deep-burial brine migration?

Euhedral, post-depositional albite from the Eastern and Western Alps, the western Carpathians and some Greek islands was examined petrographically and geochemically to gain insights into the nature of feldspar reactions in carbonate rocks. This study focuses on coarsely crystalline, homogeneously nucleated albite in order to avoid problems related to the presence of inseparable detrital material in fine-grained albite varieties. All albite samples show a very restricted compositional variability and are typically ≥ 99 mol% Ab component. Unit-cell parameters determined by Rietveld analysis are slightly more variable than previously accepted, but confirm high Al–Si ordering characteristic of low albite. The oxygen isotopic composition of albite ranges from + 19·4‰ to + 28·3‰ VSMOW. There is no direct relationship between the δ¹⁸O value and the inferred temperature of albite formation, nor is there one with stoichiometry. The coarse crystal size (up to several millimetres in diameter), petrographic evidence showing albite cross-cutting stylolites, greater abundance of albite in carbonate rocks subject to high-grade diagenetic or weak metamorphic overprinting and available fluid inclusion data suggest that albite precipitation is favoured at higher temperatures in carbonates than in sandstones. Pore fluids were invariably brines, as suggested by the inferred high positive δ¹⁸O_fluid values, the common association of albite-bearing carbonates and evaporites and reports of saline fluid inclusions in albite. The presence of authigenic albite may thus be a useful tracer of palaeobrine–carbonate reactions, particularly in deep-burial and incipient metamorphic settings.     

Seasonal and interannual variability of phytoplankton pigment in the Laccadive (Lakshadweep) Sea as observed by the Coastal Zone Color scanner

Based on Coastal Zone Color Scanner data from November 1978 through December 1981, the seasonal cycle of phytoplankton pigment in the upper part of the euphotic zone is established for the offshore Laccadive Sea. Year-round, the pigment content is low and the seasonal range is small, following the pattern of the nutrient-poor Arabian Sea to the west. Apparently, indigenous phytoplankton blooms are absent. July and August, however, were poorly studied because of cloud cover. Interannual differences during the northeast monsoon and the spring intermonsoon periods are minor. The abundant phytoplankton caused by the upwelling off India during the southwest monsoon remains essentially restricted to the shelf, but there are occasional large, zonal outbreaks into the Laccadive Sea, as well as others advected to the south of India. Visual inspection of the raw CZCS scenes for June through November 1982–1985, with almost no data until August or even September, shows such outbreaks of pigment-rich water to be common. Inspection of monthly SeaWiFS images for 1997 through part of 2001 confirms the absence of indigenous phytoplankton blooms.     

TRANSALP—deep crustal Vibroseis and explosive seismic profiling in the Eastern Alps

The TRANSALP consortium, comprising institutions from Italy, Austria and Germany, carried out deep seismic reflection measurements in the Eastern Alps between Munich and Venice in 1998, 1999 and 2001. In order to complement each other in resolution and depth range, the Vibroseis technique was combined with simultaneous explosive source measurements. Additionally, passive cross-line recording provided three-dimensional control and alternative north–south sections. Profits were obtained by the combination of the three methods in sectors or depths where one method alone was less successful.The TRANSALP sections clearly image a thin-skinned wedge of tectonic nappes at the northern Alpine front zone, unexpected graben or half-graben structures within the European basement, and, thick-skinned back-thrusting in the southern frontal zone beneath the Dolomite Mountains. A bi-vergent structure at crustal scale is directed from the Alpine axis to the external parts. The Tauern Window obviously forms the hanging wall ramp anticline above a southward dipping, deep reaching reflection pattern interpreted as a tectonic ramp along which the Penninic units of the Tauern Window have been up-thrusted.The upper crystalline crust appears generally transparent. The lower crust in the European domain is characterized by a 6–7 km thick laminated structure. On the Adriatic side the lower crust displays a much thicker or twofold reflective pattern. The crustal root at about 55 km depth is shifted around 50 km to the south with respect to the main Alpine crest.     

New aromatic biomarkers and possible maturity indicators found in New Albany Shale extracts

Aromatic hydrocarbons from benzene extracts of New Albany Shale were characterized. A biomarker that has a molecular weight of 546 and a structural configuration consistent with that of an alkyl-aromatic hydrocarbon (C₄₀H₆₆) was tentatively identified. It was found that the relative concentrations of the biomarker are indicative of differing levels of thermal maturity of the shale organic matter. A 40-carbon bicyclic carotenoid (C₄₀H₄₈) is proposed as the geochemical precursor of this biomarker. Thermal maturity of the shale organic matter can also be differentiated by observing differences in “fingerprints” as obtained by field-ionization mass spectrometry on the aromatic hydrocarbon fraction. Using this technique, we found that the more mature shale samples from southeastern Illinois contain more low molecular weight extractable aromatic hydrocarbons and the less mature shale samples from northwestern Illinois contain more high molecular weight extractable aromatic hydrocarbons. It was demonstrated that field-ionization and tandem mass spectrometric techniques through fingerprint and individual compound identification, are useful for shale aromatic hydrocarbon fraction characterization and for thermal maturation interpretation.     

Zur Stratigraphie der grobklastischen Fazies im Oxfordium des Wiehengebirges

Zusammenfassung Der Fund vonPeltoceratoides instabiliformis n. sp. in Steinbrüchen am Gehn nordwestlich von Osnabrück (Abb. 3) liefert weitere Kriterien, daß der Wiehengebirgssandstein, dessen stratigraphische Stellung wegen Mangel charakteristischer Fossilien unsicher ist, ins höhere Oxfordium zu stellen ist. Diese grobklastische Fazies vertritt im Wiehengebirge im wesentlichen die für das Wesergebirge typische kalkige Fazies des Korallenooliths. Anschließend wird zu einer neueren paläogeographischen Mitteilung über den Korallenoolith Nordwestdeutschlands kurz Stellung genommen.

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In quarries at the Gehn NW of Osnabrück, several specimens ofPeltoceratoides instabiliformis n. sp. have been found. This gives further indications to the stratigraphic position of the Wiehengebirgs sandstone — which is uncertain, due to the lack of characteristic fossils — to be of Upper Oxfordian age. In the Wiehengebirge though, this coarse clastic facies substitutes to a large extent the calcareous facies of the Korallenoolith typical for the Wesergebirge.A recent paleogeographic report on the Korallenoolith of NW-Germany is then briefly discussed.

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Résumé LesPeltoceratoides instabiliformis n. sp. découverts dans des carrières du Gehn au nord-ouest d'Osnabrück fournissent d'autres indices affirmant que le grès du Wiehengebirge dont la position stratigraphique est incertaine faute de fossiles caractéristiques doit être attribué à l'Oxfordien supérieur. Dans le Wiehengebirge, ce faciès clastique à grain grossier remplace dans l'essentiel le faciès calcaire du Korallenoolith typique pour le Wesergebirge.Il suit une brève critique d'une communication paléogéographique récemment parue sur le Korallenoolith du Nord-Ouest de l'Allemagne.

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. Peltoceratoides instabiliformis n. sp. . . , . - .

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Herrn Professor Dr.Roland Brinkmann zum 70. Geburtstag gewidmet.     

A Bayesian approach to inverse modelling of stratigraphy, part 1: method

The inference of ancient environmental conditions from their preserved response in the sedimentary record still remains an outstanding issue in stratigraphy. Since the 1970s, conceptual stratigraphic models (e.g. sequence stratigraphy) based on the underlying assumption that accommodation space is the critical control on stratigraphic architecture have been widely used. Although these methods considered more recently other possible parameters such as sediment supply and transport efficiency, they still lack in taking into account the full range of possible parameters, processes, and their complex interactions that control stratigraphic architecture. In this contribution, we present a new quantitative method for the inference of key environmental parameters (specifically sediment supply and relative sea level) that control stratigraphy. The approach combines a fully non‐linear inversion scheme with a ‘process–response’ forward model of stratigraphy. We formulate the inverse problem using a Bayesian framework in order to sample the full range of possible solutions and explicitly build in prior geological knowledge. Our methodology combines Reversible Jump Markov chain Monte Carlo and Simulated Tempering algorithms which are able to deal with variable‐dimensional inverse problems and multi‐modal posterior probability distributions, respectively. The inverse scheme has been linked to a forward stratigraphic model, BARSIM (developed by Joep Storms, University of Delft), which simulates shallow‐marine wave/storm‐dominated systems over geological timescales. This link requires the construction of a likelihood function to quantify the agreement between simulated and observed data of different types (e.g. sediment age and thickness, grain size distributions). The technique has been tested and validated with synthetic data, in which all the parameters are specified to produce a ‘perfect’ simulation, although we add noise to these synthetic data for subsequent testing of the inverse modelling approach. These tests addressed convergence and computational‐overhead issues, and highlight the robustness of the inverse scheme, which is able to assess the full range of uncertainties on the inferred environmental parameters and facies distributions.