Dissolved oxygen as an indicator of bioavailable dissolved organic carbon in groundwater

Concentrations of dissolved oxygen (DO) plotted vs. dissolved organic carbon (DOC) in groundwater samples taken from a coastal plain aquifer of South Carolina (SC) showed a statistically significant hyperbolic relationship. In contrast, DO-DOC plots of groundwater samples taken from the eastern San Joaquin Valley of California (CA) showed a random scatter. It was hypothesized that differences in the bioavailability of naturally occurring DOC might contribute to these observations. This hypothesis was examined by comparing nine different biochemical indicators of DOC bioavailability in groundwater sampled from these two systems. Concentrations of DOC, total hydrolysable neutral sugars (THNS), total hydrolysable amino acids (THAA), mole% glycine of THAA, initial bacterial cell counts, bacterial growth rates, and carbon dioxide production/consumption were greater in SC samples relative to CA samples. In contrast, the mole% glucose of THNS and the aromaticity (SUVA(254)) of DOC was greater in CA samples. Each of these indicator parameters were observed to change with depth in the SC system in a manner consistent with active biodegradation. These results are uniformly consistent with the hypothesis that the bioavailability of DOC is greater in SC relative to CA groundwater samples. This, in turn, suggests that the presence/absence of a hyperbolic DO-DOC relationship may be a qualitative indicator of relative DOC bioavailability in groundwater systems.     

Time scale of hydrothermal water-rock reactions in Yellowstone National Park based on radium isotopes and radon

We have measured ²²⁴Ra (3.4 d), ²²⁸Ra (5.7 yr), and ²²⁶Ra (1620 yr) and chloride in hot spring waters from the Norris-Mammoth Corridor, Yellowstone National Park. Two characteristic cold-water components mix with the primary hydrothermal water: one for the travertine-depositing waters related to the Mammoth Hot Springs and the other for the sinter-depositing Norris Geyser Basin springs. The Mammoth Hot Springs water is a mixture of the primary hydrothermal fluid with meteoric waters flowing through the Madison Limestone, as shown by the systematic decrease of the (²²⁸Ra/²²⁶Ra) activity ratio proceeding northward. The Norris Geyser Basin springs are mixtures of primary hydrothermal water with different amounts of cold meteoric water with no modification of the primary hydrothermal (²²⁸Ra/²²⁶Ra) activity ratio. Using a solution and recoil model for radium isotope supply to the primary hydrothermal water, a mean water-rock reaction time prior to expansion at 350°C and supply to the surface is 540 years assuming that 250 g of water are involved in the release of the radium from one gram of rock. The maximum reaction time allowed by our model is 1150 years.     

Rapid macrofaunal colonization of water-based drill cuttings on different sediments

A field experiment was conducted to investigate how water-based drill cuttings and sediment type influence colonization of soft bottom communities. Bottom frames with trays containing defaunated sediments were placed at the seabed for 6 months to study colonization of macrofauna. Two different sediments (coarse and fine) were used, and 6 or 24 mm layer of water-based drill cuttings were added on top of these sediments. Some of the sediments were controls with no additions. In the end of the experiment, the oxygen availability in sediment porewater and macrofaunal abundance were reduced in treatments with 24 mm drill cuttings compared to controls. Tube-building annelids were particularly sensitive to drill cuttings. However, these responses were only minor, and notably, the drill cuttings initiated a weaker faunal response than sediment type and site of the bottom frame. Sediments capped with water-based drill cuttings thus showed a rapid colonization of macrofaunal communities.     

Sedimentological and ichnological implications of rapid Holocene flooding of a gently sloping mud‐dominated incised valley – an example from the Red River (Gulf of Tonkin)

The Gulf of Tonkin coastline migrated at an average rate of ca 60 m year^?1 landward during Holocene sea‐level rise (20 to 8 ka). Due to a combination of rapid coastline migration and undersupply of sand, neither coastal barriers nor tidal sand bars developed at the mouth of the Red River incised valley. Only a 30 to 80 cm thick sandy interval formed at the base of full‐marine deposits. Thus, the river mouth represented a mud‐dominated open funnel‐shaped estuary during transgression. At the base of the valley fill, a thin fluvial lag deposit marks a period of lowered sea‐level when the river did not reach geomorphic equilibrium and was thus prone to erosion. The onset of base‐level rise is documented by non‐bioturbated to sparsely bioturbated mud that occasionally contains pyrite indicating short‐term seawater incursions. Siderite in overlying deposits points to low‐salinity estuarine conditions. The open funnel‐shaped river mouth favoured upstream incursion of seawater that varied inversely to the seasonal strongly fluctuating discharge: several centimetres to a few tens of centimetres thick intervals showing marine or freshwater dominance alternate, as indicated by bioturbational and physical sedimentary structures, and by the presence of Fe sulphides or siderite, respectively. Recurrent short‐term seawater incursions stressed the burrowing fauna. The degree of bioturbation increases upward corresponding to increasing marine influence. The uppermost estuarine sediments are completely bioturbated. The estuarine deposits aggraded on average rapidly, up to several metres kyr^?1. Siphonichnidal burrows produced by bivalves, however, document recurrent episodes of enhanced deposition (>0·5 m) and pronounced erosion (<1 m) that are otherwise not recorded. The slope of the incised valley affected the sedimentary facies. In steep valley segments, the marine transgressive surface (equivalent to the onset of full‐marine conditions) is accentuated by the Glossifungites ichnofacies, whereas in gently sloped valley segments the marine transgressive surface is gradational and bioturbated. Marine deposits are completely bioturbated.     

Offshore aeolian sediment transport across a human‐modified foredune

Concepts derived from previous studies of offshore winds on natural dunes are evaluated on a dune maintained for shore protection during three offshore wind events. The potential for offshore winds to form a lee‐side eddy on the backshore or transfer sediment from the dune and berm crest to the water are evaluated, as are differences in wind speed and sediment transport on the dune crest, berm crest and a pedestrian access gap. The dune is 18–20 m wide near the base and has a crest 4.5 m above backshore elevation. Two sand‐trapping fences facilitate accretion. Data were obtained from wind vanes on the crest and lee of the dune and anemometers and sand traps placed across the dune, on the beach berm crest and in the access gap. Mean wind direction above the dune crest varied from 11 to 3 deg from shore normal. No persistent recirculation eddy occurred on the 12 deg seaward slope. Wind speed on the berm crest was 85–89% of speed at the dune crest, but rates of sediment transport were 2.27 times greater during the strongest winds, indicating that a wide beach overcomes the transport limitation of a dune barrier. Limited transport on the seaward dune ramp indicates that losses to the water are mostly from the backshore, not the dune. The seaward slope gains sand from the landward slope and dune crest. Sand fences causing accretion on the dune ramp during onshore winds lower the seaward slope and reduce the likelihood of detached flows during offshore winds. Transport rates are higher in access gaps than on the dune crest despite lower wind speeds because of flatter slopes and absence of vegetation. Transport rates across dunes and through gaps can be reduced using vegetation and raised walkover structures. Copyright © 2017 John Wiley & Sons, Ltd.     

Paläoklimatische Information im Isotopengehalt14C-datierter Saharawässer: Kontinentaleffekt in D und18O

Zusammenfassung In den¹⁴C-Altern der Saharawässer spiegelt sich die wechselnde Abfolge von Feucht- und Trockenphasen während des späten Pleistozäns und Holozäns wider. Außerdem zeigt sich ein West-Ost-Gefälle in ihrem D- und¹⁸O-Gehalt, das als Kontinentaleffekt im Grundwasser gedeutet wird. Dieser Kontinentaleffekt setzt voraus, daß das nordafrikanische Klimageschehen vergangener Feuchtphasen von der Westdrift bestimmt wurde, die regenbringende atlantische Luftmassen weit ins Saharainnere getrieben hat. Ein einfaches mathematisches Modell, das den Kontinentaleffekt durch eine Rayleigh-Kondensation beschreibt, ergibt die beste Anpassung an die Meßwerte, wenn für die Sahara (ähnlich wie heute in Europa) ein West-Ost-Gefälle in den Paläo-Winterniederschlagsmengen von –30% pro 1000 km angenommen wird. Unter der Annahme ehemaliger Winterniederschläge (Sept.-März) von 600 mm (entspricht Lissabon heute) für das Gebiet an der nordafrikanischen Atlantikküste ergibt diese Modellrechnung z. B. 250 mm für die Paläo-Winterniederschläge im Gebiet des Murzuk-Beckens.

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The¹⁴C-age distribution of Saharian groundwaters shows the alternating sequence of humid and arid periods in the late Pleistocene and Holocene. The observed west-east decrease of the D- and¹⁸O-content of the Sahara waters is interpreted to be the Continental Effect in rain and groundwater. The paleoclimatic situation during ground-water formation therefore was controlled by the western drift carrying wet Atlantic air masses across the Sahara. The best fit of a simple Rayleigh condensation model of the continental effect to the experimental data is obtained with a west-east decrease of the Saharian paleo-winter precipitation of –30% per 1000 km (similar to the one in Europe today). With an annual winter precipitation rate (Sept.-March) of 600 mm (corresponding to the one of Lisboa today) for the Northafrican coastal area at the Atlantic Ocean a previous winter precipitation rate of 250 mm is obtained for the Murzuq Basin.

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Résumé Une succession de périodes humides et arides à la fin du Pléistocène et à l'Holocène se réflète dans la distribution des âges¹⁴C d'eaux souterraines du Sahara. Les teneurs en D et¹⁸O diminuent d'Ouest en Est, ce qui est interprété comme un effet continental dans l'eau souterraine. Celui-ci signifie que la climatologie des phases pluviales passées, dans l'Afrique du Nord, était déterminée par des vents d'Ouest qui apportaient des masses d'air atlantique humide à l'intérieur du Sahara. Un modèle mathématique simple décrivant l'effet continental par une condensation du type Rayleigh, reproduit avec la meilleure conformité les valeurs expérimentales, pour autant qu'on admette que les pluies hivernales au Sahara diminuaient anciennement d'Ouest en Est de 30% par 1000 km (comme à présent en Europe). En supposant qu'autrefois la quantité de pluie hivernale, de septembre à mars à la côte atlantique de l'Afrique du Nord était de 600 mm (comme aujourd'hui à Lisbonne), on obtient à l'aide de ce modèle une précipitation hivernale ancienne de 250 mm dans le bassin du Mourzouk.

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, ¹⁴C, . , ¹⁸O, , . , , , , . , Rayleigh, — , — — 30 % 1000 . , - , . . , 600 , — —, 250 .

     

Differences in vegetation characteristics with shoreline position on a tropical pocket beach

ABSTRACT

Composition and richness of coastal vegetation differs with distance from the water and sheltering by topography. Transition from pioneer beach plants to mature forests is expected to be narrow on low wave energy coasts with a tropical climate favorable to vegetation growth. The goal of this paper is to determine whether vegetation on the beach and foredune will be denser and have a greater number of species and more woody shrubs near the water as wave and wind stresses diminish because of favorable shoreline orientation within a pocket beach. Field data on beach width, beach mobility, dune height, vegetation species, vegetation height and percent vegetation cover were collected in Puerto Rico along six cross-shore transects. Beaches are more stable at transects in the lee of an eolianite barrier and a tombolo. The vegetation gradient there is compressed, with denser, taller, more diverse vegetation and more tree species close to the waterline than at more exposed sites. The lack of mobility of the beaches and dunes and lack of geomorphically significant disturbance events is in contrast to the conspicuous feedbacks between overwash, topography, and vegetation on exposed mid-latitude coasts, revealing the need for more study of low-energy beach environments.     

Liminosity distribution function for visual binary stars

The cosmic scatter of 147 of the best known visual binary stars on the Main Sequence is discussed and a new estimation of the luminosity distribution function for multiple star systems is presented. As long as the mass ratioq of a close binary is not smaller than 0.5, the distribution of close binary components is identical to the van Rhijn liminosity-function. For smaller mass ratios (q<0.5) the number of close companions decreases rapidly. It appears that less than 13% of visual binaries in our sample are simple binary systems.Communication presented at the International Conference on Astrometric Binaries, held on 13–15 June, 1984, at the Remeis-Sternwarte Bamberg, Germany, to commemorate the 200th anniversary of the birth of Friedrich Wilhelm Bessel (1784–1846).     

Demise of the northern Tethyan Urgonian carbonate platform and subsequent transition towards pelagic conditions: The sedimentary record of the Col de la Plaine Morte area, central Switzerland

The sedimentary succession of the Col de la Plaine Morte area (Helvetic Alps, central Switzerland) documents the disappearance of the northern Tethyan Urgonian platform in unprecedented detail and suggests stepwise platform demise, with each drowning phase documented by erosion and phosphogenesis. The first identified drowning phase terminated Urgonian carbonate production in a predominantly photozoan mode. Using a correlation of the whole-rock δ¹³C record with the well-dated record from SE France, its age is inferred to as Middle Early Aptian (near the boundary between the weissi and deshayesi zones). A subsequent drowning phase is dated by ammonites and by a correlation of the whole-rock δ¹³C record as Late Early Aptian (late deshayesi to early furcata zone). A third drowning phase provides an ammonite-based age of Early Late Aptian (subnodosocostatum and melchioris zones) and is part of a widely recognized phase of sediment condensation and phosphogenesis, which is dated as latest Early to Middle Late Aptian (late furcata zone to near the boundary of the melchioris and nolani zones). The fourth and final drowning phase started in the latest Aptian (jacobi zone) as is also indicated by ammonite findings at the Col de la Plaine Morte. The phases of renewed platform-carbonate production intervening between the drowning phases were all in a heterozoan mode.

During the ultimate drowning phase, phosphogenesis continued until the Early Middle Albian, whereas condensation processes lasted until the Middle Turonian. Coverage of the external margin of the drowned Urgonian platform by a drape of pelagic carbonates started only in the Late Turonian. During the Santonian, the external part of the drowned platform underwent normal faulting and saw the re-exposure of already lithified Urgonian carbonates at the seafloor.

Based on the here-inferred ages, the first drowning phase just precedes oceanic anoxic episode 1a (OAE 1a or “selli event”) in time, and the second drowning phase partly overlaps with OAE 1a. The onset of the third drowning event slightly predates two further periods of increased organic-matter accumulation in the Vocontian Basin (Noir and Fallot levels), and the onset of the fourth and final drowning phase may coincide with two further periods of increased organic-matter accumulation in the Vocontian Basin (Jacob and Kilian levels, part of OAE 1b). These correlations indicate a relationship between the so-called anoxic episodes and the stepwise demise of the Urgonian platform, even if the onset of environmental change is registered earlier on the platform than in basinal sediments.     

The return of confiscated land and property in the new Länder: The process and its geographical implications

The unification of Germany has led to claims for the restitution of more than 2.47 million pieces of property confiscated under the auspices of either the Third Reich or the East German government. The legal and administrative taks of restitution is a huge challenge for the new Germany, with far-reaching implications for the country's social and economic fabric. This paper examines the nature and scale of restitution claims and how they are being settled across the five new German states (Bundesländer) and Berlin. It reveals a picture of considerable progress overall, but with substantial regional variations.