Hydration shell structures in a LiI solution at elevated temperature and pressure: a molecular dynamics study

Molecular dynamics simulations of a 0.55 molal aqueous LiI solution have been performed at 508 K and 308 K and a density of 1.05 g/cm³. The structural changes resulting from increased temperature and pressure are discussed.     

ADAPTATION TO GLOBAL ENVIRONMENTAL CHANGE *

Atmospheric carbon dioxide is expected to double by A.D. 2050, raising global temperatures 2 to 3°C. A model for climatic deviations is presented, based upon paleoclimatic experience 5,000 to 8,000 years ago, when midlatitude temperatures were 1.5 to 2.5°C higher. The economic prognosis includes a United States barely able to meet its own agricultural needs and a substantial overall reduction of world food supplies. The revolutionary implications for contemporary sociopolitical alignments suggest an urgent need for long-range planning and more, historically oriented research.     

The record of impact cratering on the great volcanic shields of the Tharsis region of Mars

Mariner 9 images of the four great volcanic shields of the Tharsis region of Mars show many circular craters ranging in diameter from 100mm to 20 km. Previous attempts to date the volcanoes from their apparent impact crater densities yielded a range of results. The principal difficulty is sorting volcanic from impact craters for diameters $\text{?1}\text{km}$. Many of the observed craters are aligned in prominent linear and concentric patterns suggestive of volcanic origin. In this paper an attempt is made to date areas of shield surface, covered with high resolution images using only scattered small (?1 km) craters of probable impact origin. Craters of apparent volcanic origin are systematically excluded from the dating counts.The common measure of age, deduced for all surfaces studied, is a calculated “crater age” F′ defined as the number of craters equal to or larger than 1 km in diameter per 10⁶km². The conclusions reached from comparing surface ages and their geological settings are: (1) Lava flow terrain surfaces with ages, F′, from 180 to 490 are seen on the four great volcanoes. Summit surfaces of similar ages, F′ = 360 to 420, occur on the rims of calderas of Arsia Mons, Pavonis Mons, and Olympus Mons. The summit of Ascraeus Mons is possibly younger; F′ is calculated to be 180 for the single area which could be dated. (2) One considerably younger surface, F′ < 110, is seen on the floor of Arsia Mon's summit caldera. (3) Nearly crater free lava flow terrain surfaces seen on Olympus Mons are estimated to be less than half the age of a summit surface. The summit caldera floor is similarly young. (4) The pattern of surface ages on the volcanoes suggests that their eruption patterns are similar to those of Hawaiian basaltic shields. The youngest surfaces seem concentrated on the mid-to-lower flanks and within the summit calderas. (5) The presently imaged sample of shield surface, though incomplete, clearly shows a broad range of ages on three volcanoes—Olympus, Arsia, and Pavonis Mons.Estimated absolute ages of impact dated surfaces are obtained from two previously published estimates of the history of flux of impacting bodies on Mars. The estimated ranges of age for the observed crater populations are 0.5 to 1.2b.y. and 0.07 to 0.2b.y. Areas which are almost certainly younger, less than 0.5 or 0.07b.y., are also seen. The spans of surface age derived for the great shields are minimum estimates of their active lifetimes, apparently very long compared to those of terrestrial volcanoes.     

Zur Vergleichbarkeit der magmatischen Gesteine aus dem Adamello mit den Tonalitgraniten aus den Hohen Tauern

Ohne ZusammenfassungMit 15 Textabbildungen     

Deep structure and kinematics of the Northern Calcareous Alps (TRANSALP Profile)

The Northern Calcareous Alps (NCA) of southern Bavaria and northern Tyrol constitute a carbonate-dominated polyphase fold-thrust wedge; together with its Grauwacken Zone Basement, it is the northernmost part of the far-travelled Upper Austroalpine thrust complex of the Eastern Alps. The present geometry developed in several kinematic stages. Jurassic extensional faults that affected large parts of the NCA and their basement originated when the main part of the NCA was still located southeast of the Central Alpine Ötztal-Silvretta complex. These faults and related facies transitions influenced the later style of detachment of the NCA thrust sheets. Mid to Late Cretaceous detachment, thrust-sheet stacking and motion over the Central Alpine complex are registered in clastic deposits of syntectonic basins. The latest Cretaceous to Cenozoic NNE- to N-directed motion of the NCA towards Europe in front of the Central Alpine complex created another set of significant contraction structures, which at depth overprinted all previous structures. During Cretaceous to Cenozoic deformation, the NCA experienced about 80 km of shortening, i.e., about 73% along the TRANSALP Profile. The European basement and autochthonous Mesozoic cover beneath the allochthonous NCA thrust sheets and flysch complexes seem to have remained relatively undeformed.     

Chemical Mechanism Development: Laboratory Studies and Model Applications

Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.     

Fifteen days of continuous activity survey at Stromboli volcano, Italy, in late September 2000: Doppler radar, seismicity, infrared, soil humidity, and mapping of the crater region

The intention of our study was to gain new insight into the complex interplay between different types of eruption of the Stromboli volcano by combining detailed field observation with different geophysical methods. We recorded more than 600 eruptions by use of continuous Doppler radar measurements. We detected the onset of the seismic precursor and the beginning of the visible eruption by use of seismic and infrared data. Two soil samples per day were used to monitor the effect of humidity on the eruptive style. We mapped the crater region as a reference base for the long-term morphological changes of the active region and for the exact positions of our measurement systems. Two distinct types of eruption were distinguished from each other on the basis of seismic and radar data - short, wide-angle Strombolian explosions and pulsating, sharp angle fountain-like eruptions. Data and visual observations imply that weather conditions significantly effect volcanic activity. We also interpret the intensification of eruptive activity during our field study as replenishment of the reservoir with a new batch of magma in late September 2000.     

Remineralization Ratios in the Subtropical North Pacific Gyre

Based on a new mixing model of two end-members, the water column remineralization ratios of P/N/C_org - O₂ = 1/13 ± 1/135 ± 18/170 ± 9 are obtained for the Hawaii Ocean Time-series (HOT) data set at station ALOHA. The traditional Redfield ratios of P/N/C_org/–O₂ = 1/16/106/138 have standard deviations of more than 50%, when they are based on the average composition of phytoplankton. Apparently, the remineralization processes in the water column have smoothed out the observed large variability of plankton compositions. A new molar formula for the remineralized plankton may be written as ₁₃₅H₂₈₀O₁₀₅N₁₃P or C₂₅(CH₂O)₁₀₁(CH₄)₉(NH₃)₁₃(H₃PO₄). Oxidation of this formula results inC₂₅(CH₂O)₁₀₁(CH₄)₉(NH₃)₁₃(H₃PO₄) + 170O₂ 135CO₂ + 132H₂O + 13NO₃ ^- + H₂PO₄ ^- + 14H⁺.For comparison, remineralization using Redfield's formula gives:(CH₂O)₁₀₆(NH₃)₁₆(H₃PO₄) + 138O₂ 106CO₂ + 122H₂O + 16NO₃ ^-+ H₂PO₄ ^- + 17H⁺     

Product study of the reaction of OH radicals with isoprene in the atmosphere simulation chamber SAPHIR

Atmospheric oxidation of isoprene and its oxidation products methacrolein (MACR) and methyl vinyl ketone (MVK) have an important impact on the photochemical activity in the boundary layer, in particular in forested areas. The oxidation of isoprene by OH radicals was investigated in chamber experiments conducted under tropospheric conditions in the atmosphere simulation chamber SAPHIR at the Research Center Jülich. The aim was to determine the product yield of MVK and MACR in the OH-induced isoprene oxidation and the rate constant of their reaction with OH under real atmospheric conditions. The recently published updated degradation scheme for isoprene from Geiger et al. (2003) was used to determine rate constants and product yields. The fractional yields in the isoprene peroxy radical reaction with NO were found to be 0.41±0.03 for MVK and 0.27±0.03 for MACR. The rate coefficient for MACR with OH was found to be in very good agreement with the recommended value of IUPAC Atkinson (Atkinson et al., 2005). while the rate coefficient for MVK with OH was 27% lower.