Isotope Approach to Assess Hydrologic Connections During Marcellus Shale Drilling

Water and gas samples were collected from (1) nine shallow groundwater aquifers overlying Marcellus Shale in north‐central West Virginia before active shale gas drilling, (2) wells producing gas from Upper Devonian sands and Middle Devonian Marcellus Shale in southwestern Pennsylvania, (3) coal‐mine water discharges in southwestern Pennsylvania, and (4) streams in southwestern Pennsylvania and north‐central West Virginia. Our preliminary results demonstrate that the oxygen and hydrogen isotope composition of water, carbon isotope composition of dissolved inorganic carbon, and carbon and hydrogen isotope compositions of methane in Upper Devonian sands and Marcellus Shale are very different compared with shallow groundwater aquifers, coal‐mine waters, and stream waters of the region. Therefore, spatiotemporal stable isotope monitoring of the different sources of water before, during, and after hydraulic fracturing can be used to identify migrations of fluids and gas from deep formations that are coincident with shale gas drilling.     

Critical configurations of Lambert's 6‐station problem

Let A,B,C denote three mainland‐stations whose positions are unknown. Let D,E,F denote the positions of a moving ship at three different moments of time. At any of the locations D,E,F, the three azimuths to the target‐stations A,B,C are measured. The problem is to determine from these nine measurements the mutual positions of all stations A,B,C,D,E,F up to a common shift and a change of scale. The problem was formulated by J. H. Lambert in 1765. He also specified a mathematical solution. In this paper so‐called “critical configurations”; are investigated. It is shown that there are nontrivial configurations of the six stations A to F, such that solution of the problem is not unique (critical configuration of the first kind). There is a larger set of configurations, such that the linearized problem admits of an infinity of solutions (critical configurations of the second kind). In the latter case, the original nonlinear problem may be solvable, but the solution is highly unstable with respect to perturbations of the measurements. The main result obtained is as follows. If all stations A to F are located on a second degree curve, i.e., on a conic section, then the configuration is critical, at least of the second kind. The configuration continues to be critical if arbitrarily many observations and target‐points are added which are all situated on the second‐degree curve.     

Amino acid and amino sugar yields and compositions as indicators of dissolved organic matter diagenesis

Microbial decomposition experiments were used to characterize changes in the amino acid and amino sugar yields and compositions of natural marine substrates during early diagenesis in seawater. On average, 63% of added carbon and 68% of added nitrogen were removed within the first 30 days of decomposition. In all cases, amino acid utilization accounted for a substantial fraction of the removed C and N. Carbon-normalized amino acid yields decreased to less than 50% of their starting values and most of this change occurred within the first 10 days of decomposition. Increases in the concentrations of amino sugars and decreases in the GlcN:GalN ratio in particulate organic matter (POM) illustrated the significance of microbial production during the decomposition of added substrates. Changes in the mol % composition of amino acids during early diagenesis were substantial but highly variable with substrate. Previous survey data collected from the same region were used in conjunction with the experimental data to investigate the utility of several established amino acid-based indices of organic matter diagenesis. This comparison showed that a combination of these degradation indexes is most effective for describing the diagenetic state of dissolved organic matter (DOM). Carbon-normalized amino acid yields were found to be the most effective indicator for early diagenesis. Relative abundances of amino acids were effective indicators of intermediate stages of diagenesis and the mol % composition of the non-protein amino acid γ-Aba (γ-aminobutyric acid) was an effective indicator of advanced DOM diagenesis.     

Expression of the Toarcian Oceanic Anoxic Event: New insights from a Swiss transect

A sedimentological, biostratigraphical and geochemical (stable isotopes and Rock‐Eval parameters) analysis was performed on four Swiss successions, in order to examine the expression of the Toarcian Oceanic Anoxic Event along a north–south transect, from the Jura through the Alpine Tethys (Sub‐Briançonnais and Lombardian basins). The locations were selected to represent a range of palaeoceanographic positions from an epicontinental sea to a more open marine setting. The Toarcian Oceanic Anoxic Event was recognized by the presence of the characteristic negative carbon‐isotope excursion in carbonate (ca 2 to 4‰) and organic matter (ca 4 to 5‰) at the base of the falciferum ammonite Zone (NJT6 nannofossil Zone). The sedimentary expression of the Toarcian Oceanic Anoxic Event varies along the transect from laminated mudstone rich in total organic carbon (≤11 wt.%) in the Jura, to thin‐bedded marl (≤5 wt.% total organic carbon) in the Sub‐Briançonnais Basin and to hemipelagic reddish marly limestone (total organic carbon <0·05 wt.%) in equivalent levels from the Lombardian Basin. The carbon‐isotope excursion is thus independent of facies and palaeoceanographic position. The low nannofossil abundance and the peak in Calyculaceae in the Jura and the Sub‐Briançonnais Basin indicate low salinity surface waters and stratified water masses in general. Sedimentological observations (for example, obliquely‐bedded laminae and homogeneous mud layers containing rip‐up clasts) indicate the presence of dynamic conditions, suggesting that water mass stratification was episodically disrupted during the Toarcian Oceanic Anoxic Event. The proposed correlation highlights a stratigraphic gap and/or condensed interval between the Pliensbachian–Toarcian boundary and the Toarcian Oceanic Anoxic Event interval (most of the tenuicostatum ammonite Zone is missing), which is also observed in coeval European sections and points to the influence of sea‐level change and current dynamics. This transect shows that the sedimentary expression of the Toarcian Oceanic Anoxic Event is not uniform across the Alpine Tethys, supporting the importance of local conditions in determining how this event is recorded across different palaeoceanographic settings.     

Kritik und Beitrag zur Frage der Entstehung der Kreide-Feuersteine

Ohne Zusammenfassung     

Cross-shore distribution of longshore sediment transport rates on a barred non-tidal beach

This study was conducted to relate the cross-shore distribution of longshore sediment transport and grain size characteristics to cross-shore and longshore current velocities on a sandy low-energy beach in a non-tidal embayment of the Baltic Sea. Simultaneous measurements of current velocities and amount of sand caught in streamer traps were made on 31 sampling runs on 6 d in April 1999 at three fixed sites including the swash zone on the upper foreshore, the lower foreshore, and the crest of the most landward of four bars. Spilling waves broke frequently on the bar but rarely on the lower foreshore, even during onshore wind speeds up to 11.0 m s⁻¹. Waves always broke as plunging waves at the step at the base of the upper foreshore and were converted directly into swash. The greatest longshore current velocities in the swash occurred when wind speeds and water levels were greatest, but wind direction was nearly directly onshore. Longshore velocities were greater in the swash zone than at other sites except when relatively strong winds blew nearly parallel to the shoreline, causing a pronounced wind-induced current at the other two sites. Calculated longshore shear stress and rate of sediment trapped were highly correlated on the bar (r=0.90), less highly correlated in the swash zone, and least highly correlated (r=0.66) on the lower foreshore. Mean trapping rates in the swash were 14.6 times greater than on the lower foreshore and 7.2 times greater than on the bar. Greater trapping rates in the swash are attributed to the greater turbulence mobilizing sediments in the uprush and backwash. Little of the finer-grained sediment on the offshore sites was reworked under low energy conditions. The study reveals the dominance of swash transport on steep, reflective, low-energy beaches where wave energy dissipation takes place over small distances on the upper foreshore.