Alpine porphyry copper mineralization of West Romania

Alpine porphyry copper ores located in West Romania belong to the major Alpine belt developed from the Carpathians up to the Eastern Asia. They occurred along subduction zones in regions of thin continental crust characteristic of the complicated geotectonic Thetian environment during Laramian and Neogene metallogenic events. The porphyry copper ores consist of small size subvolcanic bodies with concentric alteration zones and Cu-Mo (Au) mineralization which exhibit similitudes with the Lowell and Guilbert model during Laramian times and with the diorite model during Miocene times. The magmatism related to porphyry copper mineralization is commonly Cu rich and restricted to insignificant sialic contamination. The spatial distribution of the ores is controlled by N-S Laramian tectonomagmatic alignments (Banat) and NW trending Neogene basins along extransverse faults (Metaliferi Mountains).

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Résumé Les minéralisations de cuivre porphyriques de la Roumanie occidentale appartiennent à la ceinture majeure qui s'étend depuis les Carpates jusqu' à l'Asie orientale. Leur occurrence le long des zones de subduction dans les régions à croûte continentale mince est caractéristique pour le compliqué milieu géotectonique thetien, au cours de la métallogenèse laramienne et néogène. Le cuivre porphyrique du type Cu-Mo (Au) est représenté par des corps subvolcaniques de dimensions réduites, à zonalité d'altération concentrique; la minéralisation laramienne peut être assignée au modèle de Lowell et Guilbert et la minéralisation néogène au modèle dioritique. Le magmatisme générateur est, en général, riche en cuivre et limité à une contamination sialique modique. La distribution spatiale des minéralisations est contrôlée par des alignements tectonomagmatiques laramiens orientés N-S (Banat), ainsi que par la disposition NO-SE des basins néogènes formès aux dépens des anciennes fractures transversales (Monts Metaliferi).

     

Relationship between chemical composition and magnetic susceptibility in the alkaline volcanics from the Isparta area,SW Turkey

Potassium-rich volcanic rocks in the Isparta area (SW Turkey) consist mainly of older (Pliocene) volcanic rock suites (e.g., lamprophyre, basaltic trachyandesite, trachyandesite, trachyte) and younger (Quaternary) caldera forming lava dome/flows (e.g., tephriphonolite, trachyte) and pyroclastics (ash/pumice fall deposits and ignimbritic flows). The magnetic susceptibility (K) was performed for both groups. The magnetic susceptibility value of the less evolved rocks characterized by SiO₂ < 57 wt% (e.g., basaltic trachyandesite, tephriphonolite, lamprophyric rocks) and having mostly mafic phenocrysts such as pyroxene, amphibole, and biotite-phlogopite is over 10 (10⁻³ [SI]). Fine to medium-grained and subhedral to anhedral opaque minerals are scattered especially in the matrix phase of the less evolved volcanic rocks. However, the K value of the more evolved rocks (e.g., trachyte and trachyandesites) with SiO₂ over 57 wt% vary between 0.1 and 28, but most of them below 10. SI values are negatively correlated with SiO₂, Na₂O, but positively correlated with Fe₂O₃, CaO, MnO, P₂O₅ and MgO contents, suggesting inverse variation of SI with fractionation of potassic magma. That is to say that less evolved volcanic rocks have relatively higher magnetic susceptibility values in the volcanic suite. Fine to medium-grained and subhedral to anhedral Fe-Ti oxides are scattered mainly in the matrix phase of the less evolved volcanics, presumably cause the pronounced relatively higher magnetic susceptibility.     

Geochemical evolution of groundwater in the Cambrian–Vendian aquifer system of the Baltic Basin

The shallowly buried marginal part of the Cambrian–Vendian confined aquifer system of the Baltic Basin is characterised by fresh and low δ¹⁸O composition water, whereas the deeply settled parts of the aquifer are characterized by typical Na–Ca–Cl basinal brines. Spatial variation in water geochemistry and stable isotope composition suggests mixing origin of the diluted water of three end-members—glacial melt water of the Weichselian Ice Age (115 000–10 000 BP), Na–Ca–Cl composition basin brine and modern meteoric water. The mixing has occurred in two stages. First, the intrusion and mixing of isotopically depleted glacial waters with basinal brines occurred during the Pleistocene glacial periods when the subglacial melt-water with high hydraulic gradient penetrated into the aquifer. The second stage of mixing takes place nowadays by intrusion of meteoric waters. The freshened water at the northern margin of the basin has acquired a partial equilibrium with the weakly cemented rock matrix of the aquifer.     

Submarine Groundwater Discharge Estimates Using Radium Isotopes and Related Nutrient Inputs into Tauranga Harbour (New Zealand)

Land-based pollutants such as fertilizers and wastewater can infiltrate into aquifers and discharge into surrounding coastal water bodies as submarine groundwater discharge (SGD). Oceanic islands, with a large coast length to land area ratio, may be hot spots of SGD into the global ocean. Although SGD may be a major pathway of dissolved nutrients, carbon and metals to coastal waters, studies have been limited due to the difficulties in measuring this often diffuse process. This study used radium isotopes (²²³Ra, ²²⁴Ra, ²²⁶Ra) to investigate SGD and the associated fluxes of nutrients into Tauranga Harbour, New Zealand. We calculated the apparent water mass ages of the harbour to be between ~4.1 and 7.8 days, which was similar to a previous numerical model of ~2–8 days. A ²²⁶Ra mass balance was constructed to quantify SGD fluxes at the harbour scale. A minimum SGD flux rate of 0.53 cm day^?1 was calculated by using the maximum groundwater end-member value from 22 sample sites. However, using the geometric mean from these samples as a representative end-member, a final value of 2.83 cm day^?1 or a flux of 3.09 × 10⁶ m³ day^?1 was calculated. These values were between ~1 and 2.8 times greater than all the major river and creeks discharging into the harbour during the sampling period. Due to the higher observed nutrient concentrations in groundwater, the SGD-derived dissolved inorganic nitrogen (DIN), dissolved organic nitrogen (DON) and total dissolved phosphorus (TDP) fluxes were calculated to be 1.07, 0.87 and 0.05 mmol m² day^?1, respectively. These SGD inputs were ~5 times (for nitrogen) and ~8 times (for phosphorus) greater than the input from surrounding rivers and streams. The average N:P ratio in groundwater samples was 36:1 (which was greatly in excess of the Redfield ratio of 16). The harbour water had a N:P ratio of ~17:1. A positive relationship between radium isotopes and N:P ratios in the harbour further supported the hypothesis that SGD can have major implications for primary production, including recurrent algal bloom events which occur in the harbour. We suggest SGD as a major driver of nutrient dynamics in Tauranga Harbour and potentially other similar coastal lagoon systems and estuaries on oceanic islands.     

Seismotectonic database of Turkey

Turkey is located in one of the most seismically active regions in the world. Characterizing seismic source zones in this region requires evaluation and integration of geological, geophysical, seismological and geodetical data. This first seismotectonic database for Turkey presented herein was prepared, under the framework of the National Earthquake Strategy and Action Plan—2023. The geographic information system (GIS)-based database includes maps of active faults, catalogues of instrumental and historical earthquakes, moment tensor solutions and data on crustal thickness. On the basis of these data, 18 major seismotectonic zones were delineated for Turkey and the surrounding region. The compilation and storage of the seismotectonic data sets in a digital GIS will allow analyses and systematic updates as new data accrete over time.     

The Earth-Moon system during the late heavy bombardment period - Geochemical support for impacts dominated by comets

The solid planets assembled 4.57 Gyr ago during a period of less than 100 Myr, but the bulk of the impact craters we see on the inner planets formed much later, in a narrow time interval between 3.8 and 3.9 Gyr ago, during the so-called late heavy bombardment (LHB). It is not certain what caused the LHB, and it has not been well known whether the impactors were comets or asteroids, but our present study lend support to the idea that it was comets. Due to the Earth’s higher gravity, the impactors will have hit the Earth with ∼twice the energy density that they hit the Moon, and the bombardment will have continued on Earth longer than on the Moon. All solid surface of the Earth will have been completely covered with craters by the end of the LHB.However, almost nothing of the Earth’s crust from even the end of this epoch, is preserved today. One of the very few remnants, though, is exposed as the Isua greenstone belt (IGB) and nearby areas in Western Greenland. During a field expedition to Isua, we sampled three types of metasedimentary rocks, deposited ∼3.8 billion years ago, that contain information about the sedimentary river load from larger areas of surrounding land surfaces (mica-schist and turbidites) and of the contemporaneous seawater (BIF). Our samples show evidence of the LHB impacts that took place on Earth, by an average of a seven times enrichment (150 ppt) in iridium compared to present-day ocean crust (20 ppt). The clastic sediments show slightly higher enrichment than the chemical sediments, which may be due to contamination from admixtures of mafic (proto-crustal) sources.We show that this enrichment is in agreement with the lunar cratering rate and a corresponding extraterrestrial LHB contribution to the Earth’s Hadean-Eoarchean crust, provided the bulk of the influx was cometary (i.e., of high velocity and low in CI abundance), but not if the impactors were meteorites (i.e. had velocities and abundances similar to present-day Earth-crossing asteroids). Our study is a first direct indication of the nature of the LHB impactors, and the first to find an agreement between the LHB lunar cratering rate and the Earth’s early geochemical record (and the corresponding lunar record). The LHB comets that delivered the iridium we see at Isua will at the same time have delivered the equivalent of a ∼1 km deep ocean, and we explain why one should expect a cometary ocean to become roughly the size of the Earth’s present-day ocean, not only in terms of depth but also in terms of the surface area it covers. The total impacting mass on the Earth during the LHB will have been ∼1000 tons/m².     

Landscape planning and management strategies for the Zir Valley,near Ankara,Turkey

This paper proposes a landscape planning and management method for river basins within the context of the European Landscape Convention (ELC) and European Water Framework Directive (WFD). This method has been applied to the Zir Valley in Ankara, Turkey. Landscape planning is identified by the ELC (European Treaty Series No. 176, 2000) as an important, forward-looking action to enhance, restore or create landscapes. The ELC also states that landscape management should promote sustainable development to ensure the non-degradation of landscapes and to help harmonize inevitable changes. The WFD (Directive 2000/60/EC of the European Parliament and of the Council, 2000) is a set of guidelines for managing large bodies of water. Its principle directive is to identify water bodies and the adjacent land areas that influence, and are influenced by, those water bodies. These are called River Basin Districts, and act as essential physiographic landscape units. While several regulations related to environmental planning, and used on a national as well as European basis, tend to utilize the same tools in practice, there are dissimilarities in how they are specifically applied and little effort is being made to promote a cooperative approach. In this paper, a National Approach for River Basin Management is proposed. This approach, which includes a landscape planning and management method based on landscape form and function, was developed to address the common purposes of the ELC and WFD.     

SOLAR/SOLSPEC: Scientific Objectives, Instrument Performance and Its Absolute Calibration Using a Blackbody as Primary Standard Source

SOLAR is a set of three solar instruments measuring the total and spectral absolute irradiance from 16 nm to 3080 nm for solar, atmospheric and climatology physics. It is an external payload for the COLUMBUS laboratory launched on 7 February 2008. The mission’s primary objective is the measurement of the solar irradiance with the highest possible accuracy, and its variability using the following instruments: SOL-ACES (SOLar Auto-Calibrating EUV/UV Spectrophotometers) consists of four grazing incidence planar gratings measuring from 16 nm to 220 nm; SOLSPEC (SOLar SPECtrum) consists of three double gratings spectrometers, covering the range 165 nm to 3080 nm; and SOVIM (SOlar Variability Irradiance Monitor) is combining two types of absolute radiometers and three-channel filter – radiometers. SOLSPEC and SOL-ACES have been calibrated by primary standard radiation sources of the Physikalisch-Technische Bundesanstalt (PTB). Below we describe SOLSPEC, and its performance.     

Grounding‐line dynamics during the last deglaciation of Kveithola,W Barents Sea,as revealed by seabed geomorphology and shallow seismic stratigraphy

A marine geophysical study reveals a complex deglaciation pattern in the Kveithola trough, W Barents Sea. The data set includes multibeam swath bathymetry and sub‐bottom sediment profiler (chirp) data acquired for the whole extent of a palaeo, marine‐terminating ice stream, along with high‐resolution single‐channel seismic data from chosen profiles. The multibeam data show a geomorphic landform assemblage characteristic of ice streams. The results of a combination of seismic and chirp unit stratigraphy reveal that the seabed geomorphology is governed by a deeper‐lying reflector. The reflector dominates surface expressions of several subglacial and ice‐marginal units, each connected to a separate episode of ice‐margin stillstand/advance. Analysis of the combined data set has resulted in a conceptual model of the ice‐stream retreat. The model depicts complex deglaciation of a small, confined ice‐stream system through episodic retreat. It describes the formation of several generations of grounding‐zone systems, characterized by high meltwater discharges and the deposition of fine‐grained grounding‐line fans. The inferred style of grounding‐zone deposition in Kveithola deviates from that of other accounts, and is suggested to be intermediate in the previously described continuum between morainal banks and grounding‐line wedges. The results of this paper have implications for grounding‐zone theory and should be of interest to modellers of grounding‐line dynamics and ice‐stream retreat.     

Palaeoenvironmental record of glacial lake evolution during the early Holocene at Sokli,NE Finland

The development of a glacial lake impounded along the retreating, northeastern ice margin of the Fennoscandian Ice Sheet during the last deglaciation and environmental conditions directly following the early Holocene deglaciation have been studied in NE Finland. This so‐called Sokli Ice Lake has been reconstructed previously using topographic and geomorphologic evidence. In this paper a multiproxy approach is employed to study a 3‐m‐thick sediment succession consisting of laminated silts grading into gyttja cored in Lake Loitsana, a remnant of the Sokli Ice Lake. Variations in the sediment and siliceous microfossil records indicate distinct changes in water depth and lake size in the Loitsana basin as the Sokli Ice Lake was drained through various spillways opening up along the retreating ice front. Geochemical data (XRF core‐scanning) show changes in the influence of regional catchment geochemistry (Precambrian crystalline rocks) in the glacial lake drainage area versus local catchment geochemistry (Sokli Carbonatite Massif) within the Lake Loitsana drainage area during the lake evolution. Principal component analysis on the geochemical data further suggests that grain‐size is an additional factor responsible for the variability of the sediment geochemistry record. The trophic state of the lake changed drastically as a result of morphometric eutrophication once the glacial lake developed into Lake Loitsana. The AMS radiocarbon dating on tree birch seeds found in the glaciolacustrine sediment indicates that Lake Loitsana was deglaciated sometime prior to 10 700 cal. a BP showing that tree Betula was present on the deglaciated land surrounding the glacial lake. Although glacial lakes covered large areas of northern Finland during the last deglaciation, only few glaciolacustrine sediment successions have been studied in any detail. Our study shows the potential of these sediments for multiproxy analysis and contributes to the reconstruction of environmental conditions in NE Finland directly following deglaciation in the early Holocene.