Bias correction method of high-resolution satellite-based precipitation product for Peninsular Malaysia

Theoretical and Applied Climatology - Satellite-based precipitation (SBP) is emerging as a reliable source for high-resolution rainfall estimates over the globe. However, uncertainty in SBP is...     

Aqueous heavy metals removal by adsorption on β-diketone-functionalized styrene–divinylbenzene copolymeric resin

An investigation was undertaken regarding the adsorption of different heavy metal ions from aqueous solutions using ??-diketone-functionalized styrene divinylbenzene resin under different experimental conditions such as initial concentration of metal ions, contact time, pH, and chelating capacity. The functionalization of resin was carried out by the condensation reaction of sodium salt of ??-diketones (pentane-1,3-dione) and chloromethylated styrene?Cdivinylbenzene resin in dichloromethane. Functionalized resin beads were characterized by Fourier transform infrared spectroscopy. The batch method was employed using different metal ions solution from 5 to 15?mg/L at different contact times. The adsorption kinetics was tested for the pseudo-first order, pseudo-second order reaction at different experimental conditions. The rate constant of adsorption kinetic models were also calculated and good correlation coefficient (R ²?>?0.9941) was obtained for pseudo-second order kinetic model. The maximum adsorption value obtain for lead (0.725728?mg/g), chromium (0.9199?mg/g), nickel (0.4974?mg/g), cobalt (0.6196?mg/g) and cadmium (0.6519?mg/g) at equilibrium condition, which shows that ??-diketone-functionalized styrene divinylbenzene resin is an effective adsorbent for toxic metal ions.     

Use of electrical resistivity tomography in delineating zones of groundwater potential in arid regions: a case study from Diriyah region of Saudi Arabia

A detailed geophysical investigation in the form of electrical resistivity tomography (ERT) was carried out using the SYSCAL Pro Unit at two locations with a dipole?Cdipole configuration in one of the private farms in Diriyah area of Riyadh, Saudi Arabia with the purpose of delineating the approximate depth of the water-bearing formations. The survey helped in delineating a superficial moist zone at the first site which was mainly due to the seepage from surface water pipes used for irrigating the date palms. At the second site, a potential water-bearing zone was detected starting from a depth of 23 to 46?m. However, an already existing bore well in close vicinity of the site of the second survey showed a water table depth of 85?m, indicating the presence of a layered aquifer. Finally, it was concluded that a shallow bore well drilled up to a depth of 50?C60?meters would be able to tap the water resources of shallow water-bearing horizon discovered at the second site during the survey; however, the yield of the bore well might not be sustainable over a longer period of time. The survey at the first site did not show any promising groundwater potential up to the investigated depth which was around 70?m. The study confirms the usage of ERT surveys for exploring sources of freshwater supplies in arid regions.     

Spatial Metrics to Analyse the Impact of Regional Factors on Pattern of Urbanisation in Gurgaon,India

In recent years, there has been lot of emphasis on the study of urban land use/ land cover changes to discover the growth pattern due to rapid urbanisation. This study presents spatial metrics and gradient analysis approach for quantifying and capturing changes in urban landscape using LISS III imagery of 1999, 2001 and 2004 of Gurgaon, India. A combination of spatial metrics i.e. percentage of landscape, mean patch size, number of patches, landscape shape index and largest patch index, available in Fragstats ver. 3.3, have been used to quantify the patterns of urban growth in different directions in terms of size, shape and complexity of development. The local built-up areas were quantified by the “moving window” technique. A gradient analysis has been carried out through sampling from a reference point to 8 km in 16 directions with a window size of 500 mts. Results of this study demonstrate the potential of spatial metrics and gradient modelling to quantify the impact of regional factors on the growth pattern of Gurgaon city.     

Analysis of buried pipelines subjected to reverse fault motion

Presently available simplified analytical methods and semi-empirical methods for the analysis of buried pipelines subjected to fault motion are suitable only for the strike-slip and the normal-slip type fault motions, and cannot be used for the reverse fault crossing case. A simple finite element model, which uses beam elements for the pipeline and discrete nonlinear springs for the soil, has been proposed to analyse buried pipeline subjected to reverse fault motion. The material nonlinearities associated with pipe-material and soil, and geometric nonlinearity associated with large deformations were incorporated in the analysis. Complex reverse fault motion was simulated using suitable constraints between pipe-nodes and ground ends of the soil spring. Results of the parametric study suggest that the pipeline's capacity to accommodate reverse fault offset can be increased significantly by choosing a near-parallel orientation in plan with respect to the fault line. Further improvement in the response of the pipeline is possible by adopting loose backfill, smooth and hard surface coating, and shallow burial depth in the fault crossing region. For normal or near normal orientations, pipeline is expected to fail due to beam buckling at very small fault offsets.     

Enriched finite element procedures for analyzing decoupled bolts installed in rock mass

Numerical procedures are developed to analyze interaction between fully grouted bolts and rock mass using ‘enriched finite element method (EFEM)’. A solid element intersected by a rock bolt along any arbitrary direction is termed as ‘enriched’ element. The nodes of an enriched element have additional degrees of freedom for determining displacements, stresses developed in the bolt rod. The stiffness of the enriched element is formulated based on properties of rock mass, bolt rod and grout, orientation of the bolt and borehole diameter. Decoupling at grout–bolt interface and elasto‐plastic behavior of rock mass have also been incorporated into the EFEM procedures. The results of this method are compared with analytical pull‐out test results presented by Li and Stillborg (Int. J. Rock Mech. Min. Sci. 1999; 36 :1013–1029). In addition, a numerical example of a bolted tunnel is provided to demonstrate the efficacy of the proposed method for practical applications. Copyright © 2010 John Wiley & Sons, Ltd.     

Snow cover depletion under changed climate with the help of remote sensing and temperature data

Snow cover depletion curve (SDC) is one of the important variables in snow hydrological applications, and these curves are very much required for snowmelt runoff modeling in a snowfed catchment. Remote sensing is an important source of snow cover area which is used for preparation of SDC. Snow cover maps produced by Moderate Resolution Imaging Spectroradiometer (MODIS) satellites are one of the best source of satellite-based snow cover area at a regular interval. Therefore, in this study, snow cover maps have been prepared for the years 2000?C2005 using MODIS data. The study area chosen viz. Beas basin up to Pandoh dam falls in western Himalayan region. For snowmelt runoff modeling, catchment is divided into number of elevation zones and SDC is required for each zone. When sufficient satellite data are not available due to cloud cover or due to some other reasons, then SDC can to be generated using temperature data. Under changed climate conditions also, modified SDC is required. Therefore, to have SDC under such situations, a relationship between snow cover area and cumulative mean temperature has been developed for each zone of the catchment. This procedure of having snow cover maps has two main purposes. First, it could potentially be used to generate snow cover maps when cloud-free satellite data are not available. Second, it can be used to generate snow-covered area in a new climate to see the impact of climate change on snowmelt runoff studies.     

Neoproterozoic contaminated MORB of Wadi Ghadir ophiolite,NE Africa: Geochemical and Nd and Sr isotopic constraints

The ophiolitic metabasalts (pillowed and sheeted dikes) of Wadi Ghadir area, Eastern Desert, Egypt, were analyzed for their major, trace and rare earth elements, Nd and Sr isotopes and the chemistry of their plagioclase, amphibole and chlorite was also reported. Geochemically these rocks range from tholeiitic basalt to basaltic andesite. The generally low MgO, Cr and Ni and high Zr contents are consistent with derivation of these rocks from an evolved magma. The high TiO₂ contents (mostly between 1.76% and 2.23%) classify Wadi Ghadir ophiolitic metabasalts as MORB ophiolite. The chondrite-normalized REE patterns of most samples display small LREE-enrichment with (La/Yb)_n ranging from 1.44 to 2.56. The MORB-normalized spider diagram shows variable LILE abundances, which are either similar to or enriched relative to MORB, and most samples display small Nb depletion. The abundances of some LILE (Ba, Rb and K) as well as Na and Si were modified by post-magmatic seafloor hydrothermal alteration. Enrichment of the least mobile LILE (Th & U) indicates that Wadi Ghadir ophiolitic metabasalts are akin to C (contaminated)-MORB. These geochemical characteristics are similar to BABB modified by contamination.Wadi Ghadir metabasalts have low initial Sr ratios (0.7010–0.7034) which are similar to those of MORB, while their ε_Nd(t) values (+7.7–+4.5) are either more or less positive than the value of depleted mantle (DM). The more positive ε_Nd(t) values indicate DM source for these basalts, while the less positive ε_Nd(t) values reflect the involvement of slightly older component in Wadi Ghadir ophiolite. We suggest that the parent magma of metabasalts was contaminated by slightly older material, most probably oceanic-arc crustal rocks, which caused enrichment in LREE, and by analogy LILE, but did not significantly affect Nd isotopic systematics or modify Sr isotopes.Such contaminated MORB character also revealed by other ophiolitic metavolcanics in the Central Eastern Desert, contrasting the N-MORB character of the Gerf ophiolite in the South Eastern Desert. Moreover, the present work suggests the increase of the degree of contamination of the ophiolitic metabasalts from south to north in the Central Eastern Desert.     

Floral biodiversity and geology of the Talcher Basin,Orissa, India during the Permian–Triassic interval

The review paper provides an updated account of the previous and recently published records concerning the palaeobiology and the geology of the Talcher Basin of Orissa State, India. We conclude that fossil floral species in this basin originated in the earliest Permian Talchir Formation and evolved and diversified through the Karharbari Fm., Barakar Fm., Barren Measures Fm. and the uppermost Kamthi Fm. (Late Permian–Triassic). The megaflora and the palynology of the different formations of the basin are also discussed briefly. The geological setting of the basin along with the status of different formations (especially the Kamthi Formation) has been redefined. The post‐Barakar Fm. rocks, earlier retained in the Raniganj/Kamthi, Panchet and Mahadeva formations in this basin, have been critically assessed and redefined as the Lower and Upper Kamthi formations of Late Permian and Triassic ages, respectively. Accordingly, the geological map of the basin has been modified. Permian deposits (particularly the Barakar and the lower Kamthi formations) not only have the best preserved flora but also possess the highest diversity, whereas the upper Kamthi Triassic sediments have a meagre number of taxa. The plant diversity of the basin has been discussed in detail to interpret the development of the flora, evolutionary trends and palaeoenvironments of the basin. The patchy Gangamopteris vegetation of the Talchir glacial phase has ultimately evolved and diversified through time (Karharbari Fm. to Lower Kamthi Fm.) and gave rise to the thick dense swampy forests consisting of large Glossopteris trees and other shade‐loving under‐storied pteridophytes. Several groups of plants including spores and pollen have disappeared in a ladder pattern during the Permian–Triassic interval (Lower Kamthi–Upper Kamthi Fm.) and, similarly, in steps, many new fore‐runners appeared in the Upper Kamthi Formation. Records of marine acritarchs and ichnofossils in this basin at various Permian–Triassic levels demonstrate that there were marine influences. These features suggest a paralic (coastal marine to deltaic) mode of origin of the coal beds and associated sediments in the basin. The present study also advocates the continued survival of plants, rather than a mass extinction near the vicinity of the Permian–Triassic (P–T) boundary in this basin. Copyright © 2012 John Wiley & Sons, Ltd.     

Acoustic Mode Frequencies of the Sun During the Minimum Phase Between Solar Cycles 23 and 24

We investigate the spatial and temporal variations of the high-degree mode frequencies calculated over localized regions of the Sun during the extended minimum phase between solar cycles 23 and 24. The frequency shifts measured relative to the spatial average over the solar disk indicate that the correlation between the frequency shift and magnetic field strength during the low-activity phase is weak. The disk-averaged frequency shifts computed relative to a minimal activity period also reveal a moderate correlation with different activity indices, with a maximum linear correlation of about 72?%. From the investigation of the frequency shifts at different latitudinal bands, we do not find a consensus period for the onset of solar cycle 24. The frequency shifts corresponding to most of the latitudes in the northern hemisphere and 30° south of the equator indicate the minimum epoch to be February 2008, which is earlier than inferred from solar activity indices.