Loss of 40Ar(rad) from leucite-bearing basanite at low temperature: implications on K/Ar dating.

The Bakony-Balaton Highland Volcanic Field (BBHVF) is located in the central part of Transdanubia, Pannonian Basin, with over 50 alkali basaltic volcanoes. The basanite plug of Hegyestu erupted in the first phase of volcanic activity. K/Ar and Ar/Ar ages were published for the BBHVF. K/Ar and Ar/Ar ages of the leucite-bearing basanite of Hegyestás were conflicting. This is caused by the special Ar retention feature of leucite in this basanite. K/Ar ages measured in the usual way were 25–45% younger, but after HCl treatment of the rock, or after reducing the baking temperature of the argon extraction line from 250°C to 150°C, they became similar to the Ar/Ar ages. All Ar/Ar determinations were performed after HF treatment. HCl treatment dissolved olivine, nepheline, leucite, magnetite and from 1-1 sample analcime or calcite. K dissolution studies from different locations of Hegyestü have shown that K content is mostly ≈2%, but it may decrease to ≈0.3%. HCl treatment dissolved 28.0–63.5% of the K content. The calculated K concentration for the dissolved part of samples with ~2%K was 4.02-6.42%: showing that leucite is responsible for the low temperature loss of ⁴⁰Ar(rad). Ar may release at low temperature from very finegrained mineral, or when the Ar release mechanism changes. A ⁴⁰Ar(rad) degassing spectrum has been recorded in the 55–295°C range of baking temperature and the data were plotted in the Arrhenius diagram. The diagram shows that a change of the structure in the 145–295°C range caused the loss of ⁴⁰Ar(rad). On fractions of HCl treated rock 7.56±0.17 Ma isochron K/Ar age has been determined. This is regarded as minimum age of eruption and it is similar to the Ar/Ar isochron age (7.78±0.07 Ma).     

Cenozoic Intraplate Alkaline Volcanism of Western Bohemia

Three independent volcanic suites have been recognised in W Bohemia: (i) the old unimodal alkaline ol. nephelinite-tephrite (29-19 Ma) in the Ohe Rift, (ii) two contemporaneous weakly (trachybasalt/trachyandesite-trachyte/rhyolite; 13-11 Ma) and strongly (ol. nephelinite-tephrite/basanite; 12-8 Ma) alkaline series in the flank of the Cheb-Domalice Graben formed by the Teplá Highland and (iii) the young unimodal ol. melilitite/ol. nephelinite alkaline suite (2.0-0.12 Ma) at the intersection of the above mentioned structures in the Cheb Basin. The magmas of all the suites are mantle-derived and, in the case of the Cheb-Domalice Graben series, associated with the AFC process. Two main fault systems: (i) ENE-WSW and (ii) NNW-SSE are developed in W Bohemia, corresponding to the directions of the two prominent taphrogenic structures. The southwesterly continuation of the Ohe Rift across the Mariánské Lázn Fault is marked by volcanics only.