Source Based Characterization and Pollution Profile of a Baker's Yeast Industry

Baker's yeast industry has significant effects on environment due to significant water consumption and high strength wastewater production. Effluents from baker's yeast industry are characterized by high concentrations of biological oxygen demand (BOD₅), chemical oxygen demand (COD), total Kjeldahl nitrogen (TKN), total dissolved solids (TDS), sulfate, and dark brown color. The aim of this study is to provide a detailed quantitative and qualitative identification and characterization of the wastewater sources from different processes of a baker's yeast industry. It is identified that the most polluted wastewater components of the facility are coming from rotary drum filter and evaporation process. However, the highest pollution loads is identified as tank and equipment cleaning effluent due to very high flow rate from this source. The efforts should be on the way to minimize the water usage for the tank and equipment cleaning process, and to recycle less polluted waste streams back to the process.     

Late Cenozoic stress states around the Bolu Basin along the North Anatolian Fault, NW Turkey

This study defines the Late Cenozoic stress regimes acting around the Bolu Basin along the North Anatolian Fault in northwestern Turkey. The inferred regional stress regime, obtained from the inversion of measured fault-slip vectors as well as focal mechanism solutions, is significant and induces the right-lateral displacement of the North Anatolian Fault. The field observations have also revealed extensional structures in and around the Bolu Basin. These extensional structures can be interpreted as either a local effect of the regional transtensional stress regime or as the result of the interaction of the fault geometries of the dextral Duzce Fault and the southern escarpment of the North Anatolian Fault, bordering the Bolu Basin in the north and in the south, respectively.The inversion of slip vectors measured on fault planes indicates that a strike-slip stress regime with consistent NW- and NE-trending σ_Hmax(σ₁) and σ_Hmin(σ₃) axes is dominant. Stress ratio (R) values provided by inversion of slip vectors measured on both major and minor faults and field observations show significant variations of principal stress magnitudes within the strike-slip stress regime resulting in older transpression to younger transtension. These two stress states, producing dextral displacement along NAF, are coaxial with a consistent NE-trending σ₃ axis. The earthquake focal mechanism inversions confirm that the transtensional stress regime has continued into recent times, having identical horizontal stress axis directions, characterized by NW and NE-trending σ₁ and σ₃ axes, respectively. A locally consistent NE-trending extensional, normal faulting regime is also seen in the Bolu Basin. The stress-tensor change within the strike-slip stress regime can be explained by variations in horizontal stress magnitudes that probably occurred in Quaternary times as a result of the westward extrusion of the Anatolian block.     

A New Natural Secondary Reference Material for Garnet U-Pb Dating by TIMS and LA-ICP-MS

Gem quality andradite-rich garnet (IUC-1), obtained from the Miocene trachyte dome near Ankara city (Turkey), has been identified as a potential natural secondary reference material for U-Pb dating. In this study, U-Pb dating was performed in five different laboratories using isotope dilution TIMS and laser ablation ICP-MS to determine the homogeneity of euhedral garnet crystals. The U-Pb ID-TIMS data for IUC-1 yielded ²⁰⁷Pb/²³⁵U and ²⁰⁶Pb/²³⁸U ages of 20.9 ± 0.4 and 20.6 ± 0.8 Ma respectively, and these values are consistent with U-Pb LA-ICP-MS analyses, in which different garnet crystals yielded ages of 20.8 ± 0.1, 20.7 ± 0.1, 20.7 ± 0.2 and 20.2 ± 0.1 Ma. An andradite (IUC-2) from the Serçeören wollastonite skarn (Turkey) can be used as a secondary reference material provided detailed imaging of the crystals is undertaken. ID-TIMS data yielded ²⁰⁷Pb/²³⁵U and ²⁰⁶Pb/²³⁸U ages of 20.4 ± 0.4 and 20.9 ± 1.0 Ma respectively, and yielded U-Pb ages on different grains of 20.5 ± 0.1, 20.7 ± 1.0, 20.8 ± 1.7 and 20.9 ± 1.6 Ma. The assigned weighted mean age of IUC-1 (20.4 ± 0.5 Ma, 2s) is proposed as a 2023 reference value. IUC-1 garnet is expected to contribute significantly to rapidly developing garnet geochronology in the near future.     

Identification and origin of bitumen in Neolithic artefacts from Demirköy Höyük (8100 BC): Comparison with oil seeps and crude oils from southeastern Turkey

Two ring-like artefacts from the aceramic Neolithic site of Demirköy Höyük in southeastern Turkey were analysed using geochemical techniques in order to determine whether they were prepared using a bitumen amalgam or not. The artefacts, dated 8100 BC, are early evidence of the innovative use of a petroleum-based material to prepare pieces of ornaments (beads, rings, etc.) for the elite of a Neolithic settlement. In order to trace the source of the presumed bitumen, two oil seeps, Boğazköy and Yeşilli, were sampled. To complete the genetic references, geochemical data on crude oils from the main oil fields from the area were compiled.Basic geochemical data show that bitumen is present in the artefacts. Sterane and terpane patterns, as well as carbon isotopic data on C₁₅₊ saturated and C₁₅₊ aromatic hydrocarbons, allowed us to conclude that the Demirköy Höyük bitumen and the Boğazköy oil seep were generated from a Silurian source rock. The detailed geochemical characteristics show, however, that the Demirköy Höyük bitumen does not correlate perfectly with the Boğazköy oil. This discrepancy suggests several explanations: the real bitumen source may be elsewhere in the vicinity and has not been discovered or was at the Boğazköy oil seep location but with slightly different properties in Neolithic times, or has disappeared. Another possibility is that the slight molecular differences are due to weathering effects, which affected the pristine bitumen within the archaeological sample.     

Hydrology,hydrogeology and hydrochemistry of wetlands: a case study in Izmir Bird Paradise,Turkey

Izmir Bird Paradise is one of the most valuable wetlands in Turkey, but this area is now being threatened by the drying out of marshes and water pollution. This wetland consists of two ecosystems: fresh- and saltwater. The recharge of marshes is from rainfall, the Gediz River and groundwater from Can Suyu Pond. The water type of the river is Ca-Mg-Na-HCO₃-SO₄, whereas the groundwater is a Na-Cl water type. The reasons for the drying are long-term drought (evapotranspiration at 894 mm is >> rainfall at 546 mm), and excessive pumping of groundwater and seawater intrusion into Menemen Plain. Therefore, an additional freshwater resource is necessary. This water can be supplied from the limestone levels of Neogene sedimentary rocks in and around Izmir Bird Paradise that have a Ca-HCO₃ water type. Water pollution levels were also analysed. In the freshwater ecosystem Cd, Cr, Fe, Mn, Ni, Pb, Sb and Zn values, in the open channel in Izmir Bird Paradise Sb, Fe, Ni and Cd values, and in the river Fe, Pb and Sb values exceed the TSE 266 and EPA 2000 standards probably due to agricultural and industrial sources.     

A field application for lime stabilization

This study presents the improvements achieved as a result of the lime stabilization application conducted by the joint effort of the Turkish Association of Lime Industrialists and the General Directorate of Rural Services on the 200 m long section of the Ankara Province Yukar? Yurtçu Village road where green and brown clays are dominant. The study also numerically demonstrates the impacts of these improvements on the road section based on the results of various laboratory and field tests. The lime stabilization in field conditions was performed with 5% lime for both clays and was applied as a 30 cm thick single layer. In the soaked California bearing-ratio (CBR) tests conducted in the laboratory, increases that reach up from 16 and 21 times compared to initial soaked CBR values were observed in green and brown clays, respectively, at the end of 28 days. The high increases observed in soaked CBR values would reduce the upper layer thickness of the roads. The similar improvements are also achieved in unconfined compression and plate loading tests. The comparisons performed with the plate loading tests clearly demonstrated the behavior of the surface to lime and its cure impact.     

Analysis of Ezinepazarı–Sungurlu Fault Zone (Turkey) using Landsat TM data and its kinematic implications

The study area is located between Çorum and Amasya along the Ezinepazar?–Sungurlu Fault Zone (ESFZ) which is regarded as the splay of the North Anatolian Fault Zone (NAFZ). By this study, the 1/25,000 scaled geological map of the study area was prepared, and its stratigraphic and tectonic characteristics were unraveled as a result of palaeontological and petrographical analyses of the samples collected from different rock units. Particularly, geologic ages of the Late Jurassic–Early Cretaceous Ferhatkaya and Carcurum and Middle Eocene Çekerek formations were provided from palaeontological determinations. Using Landsat TM and Shuttle Radar Topography Mission 3 (SRTM 3) data of the region, the borders between the rock units and the tectonic characteristics in the study area were clarified by spectral and spatial enhancement methods. Kinematic characteristics of ESFZ obtained from the young sedimentary rocks along both sides of the fault zone were also inferred in this study. Understanding the kinematic and geometrical characteristics of the faults is important in terms of the seismotectonics of the region. In the statistical study conducted on the basis of the directions of the lineaments indicates the highest concentrations in general between N 50° - 60° E and N 60° - 70° E. Band 7 of the study area was enlightened in SE direction taking into consideration the relation of the geologic structures in the region with NAFZ and ESFZ and their general strike directions. Along with the formation of NAFZ, the region has undergone a counterclockwise rotation of approximately 20°–30°, which has developed between the “splay” faults in the south block of that fault. These faults are strike-slip faults formed under the compressional regime roughly in a NW–SE direction. It is noted that this tectonic regime has developed under compression in NW–SE direction, which was dominant in similar kinematic analysis studies conducted on NAFZ.     

Geochemistry of mafic dykes from the Southeast Anatolian ophiolites,Turkey: Implications for an intra-oceanic arc–basin system

The Late Cretaceous–Tertiary accretionary prism in Eastern Turkey includes several ophiolitic megablocks and/or tectonic slivers (Mehmetalan, Mollatopuz and Alabayir) within a mélange complex, mainly comprising harzburgite, dunite and cumulate-textured gabbro. The diabases, which are the main focus of this study, cut across the ophiolites as parallel and variably thick dyke-swarms. Geochemistry of the diabases reveals three distinct groups, including a) supra-subduction zone (SSZ) type, which is characterized by marked Nb-anomaly and normal mid-ocean ridge basalt (N-MORB) like HFSE distribution, b) enriched MORB (E-MORB) type, showing some degree of enrichment relative to N-MORB, c) oceanic-island basalt (OIB) type with characteristic hump-backed trace element patterns, coupled with fractionated REE distribution. Among these groups, SSZ- and E-MORB-type signatures are acquired from the Mehmetalan and Mollatopuz suites, whereas OIB-type characteristics are found in the Alabayir suite. The melting models indicate involvement of both depleted and enriched sources for the genesis of the studied dykes. The close spatial relationship, similar ages (based on Ar–Ar dating) and the presence of variable subduction component displayed by Mehmetalan and Mollatopuz suites may indicate melt generation in an intra-oceanic SSZ within the southern branch of Neotethys. In spite of the solely OIB-like character of the Alabayir suite, the similar age obtained from these dykes may suggest their formation in a similar SSZ setting. Alternatively, the Alabayir suite may have represented an oceanic island or seamount formed in an intra-plate setting with or without plume influence. We suggest that decompression melting triggered by slab roll-back mechanism during the closure of the southern branch of the Neotethys during the Late Cretaceous may have been the main process that led to generation of magmas of both depleted and enriched characteristics.     

Stochastic modeling applications for the prediction of COD removal efficiency of UASB reactors treating diluted real cotton textile wastewater

A three-layer Artificial Neural Network (ANN) model (9:12:1) for the prediction of Chemical Oxygen Demand Removal Efficiency (CODRE) of Upflow Anaerobic Sludge Blanket (UASB) reactors treating real cotton textile wastewater diluted with domestic wastewater was presented. To validate the proposed method, an experimental study was carried out in three lab-scale UASB reactors to investigate the treatment efficiency on total COD reduction. The reactors were operated for 80 days at mesophilic conditions (36–37.5°C) in a temperature-controlled water bath with two hydraulic retention times (HRT) of 4.5 and 9.0 days and with organic loading rates (OLR) between 0.072 and 0.602 kg COD/m³/day. Five different dilution ratios of 15, 30, 40, 45 and 60% with domestic wastewater were employed to represent seasonal fluctuations, respectively. The study was undertaken in a pH range of 6.20–8.06 and an alkalinity range of 1,350–1,855 mg/l CaCO₃. The concentrations of volatile fatty acids (VFA) and total suspended solids (TSS) were observed between 420 and 720 mg/l CH₃COOH and 68–338 mg/l, respectively. In the study, a wide range of influent COD concentrations (COD_i) between 651 and 4,044 mg/l in feeding was carried out. CODRE of UASB reactors being output parameter of the conducted anaerobic treatment was estimated by nine input parameters such as HRT, pH, COD_i concentration, operating temperature, alkalinity, VFA concentration, dilution ratio (DR), OLR, and TSS concentration. After backpropagation (BP) training combined with principal component analysis (PCA), the ANN model predicted CODRE values based on experimental data and all the predictions were proven to be satisfactory with a correlation coefficient of about 0.8245. In the ANN study, the Levenberg-Marquardt Algorithm (LMA) was found as the best of 11 BP algorithms. In addition to determination of the optimal ANN structure, a linear-nonlinear study was also employed to investigate the effects of input variables on CODRE values in this study. Both ANN outputs and linear-nonlinear study results were compared and advantages and further developments were evaluated.