相山铀矿田成矿机理研究

本文重点研究了相山铀矿田的成矿时代及成矿环境 ,并剖析了典型矿床在垂向上物质成份的变化规律。研究结果表明 :相山矿田主要经历了两期铀矿化作用 ,第一期为铀 赤铁矿化阶段 ,成矿年龄为 1 1 5± 0 6Ma ;第二期为铀 萤石 水云母化阶段 ,成矿年龄为 99± 6Ma。两期成矿作用分别形成于不同的地质环境 ,第一期成矿作用主要与大规模火山塌陷及次火山岩侵位有关 ,第二期成矿作用则主要与因太平洋板块的松弛作用而形成的区域性伸展、裂解及中基性脉岩的活动有关。相山矿田的热液蚀变类型不仅在平面上存在东碱、西酸的演化趋势 ,而且在垂向上还存在上酸、下碱的演化规律。通过对相山矿田成矿机理的深入探讨 ,认为相山矿田是成矿元素多阶段富集、成矿热液多期叠加以及多种地质因素共同作用的产物。     

内蒙古阿钦楚鲁二长花岗岩锆石SHRIMP U-Pb年龄及地球化学特征

阿钦楚鲁二长花岗岩体位于西伯利亚板块东南缘查干敖包奥尤特朝不楞早古生代构造-岩浆岩带中段, 主要岩石类型为中细粒二长花岗岩和中粗粒二长花岗岩。SHRIMP锆石U-Pb同位素定年结果表明, 阿钦楚鲁二长花岗岩的成岩年龄为(296.3±3.8) Ma, 为华力西晚期。岩石地球化学分析结果表明:阿钦楚鲁二长花岗岩富硅, w(SiO₂)为73.48%~74.22%, 过铝质, w(Al₂O₃)为13.63%~14.01%, A/CNK值为1.04~1.10, 碱质含量较高, w(K₂O)+w(Na₂O)为8.08%~8.54%, 里特曼指数(σ)为2.13~2.46, 相对富钾, K₂O/Na₂O值为1.31~1.54, 属高钾钙碱性系列。该岩石富集大离子亲石元素Rb、Sr、Ba和轻稀土元素(LREE), 相对亏损Ta、Nb、Ti等高场强元素, 稀土元素总量为(112.05~130.16)×10^-6, 中等Eu负异常(δEu=0.52~0.65), 稀土元素配分曲线呈现出略微右倾型, 轻稀土较陡, 重稀土较缓, 具有向A型花岗岩过渡的后碰撞高钾花岗岩特征;岩石具有较低的⁸⁷Sr/⁸⁶Sr初始值(0.703 849~0.704 236)和正的ε_Nd(t)值(4.2~4.3), 反映其物质来源可能主要为幔源岩浆底侵作用形成的新生大陆地壳。基于上述分析研究和构造环境判别, 结合区域对比, 推测阿钦楚鲁二长花岗岩为在岩石圈由挤压增厚向伸展体制转换的动力学背景下, 由于俯冲板片的断离, 造成软流圈上涌和岩石圈地幔的部分熔融, 而部分幔源岩浆底侵到地壳的下部或者呈基性侵入体的形式侵入地壳, 引起上部地壳的熔融而形成后碰撞高钾钙碱性花岗岩。     

山西宁武煤田大同组植物群特征

山西宁武煤田大同组植物化石笔者鉴定计２１属４１种，以真蕨类，银杏类为主，有节类，柏柏类次之，苏铁类稀少。该植物群可归于北方普遍发育的Ｃｏｎｉｏｐｔｅｒｉｓ－Ｐｈｏｅｎｉｃｏｐｓｉｓ植物群，并可与大同煤田的大同组、北京西山门头沟群、鄂尔多斯盆地延安组及表海大煤沟组所含植物各对比，时代属中侏罗世。     

Major element geochemistry of purple soils/rocks in the red Sichuan Basin, China: implications of their diagenesis and pedogenesis

Major element compositions and chemical weathering features of the purple soils and their corresponding rocks in the Red Sichuan Basin, China were studied in this paper to infer the diagenetic features of the purple rocks and the pedogenetic features of the purple soils. The results showed that all of the rock and soil samples, except those from Yibin, have strongly similar major element compositions and the distribution patterns of their major element compositions are similar to those of the upper continental crust. Chemical index of alteration, chemical index of weathering and Na₂O/K₂O indicate that the purple soils and rocks have similar chemical weathering intensities, whereas the Al₂O₃–CaO* + Na₂O–K₂O (A–CN–K) relationship, suggests that chemical weathering was strong during diagenesis of the purple rocks, but weak during pedogenesis of the purple soils. Variations in major element compositions of the purplish rock samples, except that from Yibin, do not primarily reflect differences in compositions of the sediment source, sediment recycling and potassium metasomatism, and therefore the effects of chemical weathering on the major element compositions were mainly dependent on climate condition and the residence time of material exposed to chemical weathering. Chemical weathering of the purple rocks reached only moderate degrees under the general influence of warm and humid climate during Jurassic and Cretaceous. Warmer and more humid climate conditions partly resulted in stronger chemical weathering of rocks in the southern region of the basin than in the central and western region, whereas shorter residence time of material in upslope position partly resulted in weaker chemical weathering of rocks in the eastern region than in the central and western region. The same climate and stable tectonic setting led to comparable chemical weathering intensities of rocks in the Ziliujing and Jiaguan Formations. Gradually colder and dryer climate from Early Jurassic to Middle Jurassic then to Late Jurassic and shorter residence time in tectonically active setting of Middle Jurassic and late Late Jurassic resulted in the following order of chemical weathering intensity of the purple Jurassic rocks: Ziliujing Formation ? Shaximiao Formation ≈ Suining Formation > Penglaizhen Formation.     

基于硫酸盐还原菌作用的油菜秆固定床处理模拟含Cr（Ⅵ）废水

探讨了固定床除Cr工艺以油菜秆为微生物生长的缓释碳源,含SRB的混合微生物和油菜秆对Cr（Ⅵ）的还原和固定的共同作用。动态实验分2阶段开展：初始2周的驯化阶段和梯度增加Cr（Ⅵ）浓度的除Cr实验阶段。除Cr实验中,间歇对固定床出水pH、氧化还原电位、SO42-及硫化物浓度、DOC、Cr（Ⅵ）浓度进行测试,实验结束后对固定床中固体产物进行SEM、EDS和XPS等分析。结果表明,油菜秆固定床处理模拟含Cr（Ⅵ）废水效果明显。当进水Cr（Ⅵ）浓度ρ[Cr（Ⅵ）]〈19.52 mg/L时,出水Cr（Ⅵ）和Cr（Ⅲ）浓度均低于排放标准（0.05 mg/L）;Cr（Ⅵ）被还原为Cr（Ⅲ）,Cr（Ⅲ）以氢氧化物的形式沉淀附着于油菜秆和其它固体物质之上。分析认为,油菜秆在固定床处理模拟含Cr（Ⅵ）废水中所起的作用主要包括3方面（作为微生物生长的缓释碳源;吸附Cr（Ⅵ）,降低其对微生物的毒性;作为Cr（Ⅲ）矿化产物的沉淀附着界面）;Cr（Ⅵ）主要通过SRB的直接作用及H2S的作用被还原为Cr（Ⅲ）;以油菜秆为碳源的固定床处理Cr（Ⅵ）的浓度上限介于15.05～19.52mg/L之间。     

海水养殖珍珠表层微形貌的结构研究--以广西防城养殖珍珠为例

海水养殖珍珠的表层微形貌呈现以文石晶体及壳角蛋白膜为结构单元组成的按一定方式排列的层状或阶梯状的结构或形态。单元结构的生长方式符合“隔室效应”原理。表层结构中文石的结晶度、结构有序度及壳角蛋白膜厚度是珍珠光泽强度与明亮度的决定因素 ,并影响珍珠的透明度、伴色及体色。     

辐照绿柱石的色心与赋色机制

在不同辐照剂量的带电粒子作用下，四川无色绿柱石因赋色而呈现浅蓝色，蓝绿色，黄绿色，浅黄色及橙黄色，紫外可见吸收光谱（UV－VIS）和阴极发光光谱（CLS）研究表明，辐照绿柱石中存在两组与赋色密切相关的色心组合，其一为相对稳定的[Fe^3 ]OH和[Fe^3 4]心，其二则为不稳定的[H^0]i心和F^ 心，二者对可见光的能量分别具有不同程度的选择性吸收和发射，由此产生特征的吸收与发射光谱。低温退火处理（210℃），有助于消除辐照绿柱石中不稳定的色心，使相对稳定的[Fe^3 ]OH心黉度再度聚集，并形成新的缺陷（二次缺陷），进而提高稳定色心的主波长和饱和度。研究证实，二次缺陷形成的初始温度，可近似代表辐照绿柱石的最佳热固色温度点，经辐照与热固色作用而形成的黄色，橙黄色绿柱石的颜色相对稳定，并不因长期日照或低温受热（＜280℃）而褪色。     

利用扫描电镜、压汞法、氮气吸附法评价近海黏土孔隙特征

近海地区黏土的微观结构单元--黏土畴中含有大量的粒内孔隙,其孔径小至纳米级,这部分孔隙对黏土的物理指标、水稳性、膨胀性、收缩性等具有重要影响,一般方法很难准确地描述其孔隙特征。试验利用扫描电镜、压汞法、氮气吸附法对湛江黏土的微观孔隙特征及其孔隙发育的控制因素分析,建立微观结构与物理指标、力学行为的相互关系与灵敏性分析。结果表明,湛江黏土具有不良物理性质和良好力学特性指标的异常组合,是一种高灵敏性的强胶结结构性黏性土,其机制主要是：湛江黏土的微观结构为带有胶质联结特性的、定向性无序的开放式絮凝结构,孔隙结构为具有较高的强度和空间稳定性的边－面－角联结的空间网架系统。由于特殊的孔隙网架结构以及“墨水瓶”型孔隙的存在,导致退汞过程出现滞留现象及产生吸附回线。研究表明,联合扫描电镜、压汞法、氮气吸附法能够准确、完整地对近海地区黏土孔隙体系特征进行定性与定量的评价。     

Bearing Capacity of Two-Layered Artificial Ground with Firm Crust and Weak Subgrade Under Circular Pressure

Classical bearing capacity expressions can not afford variant engineering requests, since they were deducted under hypotheses of strip footing on homogeneous soil. An often met case was taken into account that circular footing on two-layered ground, which has firm crust and weak subgrade. Weighted method and layered method were used in capacity deduction, respectively. The former counts layered soils as single layer of weighted structure and material parameters. But it is restricted to conditions with close strength to each layer. The latter is preferred in engineering calculation, which regards the whole bearing capacity as subgrade’s capacity under the influence of the upper layer. Thus the issue is transformed to K. Terzaghi model plus stress reduction and dispersion effects. At last, the expressions gained from both methods and finite element analysis (FEA) were used in an example calculation, respectively. It approves layered calculating method and suggests the corresponding security coefficient based on elastoplastic FEA results.