A new approach to the librational solution in the Ideal Resonance Problem

The librational motion of the Ideal Resonance Problem (Garfinkel, 1966, Jupp, 1969) is treated through an initialnon-canonical transformation which, however, leaves the equations of motion in a quasi-canonical form, with Hamiltonian expressed in standard trigonometric functions amenable to traditional averaging techniques. The perturbed solutions, similarly expressed intrigonometric near-identity transformations, and their frequencies can be found to arbitrary order, with the elliptic integrals expected of the system introduced only in a final explicit quadrature for a Kepler-type equation in the angular variable. The specific transformations and resulting equations of motion are introduced, and explicit solutions for the original variables are found to second order, with mean motion accurate to fifth. Limitation of the present solution to the librational region, the extension of that solution to higher order, and observations on the form of the associated Hamiltonian are also discussed.     

The role of cavities and mantles in the ultraviolet extinction peak of graphite spheres with particular reference to a possibly discovered C60 structure

A computer routine using rigorous Güttler theory was developed to consider effects of concentric cavities and organic mantles within and around graphite spheres, with a view to assessing the stability of the extinction peak near 4.60 m^–1. The newly discovered stable carbon molecule of 60 atoms gives an absorption band at 4.60 m^–1 which closely agrees with the observed; moreover, it leads to the observed extinction rise in the far UV and can possibly explain the fine structure around the 5.5–7 m^–1 dip, while its own structure deals successfully with the main objections to previous carbon-graphite models. The role of the electric vector component perpendicular to the basal plane of the crystal in achieving the fit is stressed.     

Silica phase transformations in the petroliferous sequences

The joint evolution of organic matter and silica in petroliferous sequences is considered in the terms of the laws of transformation of dispersion systems. The dispersion systems are transformed under conditions of low-temperature solid-phase processes accompanied by the silica phase transition and dehydration that favors the evolution of organic matter.     

DEFORMATION OF SEISMIC WAVELETS BY THIN LAYERS AND LAYERED BOUNDARIES*

Using plane wave theory and assuming a given input wavelet the shape of the reflected (or transmitted) wavelet from a layered boundary is derived. Several types of boundaries are considered, among them the weathered layer and a wedge shaped intermediate layer. Different angles of incidence and all internal multiples are taken into account. The examples shown in the figures can be used for a direct comparison between theoretical and observed shapes of reflected (or transmitted) wavelets from special boundaries.     

Irish on the move

Trends in emigration from Ireland over time are reviewed. "During the eighteenth and nineteenth centuries overseas migration to the United States and seasonal harvest migration to Britain were the main types of movement, but over the past 100 years the Irish have developed a special affinity for settling in British towns. Although the outflow was halted for a time during the 1970s, when return migration took over, the 1980s have seen a renewal of the exodus. This time, however, the character of the flow has changed from predominantly low-skill construction and factory workers to embrace better-educated emigrants, including many graduates. This shift reflects Ireland's changing position in the international market for labour."     

Powder- and single crystal Mössbauer spectroscopy on synthetic fayalite

Mössbauer measurements on synthetic iron orthosilicate Fe₂SiO₄ (fayalite) were carried out in the antiferromagnetic spin state below T _N 65 K. The Mössbauer parameters isomer shift , inner magnetic field H(0), angle between H(0) and the z-component of the electric field gradient (efg), quadrupole splitting QS and asymmetry parameter were determined as a function of temperature. These parameters could be attributed to the two crystallographic sites M1 and M2.The smaller isomer shift on M1 with respect to M2 displays the more covalent character of the Fe-O bond on M1, which is supported by previous neutron diffraction experiments. H(0) shows a Brillouin-type behaviour with different fields on the two crystallographic sites (stronger on M1) and a small discontinuity at T = 23 K which corresponds with previous magnetic measurements. The quadrupole splitting is equal on both sites within error bars, in agreement with previous theoretical results and in contradiction to previous Mössbauer refinements published elsewhere.