Magnesium-iron compositional variance in hornblende pyroxene granulites

Hornblende-orthopyroxene-calcic pyroxene-plagioclase (andesine-labradorite) — magnetite-ilmenite±quartz assemblages are evidently the most common granulite facies representatives of basic rocks throughout the world, and they must represent a variance of more than one. Ramberg (1948) invoked an additional degree of freedom arising out of unequal fractionation of Mg and Fe in the ferromagnesian silicates in such rocks. This is examined in detail on the basis of chemical data on twentytwo hornblende-orthopyroxenecalcic pyroxene triads, half of them from the type charnockite area near Madras.Theoretical consideration of a magnesium-iron distribution model shows that in quartz-bearing hornblende pyroxene granulites, the Mg/Mg+Fe ratios of hornblende, orthopyroxene and calcic pyroxene are uniquely determined by temperature at constant pressure. But these assemblages contain quartz rarely and Mg-Fe distribution among the three can be best described by three exchange equilibria where, at constant temperature, there is a fixed relation between the Mg/Mg+Fe ratios of the minerals. Among these, the exchange equilibria between hornblende-orthopyroxene and hornblende-calcic pyroxene appear to be interdependent; however, they are known to be significantly modified by varying tetrahedral aluminium contents of hornblendes. Comparison of molecular Mg/(Mg+Fe) ratios of hornblendes and parent rocks strongly points to an absence of Mg-Fe compositional variance in the total system, a petrologically important corollary being that the hornblendes in these rocks are highly unlikely to be secondary after pyroxenes. The general variance of the assemblages is also discussed.     

Allochthonous and autochthonous organic matter in surface waters in Karelia

A relationship between indirect chemical indices of organic matter content of surface waters and light absorption in the visible and ultraviolet ranges is discussed. The allochthonous and autochthonous types of organic matter are found to essentially differ in the rate of light absorption. Techniques are proposed for the calculation of the concentrations of allochthonous and autochthonous organic matter by the integral rate of light consumption in the visible region and the bichromate oxidability of water, as well as by three indirect indices: chemical oxygen demand, permanganate oxidability, and water color index. The mean concentrations of allochthonous and autochthonous organic matter in large lakes (Ladoga, Onega, and Baikal) and in rivers and smaller water bodies in Karelia (>300 water objects) are analyzed. Allochthonous organic matter was found to predominate in most surface waters of Karelia (>80%), while allochthonous organic matter predominates only in lakes with a small specific catchment area (supposedly, <5) and in highly eutrophic lakes.     

Biofacies analysis of Upper Cretaceous deposits in the Ust-Yenisei region: Implications of palynomorphs

The results of palynomorph biofacies analysis in the Upper Cretaceous deposits of the Ust-Yenisei region are presented. The established facies confinement and indicative features of separate palynomorph groups are used, along with identified dinocyst morphotypes and taxa, in paleogeographic reconstructions. Seven palynomorph associations characterizing continental, coastal-marine, shallow-and deep-water facies are distinguished based on quantitative proportions between morphological groupings and individual taxa. As boundaries between distinguishable biostratigraphic and facies subdivisions do not coincide, dinocysts were likely insignificantly dependent in distribution on facies in the West Siberian epicontinental basin at least. On the other hand, distribution trends of particular dinocyst morphotypes and other microphytofossils are correlative with transgressive-regressive cycles and can be used for reconstruction of paleoenvironments.     

Hydrodynamic processes in young binaries as a source of cyclic variations in circumstellar extinction

Hydrodynamic models of a young binary accreting matter from the remnants of a protostellar cloud have been calculated by the SPH method. Periodic variations in column density in projection onto the primary component are shown to take place at low inclinations of the binary plane to the line of sight. These can result in periodic extinction variations accompanied by brightness variations in the primary. Generally, there can be three periodic components. The first component has a period equal to the orbital one and is attributable to the streams of matter penetrating into the inner regions of the binary. The second component has a period that is a factor of 5–8 longer than the orbital one and is related to the density waves generated in a circumbinary (CB) disk. Finally, the third, longest period is attributable to the precession of the inner CB disk regions. The relationship between the amplitudes of these cycles depends on the model parameters as well as on the inclination and orientation of the binary in space. We show that at a dust-togas ratio of 1: 100 and amass extinction coefficient of 250 cm² g^?1, the amplitude of the V-band brightness variations in the primary component can reach 1 ^m at a mass accretion rate onto the binary components of 10.8^?8 M _⊙ yr^?1 and a 10° inclination of the binary plane to the line of sight. We discuss possible applications of the model to young, pre-main-sequence stars.     

Stable isotope composition of subfossil Cerastoderma glaucum shells from the Szczecin Bay brackish deposits and its palaeogeographical implications (South Baltic Coast,Poland)

The environmental conditions of the Szczecin Bay, which existed prior to Szczecin Lagoon, have been reconstructed on the basis of the stable carbon and oxygen isotope (¹⁸O and ¹³C) analysis and radiocarbon dates obtained for subfossil shells of Cerastoderma (Cardium) glaucum. The shells in the collected core were well preserved in their life positions, representing a geochemical record of past temperature variation over the middle Holocene. Three major periods with different thermal conditions have been distinguished in the interval ~ 6000–4300 cal yr BP, when the important Littorina regional transgression took place. During the first period, 6000–5250 cal yr BP, water temperature decreased by 1.4°C, and then remained constant over the second period (5250–4750 cal yr BP). In contrast, during the third period (4750–4300 cal yr BP) both δ-values were highly variable and the mean summer temperature (March–November) increased by about 3.5°C. During first two periods, δ¹⁸O and δ¹³C were significantly correlated, indicating stability of the environmental conditions.     

Buried paleo-channels on the New Jersey continental margin: channel porosity structures from electromagnetic surveying

We report on a marine electromagnetic (EM) survey across two portions of the New Jersey continental margin that have been previously shown to contain buried paleo-channels. The EM method used provides bulk porosity estimates to depths of around 20 m below the seafloor and is thus able to place porosity constraints on the nature of the channel infill and the contrast in physical properties across the channel boundaries. Our data show that a key condition for the channels to have an electrical signature is that they incise an underlying regional unconformity, R, thought to represent a subaerially eroded surface, exposed during the late Wisconsinan glaciation. Channels that cut R are seen through increases in apparent porosity. Another seismically imaged channel sequence, which lies within the outer-shelf sediment wedge sequence above R, does not have an electrical signature, indicating that the sediments above and below the channel boundaries have similar physical properties.     

Qualitätsanforderungen an Oberflächengewässer: Zielvorgaben,Qualitätsziele und chemische Gewässergüteklassifizierung

Quality Requirements for Fresh Waters: Water Quality Targets, Water Quality Objectives, and Chemical Water Quality Classification In the Federal Republic of Germany, water quality requirements for the protection of inland surface waters against hazardous substances are formulated on the basis of a quality targets derivation concept developed jointly by the Federal Government and the Federal States. The quality requirements were termed “water quality targets” in order to make it clear that the values derived are orientational values rather than legally binding limit values. The international comparison of quality requirements for surface waters shows that, on the whole, the national quality targets ensure a high level of protection. According to present scientific knowledge, impairments of uses, such as supply of drinking water, or risks to aquatic communities need not to be expected if the quality targets are complied with. A comparison of water quality data with the water quality targets makes it possible, on the one hand, to identify those substances whose inputs must be further reduced; on the other hand, it also shows that, for a number of substances, there is no need at present for concern over their adversely water quality. A further differentiation of the aquatic hazard potential of pollutants allows a water quality classification system to be developed on the basis of the quality targets derivation concept. The basic elements of this water quality classification system are presented, and its application is explained by way of examples.     

Nonstationary pearl pulsations as a signature of magnetospheric disturbances

We analyse long-lasting (several hours) Pc1 pearl pulsations with decreasing, increasing or constant central frequencies. We show that nonstationary pearl events (those with either decreasing or increasing central frequency) are observed simultaneously with increasing auroral magnetic activity at the nightside magnetosphere while the stationary events (constant central frequency) correspond to quiet magnetic conditions. Events with decreasing central frequency are observed mostly in the late morning and daytime whereas events with increasing central frequency appear either early in the morning or in the afternoon. We explain the diurnal distribution of the nonstationary pearl pulsations in terms of proton drifts depending on magnetic activity, and evaluate the magnetospheric electric field based on the variation of the central frequency of pearl pulsations.     

Groundwater-level prediction using multiple linear regression and artificial neural network techniques: a comparative assessment

The potential of multiple linear regression (MLR) and artificial neural network (ANN) techniques in predicting transient water levels over a groundwater basin were compared. MLR and ANN modeling was carried out at 17 sites in Japan, considering all significant inputs: rainfall, ambient temperature, river stage, 11 seasonal dummy variables, and influential lags of rainfall, ambient temperature, river stage and groundwater level. Seventeen site-specific ANN models were developed, using multi-layer feed-forward neural networks trained with Levenberg-Marquardt backpropagation algorithms. The performance of the models was evaluated using statistical and graphical indicators. Comparison of the goodness-of-fit statistics of the MLR models with those of the ANN models indicated that there is better agreement between the ANN-predicted groundwater levels and the observed groundwater levels at all the sites, compared to the MLR. This finding was supported by the graphical indicators and the residual analysis. Thus, it is concluded that the ANN technique is superior to the MLR technique in predicting spatio-temporal distribution of groundwater levels in a basin. However, considering the practical advantages of the MLR technique, it is recommended as an alternative and cost-effective groundwater modeling tool.