A model for the constant-head pumping test conducted in vertically fractured media

An analytical model for the constant-head pumping test is developed for a partially penetrating well that has a finite thickness skin, and intersects a single vertical fracture. In the model, the fracture is fully confined and flow occurs only in the fracture. The model is developed using Laplace transform and finite Fourier transform methods. The model is to be used for analysing well test data from vertically fractured media and for verifying numerical models. Dimensionless curves are used to study the effects of a finite thickness skin and a partially penetrating wellbore. In the presence of a finite thickness skin, or a partially penetrating wellbore, a typical flow response for the constant-head pumping test has three distinct periods of flow corresponding to small-, intermediate- and large-time. Small- and large-time approximations are presented for the model. For tests where the wellbore is fully penetrating, or the partial penetration ratio is known, these approximations can be used to analyse field data.     

Drumlin formation in Southern Anglesey and Arvon,Northwest Wales

This is a study of Late Devensian drumlins formed in southern Anglesey and Arvon, northwest Wales. This area was affected by ice sheet coalescence when the Welsh ice sheet met with the lrish Sea ice sheet, and drumlins were formed once the two had coalesced. It is suggested that the drumlins were the result of net subglacial soft-bed erosion, and that they represent more resistant cores within the subglacial deforming layer. The drumlins have either gravel or till cores, and where the core was deformable, large-scale compressive glaciotectonic structures were seen (e.g. Dinas Dinlle) with local subglacial compression of –59%. Where the cores were more resistant (e.g. Lleiniog) these were not deformed but remained as more competent masses within the deforming layer. It is suggested that the less competent material flowed around the cores, some remaining as a thin carapace, but most of the material being removed down glacier, leaving the drumlins as erosional remnants. In northwest Wales there is a multi-till sequence that traditionally has been interpreted as having been deposited as the result of separate ice-sheet advances and retreats. However, in this study, it is suggested that the different tills were deposited as the result of ice-sheet coalescence, and that sites such as Dinas Dinlle do not show evidence of a major readvance in the retreat of the Devensian ice, but are indicative of continuously changing conditions within the subglacial deforming bed.     

Silica phase transformations in the petroliferous sequences

The joint evolution of organic matter and silica in petroliferous sequences is considered in the terms of the laws of transformation of dispersion systems. The dispersion systems are transformed under conditions of low-temperature solid-phase processes accompanied by the silica phase transition and dehydration that favors the evolution of organic matter.     

Diffusion-deposition patterns in Martian streaks

The spreading angle of a number of light and dark Martian streaks is determined from selected Mariner 9 images. The resulting frequency distributions of spreading half-angles have maxima at ～5° for light, and ～7° for dark streaks; however the dark streaks have a secondary maximum spreading angle at ～14°. The smaller values, which include most streaks, are interpreted as crater-wake spreading phenomena. The larger value, found in only a few dark streaks or “tails,” may result from atmospheric diffusion and subsequent deposition of material from isolated sources such as vents or blowouts. An atmospheric diffusion-deposition analysis is presented, assuming this streak origin, from which it is possible to deduce the eddy diffusivity, K, in Mars' boudary layer. Calculated K values are found to agree with various theoretical estimates. They lie in the range 10⁷ and 10⁹ cm² sec^?1 and exhibit the proper scale dependence. Thus it appears that, in addition to streak-derived wind direction patterns and speed information, it is possible in a few cases to derive information on Mars' boundary-layer turbulence from streak-spreading measurements.     

Late Cretaceous rift-related upwelling and melting of the Trindade starting mantle plume head beneath western Brazil

High mantle potential temperatures and local extension, associated with the Late-Cretaceous impact of the Trindade mantle plume, produced substantial widespread and voluminous magmatism around the northern half of the Paraná sedimentary basin. Our previous studies have shown that, above the central and eastern portions of the postulated impact zone where lithosphere extension is minimal, heat conducted by the plume caused large-scale melting of the more fusible parts of the subcontinental lithospheric mantle beneath the margin of the São Francisco craton and the surrounding Brasilía mobile belt. Here we combine geochemical data and field evidence from the Poxoreu Igneous Province, western Brazil to show how more intense lithospheric extension above the western margin of the postulated impact zone permitted greater upwelling and melting of the Trindade plume than further east. Laser ⁴⁰Ar/³⁹Ar age determinations indicate that rift-related basaltic magmas of the Poxoreu Igneous Province were emplaced at ? 84 Ma. Our detailed geochemical study of the mafic magmas shows that the parental melts underwent polybaric crystal fractionation within the crust prior to final emplacement. Furthermore, some magmas (quartz-normative) appear to have assimilated upper crust whereas others (nepheline- and hypersthene-normative) appear to have been unaffected by open-system crustal magma chamber processes. Incompatible trace element ratios (e.g. chondrite-normalised La/Nb?=?1) and isotopic ratios (⁸⁷Sr/⁸⁶Sr?=?0.704 and ¹⁴³Nd/¹⁴⁴Nd?=?0.51274) of the Hy-normative basalts resemble those of oceanic islands (OIB). We therefore propose that these “OIB-like” magmas were predominantly derived from convecting-mantle-source melts (i.e. Trindade mantle plume). Inverse modelling of rare-earth element (REE) abundances suggests that the initial melts were predominantly generated within the depth range of ?80–100 km, in mantle with a potential temperature of ?1500 °C.     

A Model of Magmatic Crystallization

A computer model simulating fractional crystallization at oneatmosphere pressure incorporates nine broadly-defined minerals—magnetite,olivine, hypersthene, augite, quartz, plagioclase, orthoclase,leucite, and nepheline. The crystallization temperature of eachmineral is considered to be a smooth function of the compositionof the magmatic liquid. These mineral temperature equationsare obtained by multiple linear regression analysis of informationfrom published silicate systems and rock melting experiments.The nine equations are solved for any primary liquid, withinthe broad range of common magma types, to select the crystallizingmineral or minerals. Partition ratios from published experimentsand analyses of lavas and phenocrysts permit calculation ofthe composition of the crystallizing mineral assemblage. Subtractionof a small amount of that composition from the primary liquidyields a new liquid, which may be recycled to yield a sequenceof liquids during fractional crystallization. The crystallizationmodel handles assemblages of co-precipitating minerals, andcan trace progressive saturation in new minerals, substitutionof a new mineral for an old mineral, and cessation of crystallizationof a mineral. The sequences of minerals and liquids derivedfrom a broad set of primary liquids are geologically realistic,so the model is useful in predicting phenocrysts in volcanicrocks and events during crystallization of shallow intrusions.     

A new semi-quantitative Surface-Enhanced Raman Spectroscopy (SERS) method for detection of maleimide (2,5-pyrroledione) with potential application to astrobiology

Nitrogen-containing heterocyclic compounds are fundamental biochemical components of all life on Earth and, presumably, life elsewhere in our solar system. Dete...