A preliminary investigation into the use of ochre as a remedial amendment in arsenic-contaminated soils

Ochre is an unwanted waste product that accumulates in wetlands and streams draining abandoned coal and metal mines. A potential commercial use for ochre is to remediate As contaminated soil. Arsenic contaminated soil (605 mg kg⁻¹) was mixed with different ochres (A, B and C) in a mass ratio of 1:1 and shaken in 20 mL of deionised water. After 72 h As concentration in solution was ca. 500 μg kg⁻¹ in the control and 1–2.5 μg kg⁻¹ in the ochre treated experiments. In a second experiment soil:ochre mixtures of 0.05–1:1 were shaken in 20 mL of deionised water for 24 h. For Ochres A and C, as solution concentration was reduced to ca. 1 μg kg⁻¹ by 0.2–1:1 ochre:soil mixtures. For Ochre B, as concentration only reached ca. 1 μg kg⁻¹ in the 1:1 ochre:soil mix. Sorption of As was best modelled by a Freundlich isotherm using As sorption per mass of goethite in the ochre (log K = 1.64, n = 0.79, R² = 0.76, p 0.001). Efficiency of ochre in removing As from solution increased with increasing total Fe, goethite, citrate dithionite extractable Fe and surface area.     

Age and source material of the Kingash ultramafic-mafic massif,East Sayan

The REE distribution patterns and Nd whole-rock and mineral isotope ratios of the Kingash ultramafic-mafic massif enabled us to propose a multistage history for its evolution at 1410 and 875 Ma. These stages reflect the magmatic evolution of the Siberian paleocontinent margin during the Late Precambrian. The age of metamorphism of the massif during collision and accretion in the Early Paleozoic (∼500 Ma) was obtained based on a Sm-Nd mineral isochron from rheomorphic veined albitite. The Nd and Sr isotopic compositions of rocks from the Kingash massif suggest mantle sources for picritic and basic magmas, which are thought to have originated by mixing of different proportions of depleted (PREMA or DM) and enriched (EM) melts. The initial isotope ratios of the parental melts transformed during interaction with Sr-rich material from the host metasedimentary complexes.     

Estimating water balance components of tropical wetland lakes in the Pantanal dry season,Brazil

Abstract

Water balance studies with stable water isotopes have rarely been conducted in remote and tropical wetland areas. As such, little is known regarding the water balance and groundwater–surface water interaction in the Pantanal, one of the largest and most pristine wetlands in the world. We applied MINA TrêS, a water balance model utilizing stable water isotopes (δ¹⁸O, δ²H) and chloride (Cl^-) to assess the dry-season hydrological processes controlling groundwater–surface water interactions and the water balance of six floodplain lakes in the northern Pantanal, Brazil. Qualitatively, all lakes exhibited similarity in hydrological controls. Quantitatively, they differed significantly due to morphological differences in controlling groundwater inflow and lake volume. Our approach is readily transferable to other remote and tropical wetland systems with minimal data input requirements, which is useful in regions with sparse hydrometric monitoring.

Editor Z.W. Kundzewicz     

Uranium and lead gain of detrital zircon studied by isotopic analyses and fission-track mapping

Besides Pb and U loss and mixing of crystals of different age, U gain is considered a possible cause of discordant U-Pb ages of zircons. However, whether U gain without new zircon growth occurs in nature had not been proven, so far. In order to test this possibility, two detrital zircon populations were studied for which the absence of later zircon overgrowth after deposition could be demonstrated. The samples were separated from a metaquartzite near a large pegmatite body and from metaquartzite inclusions found in the pegmatite (Martell Valley, Italian Alps). The distribution of neutron-induced fission tracks reveals distinct accumulation of U in the rims of more than 90% of the zircon grains of the inclusions (total U in the crystals: 540–850 ppm), whereas in the country rock only some of the grains show similar but weaker patterns (total U: 155–320 ppm). From the isotopic data and from additional U-Pb and Rb-Sr analyses of minerals and whole-rock samples of the pegmatite, the marginal accumulation and the higher concentration of U in the zircon grains of the inclusions are interpreted as the result of episodic U gain during the intrusion of the pegmatite and/or during a later metamorphism. From the concentration levels of common Pb, an addition of Pb - and possibly other elements - to the zircon grains is inferred.     

Oil-spill disasters and the rural hazardscape of Eastern Nigeria

The objective of the paper is to investigate the links between the patterns of incidents, the amount of hazardous materials locally present and capability of local emergency preparedness in rural local government councils. Four states Abia, Akwa Ibom, Bayelsa and Rivers State were used to examine the nature and pattern of oil-spill disasters in rural Nigeria. It is argued that oil-spill hazards are more than isolated engineering malfunctions. They can be alternatively understood as reflections of the social, economic and political contexts in which they occur. Discriminant analysis is used to examine the relationship between 71 country risk-related and preparedness variables and incident frequency. The findings illustrate the usefulness of contextual analysis in examining the restructuring of rural life and the capacity of fiscally and socially stressed rural communities to respond to environmental change.     

Paleosols and prehistoric populations in the high plains

Excavations in 1980–1981 at sites (32MZ319 and 32MZ380) along Cinnamon Creek Ridge in the Little Missouri River Badlands of McKenzie County, North Dakota, unexpectedly revealed at each locality the presence of one or more deeply buried paleosols with associated cultural materials. At both sites, 32MZ319 and 32MZ380, multiple paleosols are present, each of which is terminated by an episode of aeolian deposition. Fifteen radiocarbon dates on these paleosols establish an incipient chronology for paleosol development in the study area and permit correlation with other High Plains archaeological complexes. Geological and archaeological data for the two multiple paleosol sites are summarized.     

Investigating Bermuda's pollution history through stable isotope analyses of modern and museum-held gorgonian corals

For centuries, Bermuda has been challenged with wastewater management for the protection of human and environmental health. By quantifying the δ¹⁵N of the common sea fan Gorgonia ventalina sampled from 30 sites throughout Bermuda we show that sewage-derived nitrogen is detectable on nearshore coral reefs and declines across the lagoon to the outer rim. We also sampled gorgonians from two museum collections representing a 50y time-series (1958–2008). These samples revealed an increase in δ¹⁵N of > 4.0‰ until the mid-1970s, after which δ¹⁵N values slowly declined by ~ 2.0‰. A δ¹⁵N chronology from a gorgonian skeleton exhibited a similar decline over the last 30–40 years of approximately 0.6‰. We conclude that policies have been effective in reducing sewage impacts to Bermudian reefs. However, significant sources of sewage pollution persist and are likely have a strong impact on harbor and nearshore coral communities and human health.     

A very large scale GIS-based groundwater flow model for the Nubian sandstone aquifer in Eastern Sahara (Egypt,northern Sudan and eastern Libya)

A three-dimensional GIS-based groundwater flow model for the Nubian Sandstone Aquifer in the eastern Sahara was developed and calibrated under steady-state and transient conditions. The model was used to simulate the response of the aquifer to climatic changes that occurred during the last 25,000 years. The simulation results indicated that the groundwater in this aquifer was formed by infiltration during the wet periods 20,000 and 5,000 years b.p. The recharge of groundwater due to regional groundwater flow from more humid areas in the south was excluded. It also indicates that the Nubian Aquifer System is a fossil aquifer, which had been in an unsteady state condition for the last 3,000 years.

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Resumen Fue desarrollado un modelo de flujo de agua subterránea en tres dimensiones, basado en un SIG, para el Acuífero Arenisca Nubian en el Sahara Oriental, el cual fue calibrado para condiciones de estado estacionario y transitorio. El modelo se usó para simular la respuesta del acuífero a los cambios climáticos que ocurrieron durante los últimos 25000 años. Los resultados de esta simulación indicaron que el agua subterránea en este acuífero, se formó por infiltración, durante los períodos húmedos que hubo hace 20000 y 5000 años, antes del presente. Fue excluida la recarga del acuífero debida a un flujo regional de agua subterránea proveniente de áreas con un clima más húmedo en el sur. El modelo también muestra, que el Sistema Acuífero Nubian es un acuífero fósil, el cual ha permanecido en una condición de estado no estacionario, durante los últimos tres mil años.

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Résumé Pour laquifère gréseux Nubien de Sahara -Est on a mis au points un modèle tridimensionnel, basé sur GIS. Le modèle a été calibré tant pour lécoulement stationnaire que pour lécoulement transitoire. On a simulé après la réponse de laquifère aux changements climatiques des derniers 25000 ans. Les résultats des simulations indiquent que la nappe a été rechargée par des infiltrations pendant une période humide qui sétend 5000 et 20000 ans, dès temps actuel. On na pas pris en compte la recharge de laquifère par la zone plus humide située dans sa partie sud. Le modèle indique aussi que leau de laquifère Nubien est une eau fossile qui a eu un écoulement transitoire pendant les derniers 3000 ans.