Distribution of Indus born mica along Gulf of Kachchh coast: Implications in understanding current dynamics

Indus is one of the major sources of sediments to the Gulf of Kachchh. Yet only its <63 micron fraction is studied in detail with regards to the offshore current dynamics. Hence here we present our study on characteristic signature of the Indus sediment load (i.e. mica minerals) in >63 micron size fraction along the coast of Gulf of Kachchh. The spatial distribution of mica minerals along the Gulf of Kachchh coast was studied which showed in general decreasing trend as we move along the northern and southern coast of the Gulf of Kachchh but, an increase in amount near the southern mouth at Okha. The study shows that the earlier proposed tidal barrier is ineffective in restricting movement of mica across the mouth of the gulf due to its characteristic transport mechanism. Also the presence of mudflats along the gulf of Kachchh coast plays a vital role as sediment receptors in the active sediment transport processes and mica minerals prove to be a promising simple tracer in studying the Indus born sediments in the region.     

Saraca indica leaf powder for decontamination of Pb: removal, recovery, adsorbent characterization and equilibrium modeling

The present study explores the effectiveness of Saraca indica leaf powder, a surplus low value agricultural waste, in removing Pb ions from aqueous solution. The influence of pH, biomass dosage, contact time, particle size and metal concentration on the removal process were investigated. Batch studies indicated that maximum biosorption capacity for Pb was 95.37% at the pH 6.5. The sorption process followed the first order rate kinetics. The adsorption equilibrium data fitted best to both Langmuir and Freundlich isotherms. Morphological changes observed in scanning electron micrographs of untreated and metal treated biomass confirmed the phenomenon of biosorption. Fourier transform infrared spectroscopy of native and exhausted leaf powder confirmed lead biomass interactions responsible for sorption. Acid regeneration was tried for several cycles with a view to recover the sorbed metal ion and also to restore the sorbent to its original state. The findings showed that Saraca indica leaf powder can easily be envisaged as a new, vibrant, low cost biosorbent for metal clean up operations.     

Can Plant Competition and Diversity Reduce the Growth and Survival of Exotic <Emphasis Type="Italic">Phragmites australis</Emphasis> Invading a Tidal Marsh?

The rapid proliferation of Phragmites australis in North America has challenged resource managers to curb its expansion and reduce the loss of functional tidal marsh. We investigated whether native plant competition could reduce the ability of Phragmites to invade a tidal marsh, and if plant diversity (species richness, evenness, and composition) altered the competitive outcome. Immature Phragmites shoots and four native halophytes were transplanted to small but dense field plots (~1,200 shoots m⁻²) comprising three community structure types (Phragmites alone, Phragmites + 1 native species, and Phragmites + 4 native species). Interspecific competition significantly reduced Phragmites aboveground biomass, shoot length production, density, and survival by approximately 60%. Additionally, plots planted with greater native diversity contained Phragmites with the lowest growth and survival, potentially indicating diversity-enhanced resource competition. Competition consistently reduced the growth of Phragmites even under favorable conditions: lack of strong tidal flooding stresses as well as elevated nutrient pools.     

Effects of a proline solution cover on the geochemical and mineralogical characteristics of high-sulfur coal gangue

Batch experiments were conducted to comparatively evaluate the inhibition effects and mechanisms of a low-concentration (1%) proline solution cover on the release of pollutants from high-sulfur coal gangue. High-sulfur coal gangue was continuously immersed in a proline solution and in deionized water (as a control treatment) for 540 days. The results showed that the coal gangue in the control treatment was oxidized and generated leachate with poor water qualities, i.e., the leachate exhibited lower pH values, higher redox potential values, higher pollutant concentrations (SO₄^2?, Fe, Mn, Cu, and Zn), and high levels of acidophilic sulfur-oxidizing bacteria. However, compared to the control treatment, the addition of the proline solution (1%) significantly improved the water quality of the leachate by significantly reducing the Eh values, the pollutant concentrations (SO₄^2?, Fe²⁺, Fe, Mn, Cu, and Zn), and the activity of acidophilic sulfur-oxidizing bacteria and by significantly increasing the pH value to neutral. The proline treatment significantly inhibited the oxidation of coal gangue and the release of pollutants, mainly by inhibiting the activity of acidophilic sulfur-oxidizing bacteria and by altering the heavy metal fractions and the mineralogical characteristics. Therefore, in engineering practice, workers should consider using an environmental friendly aqueous proline solution cover to achieve the in-situ control of pollutant releases from coal gangue dumps.     

Experimental Investigation of Turbulent Momentum Transfer in a Neutral Boundary Layer over a Rough Surface

The turbulent characteristics of the neutral boundary layer developing over rough surfaces are not well predicted with operational weather-forecasting models. The problem is attributed to inadequate mixing-length models, to the anisotropy of the flow and to a lack of controlled experimental data against which to validate numerical studies. Therefore, in order to address directly the modelling difficulties for the development of a neutral boundary layer over rough surfaces, and to investigate the turbulent momentum transfer of such a layer, a set of hydraulic flume experiments were carried out. In the experiments, the mean and turbulent quantities were measured by a particle image velocimetry (PIV) technique. The measured velocity variances and fluxes \({(\overline{{u_{i}^{\prime}}{u_{j}^{\prime}}})}\) in longitudinal vertical planes allowed the vertical and longitudinal gradients (?/?z and ?/?x) of the mean and turbulent quantities (fluxes, variances and third-order moments) to be evaluated and the terms of the evolution equations for ?e/?t, \({\partial \overline{u^{\prime 2}}/\partial t}\), \({\partial \overline{w^{\prime 2}}/\partial t}\) and \({\partial \overline{{u^{\prime}}{w^{\prime}}}/\partial t}\) to be quantified, where e is the turbulent kinetic energy. The results show that the pressure-correlation terms allow the turbulent energy to be transferred equitably from \({\overline{{u^{\prime}}^{2}}}\) to \({\overline{{w^{\prime}}^{2}}}\). It appears that the repartition between the constitutive terms of the budget of e, \({\overline{{u^{\prime}}^{2}}}\), \({\overline{{w^{\prime}}^{2}}}\) and \({\overline{{u^{\prime}}{w^{\prime}}}}\) is not significantly affected by the development of the rough neutral boundary layer. For the whole evolution, the transfers of energy are governed by the same terms that are also very similar to the smooth-wall case. The PIV measurements also allowed the spatial integral scales to be computed directly and to be compared with the dissipative and mixing length scales, which were also computed from the data.     

Imbalance in the carbonate budget of surficial sediments in the North Atlantic Ocean: variations over the last millenium?

Fluxes contributing to the particulate carbonate system in deep-sea sediments were investigated at the BENGAL site in the Porcupine Abyssal Plain (Northeast Atlantic). Deposition fluxes were estimated using sediment traps at a nominal depth of 3000 m and amounted to 0.37±0.1 mmol C m⁻² d⁻¹. Dissolution of carbonate was determined using flux of total alkalinity from in situ benthic chambers, is 0.4±0.1 mmol C m⁻² d⁻¹. Burial of carbonate was calculated from data on the carbonate content of the sediment and sedimentation rates from a model age based on ¹⁴C dating on foraminifera (0.66±0.1 mmol C m⁻² d⁻¹). Burial plus dissolution was three times larger than particle deposition flux which indicates that steady-state is not achieved in these sediments. Mass balances for other components (BSi, ²¹⁰Pb), and calculations of the focusing factor using ²³⁰Th, show that lateral inputs play only a minor role in this imbalance. Decadal variations of annual particle fluxes are also within the uncertainty of our average. Long-term change in dissolution may contribute to the imbalance, but can not be the main reason because burial alone is greater than the input flux. The observed imbalance is thus the consequence of a large change of carbonate input flux which has occured in the recent past. A box model is used to check the response time of the solid carbonate system in these sediments and the time to reach a new steady-state is in the order of 3 kyr. Thus it is likely that the system has been perturbed recently and that large dissolution and burial rates reflect the previously larger particulate carbonate deposition rates. We estimate that particulate carbonate fluxes have certainly decreased by a factor of at least 3 and that this change has occurred during the last few centuries.     

Hydrodynamic conditions and karst formation in the northwest part of Syria

The study of hydrodynamic zonation and karst formation in the northwest part of Syria is a topical hydrogeological problem. It is important to trace the history of karst formation and evaluate the spread of karst structures in the area and the rate of development of karst processes, as well as their influence on water supplies and irrigation. The solution of this problem was performed by integrated geophysical methods (electric and seismic exploration works) and data analysis of well-drilling, geological, hydro-geological, and subsurface territory explorations. The most detailed works were done near Ras Al-Ain. This paper is devoted to the results of the study of hydrodynamic conditions and karst formation.     

Influence of lithology and fluid flow on the temperature distribution in a sedimentary basin: A case study from the Cold Lake area, Alberta, Canada

A detailed study of the groundwater and terrestrial heat flow was carried out over an area of 23,700 km² west of Cold Lake, Alberta, which is part of the western Canada sedimentary basin. The information for the study was provided from data from 3100 wells drilled in the area. The screening and processing of thousands of stratigraphic picks, drillstem test data, bottom hole temperatures and formation water chemistry data was performed mainly using a specially designed software package. As a result, every stratigraphic unit is characterized by appropriate hydraulic and thermal parameters.

A sequence of aquifers, aquitards and aquicludes was differentiated. The groundwater flow in the Paleozoic aquifers is regional in nature and mainly horizontal. The flow in the Cretaceous aquifers is of intermediate type, mainly downward oriented. In general, the permeability of the Cretaceous and Paleozoic strata has such low values that the fluid velocity is less than 1 cm/yr.

The convective heat transport in the hydrostratigraphic sequence is negligible with respect to the conductive heat transfer, as shown by the Peclet number of the fluid and heat flow in porous media. The flow of the terrestrial heat flux from the Precambrian basement of the sedimentary basin to the atmosphere is controlled by the variability in the thermal properties of the formations in the basin.

The geothermal gradients were computed by hydrostratigraphic unit using a linear regression fit to the temperature data. As expected, they show higher values for the less conductive layers, and lower values for the more conductive ones. The weighted average, or the integral geothermal gradient of the whole sedimentary column, was computed by considering the difference between the temperature measured at the Precambrian basement and the annual average temperature at the surface. The areal distribution of the integral geothermal gradient (with an average of 22.0 mK/m) shows a strong correlation with the lithology.

The areal temperature distribution for each hydrostratigraphic unit was analyzed by mapping the deviation of the measured value from the computed geothermal gradient. The lateral heat flow from warmer to colder areas is one order of magnitude smaller than the vertical heat flow. In the more homogeneous units, the lateral heat flow presents a trend that seems to reflect the geometry and lithology.     

Equatorial Indian Ocean evaporation estimates from operational meteorological satellites and some inferences in the context of monsoon onset and activity

The estimation of evaporation from the sea surface is not yet achieved adequately by remote sensing techniques, in general. However, for approximate averaged estimates over moderate space and time scales over a specific tropical region, e.g., weekly values over the Indian Ocean as needed in monsoon moisture diagnosis, it may be possible to extrapolate satellite wind and humidity data to the ocean surface and then use bulk aerodynamic parameterization for estimating evaporation. In the present investigation, GOES low-level cloud winds and TIROS-N moisture profiles over the Indian Ocean are extrapolated to the ocean surface. The planetary boundary layer (PBL) wind shear is obtained over different sub-regions and periods during the monsoon season, by reference to objectively analysed fields. These shear values are applied to GOES satellite winds to obtain sea-surface winds. The humidity extrapolation was based on (i) an exponential fit for water vapour density and (ii) a vertical distribution of relative humidity approximately proportional to atmospheric pressure. The exchange coefficient is varied slightly depending on wind speed and boundary-layer stability inferred approximately from TIROS-N sea surface temperatures and temperature profiles. The evaporation estimate as based on these satellite parameters is assessed by comparison with ships' surface observations. Sensible heat exchange is also estimated and assessed. Some inferences based on these estimates are also presented, in relation to monsoon onset and activity.     

Fabric development in shear zones: theoretical controls and observed phenomena

It is suggested that the kinematic framework controls the orientation of crystallographic fabrics developed in plastically deformed quartzites. Important directions in this framework are those of the instantaneous stretching axes, and the flow plane and flow direction if these can be uniquely defined. Rotation of the crystal axes takes place at any instant of time dependent on the orientation of the grain relative to the stretching axes. Because of this dependence the skeletal outline^* of a pattern of preferred orientation is sensitive to the closing stages of deformation. Thus fabrics measured in major movement zones cannot be related to early thrust or shear displacements without considering the effects of the geological history subsequent to those events.Nevertheless, asymmetric fabrics in movement zones may allow determination of the shear direction and sense of shear. Asymmetry in the intensity distribution is less susceptible to modification than asymmetry in the fabric skeleton, and may remain as a persistent measure of the sense of shear in mylonites subjected to coaxial deformation after non-coaxial events. However, fabric asymmetry need not always be related to the deformation history, and effects related to the population of initial grain-orientations must be considered, as well as the influence of recrystallization and grain growth.A problem of scale is involved in extrapolating the movement picture inferred from the behaviour of a few hundred crystal grains to larger dimensions. This question is also encountered when trying to specify deformation paths in mesoscopic shear zones. It is difficult to obtain simple shear experimentally because of the role discontinuities play in deformation. In certain cases in natural shear zones the quartz grains may be subjected to a coaxial deformation path while the bulk deformation is progressive simple shear. Caution must therefore be exercised when attempting to use quartz fabrics to infer characteristics of the bulk kinematics or movement picture applicable during deformation.