The importance of the diet as a source of tributyltin (TBT) in Nucella lapillus was studied using [14C]tributyltin chloride. In N. lapillus provided with prelabelled mussels, Mytilus edulis, in labelled water (mean 20·5 ng/litre TBT) the rate of accumulation of total 14C was 2–3 times that in unfed animals. Owing to its degradation in the tissues of both fed and unfed animals, concentrations of [14C]TBT tended to reach a plateau after only 28 days. However, total concentrations of 14C were still increasing after 49 days. Under experimental conditions (15°C, ample food, no disturbance) the diet accounted for about 50% of the body burden of TBT in N. lapillus after 49 days exposure: concentration factors (dry tissue/water) for [14C]TBT in both male and female N. lapillus were similar at about 60 000 in fed and 30 000 in unfed animals. It is concluded that the diet may contribute less than half of the body burden of TBT found in natural populations subjected to life-long exposure. 相似文献
This paper investigates the use of data assimilation in coastal area morphodynamic modelling using Morecambe Bay as a study site. A simple model of the bay has been enhanced with a data assimilation scheme to better predict large-scale changes in bathymetry observed in the bay over a 3-year period. The 2DH decoupled morphodynamic model developed for the work is described, as is the optimal interpolation scheme used to assimilate waterline observations into the model run. Each waterline was acquired from a SAR satellite image and is essentially a contour of the bathymetry at some level within the inter-tidal zone of the bay. For model parameters calibrated against validation observations, model performance is good, even without data assimilation. However the use of data assimilation successfully compensates for a particular failing of the model, and helps to keep the model bathymetry on track. It also improves the ability of the model to predict future bathymetry. Although the benefits of data assimilation are demonstrated using waterline observations, any observations of morphology could potentially be used. These results suggest that data assimilation should be considered for use in future coastal area morphodynamic models. 相似文献
Rapid shifts in past climate recorded in polar ice sheets have elicited various explanations relating to either thermohaline
circulation changes by ice-rafting or natural greenhouse gas concentrations modulated by climatic conditions in the tropics.
To compare the tropical paleoclimate record with the polar record, one must choose sediment cores from highly productive ocean
regions. Necessarily, such regions reflect the wind records in the tropics, because high productivity is associated with upwelling
driven by winds. Comparing tropical precipitation records with high-latitude records is, however, a more difficult task because
sediments recording paleoprecipitation usually have low sedimentation rates, and offer coarser resolution relative to polar
ice cores. Here, we present δ18O data of three planktonic species of Foraminifera (a proxy for precipitation) from such a sediment core, spanning the past
35 ka for the equatorial Indian Ocean, which falls under the southwest monsoon (SWM) realm. Results show that minimum SWM
precipitation occurred at the Last Glacial Maximum, with a subsequent increase at Termination IA. During the Holocene, SWM
precipitation intensified uniformly up to the core top (∼2.2 ka b.p.), as revealed by generally decreasing δ18O values. Variations in precipitation are consistent with climate changes recorded in polar ice sheets. Although the different resolutions of the two records preclude
a rigorous comparison, abrupt cooling/warming events appear to be accompanied by sudden reduction/enhancement in (SWM) rainfall.
Thus, mechanisms with time scales much shorter than a millennium, such as natural greenhouse warming (e.g., CH4 concentration), controlled by emissions from the tropics, could have played a major role in high-latitude climate change. 相似文献
Extensive potassium and phosphorous-rich mineralization occurs on the outer continental shelf of the southern and west coasts of South Africa and Nambia. This article reviews the potential of exploiting these deposits in an environmentally sound manner for the manufacture of fertilizer. At present, reserves of potash and phosphate fertilizer are exploited from terresterial deposits, the majority being surface mined. The use of fertilizer in South Africa has shown no growth in the past 13 years, and, in some years, usage has even declined. On average, over the last decade, South Africa has consumed 2 million Mt of fertilizer (including nitrogen) per annum, the vast majority of phosphate fertilizer being produced by FOSKOR from the Phalaborwa Igneous Complex. Potash fertilizer is imported into South Africa. Although fertilizer consumption is expected to decrease in the short-term, there are good future prospects for the domestic and international fertilizer market. Considerable research into both glauconitic (containing K 2 O) and phosphatic deposits along the southern African continental shelf indicate that these sedimentary deposits have a complex genesis and mineralization. Of the total K 2 O reserves of 1300 million Mt on the southern African margin, 1000 million Mt is located off the southern African west coast, and the remainder situated on the Agulhas Bank. The largest glauconite concentration ( ±300 million Mt K 2 O) off southern Africa lies west of Saldanha Bay, South Africa. The distribution of P 2 O 5 off southern Africa is dominated by the vast deposit between Walvis Bay and Luderitz, Nambia. This reserve is estimated to contain 1000 million Mt of greater than 5% P 2 O 5 in a relatively small area of about 10000 km2. The phosphorite deposit south of Saldanha Bay constitutes a reserve of ±3500 million Mt of apatite and the deposit on the Agulhas Bank comprises 5500 million Mt. The phosphate deposit off Saldanha Bay occurs as an extensive, low to medium grade deposit. Although vast resources of potash and phosphatic minerals occur along the southern African outer continental shelf the expensive nature of marine exploitation may render most of these deposits, especially the phosphates, subeconomic. The low price of fertilizer andextensive natureontheonland deposits, although confined to asmallnumber of countries, mean that it will not be financially viable to extract these deposits. Assuming high grade glauconitic sand with the right composition can be located, the high market price indicates good future prospects for these potash deposits. 相似文献
Based on a multiparameter approach a combined litho- and organofacies concept was developed for glacial and interglacial sediment sections along an E-W transect through the central part of the Norwegian-Greenland Sea (NGS).
Modern and past surface water regimes are clearly displayed by specific litho- and organofacies patterns. Interglacial conditions reveal specific Atlantic water associated lithofacies (A and B3) in the eastern and central sector of the Norwegian-Greenland Sea (NGS). Corresponding interglacial organofacies in general are not well correlated to lithofacies due to strong diagenetic degradation of labile, e.g. autochthonous organic matter (OM). While in near-surface sediments a marine-dominated organofacies (I-1) is preserved under Atlantic water masses, this correlation is not evident for lower Holocene and Isotope Stage 5 deposits. However, during Isotopic Event 5.5.1 increased proportions of marine OM are recorded in a high accumulating core on the Vøring Plateau. Glaciomarine background lithofacies (B and C) indicate minor input of ice rafted debris (IRD) and seasonal variable sea-ice cover. Corresponding organofacies (II-1, non-oxidized and II-2, oxidized) are dominated by allochthonous OM. Most spectacular are glacial diamictons (Lithofacies E and F) evidencing short-term sediment pulses due to a sudden disintegration of far advanced tide water ice margins on the outer shelves. These diamictons bear specific organofacies (III-1 and III-2) with a clear predominance of terrigenous and reworked OM.
Some of the diamictons seem to occur contemporaneous with the so called “Heinrich-layers” H1 and H2, suggesting a common trigger-mechanism for the almost simultaneous disintegration of huge continental ice masses along the shelves of North America and the eastern margin of the NGS.
Application of a combined organo- and lithofacies concept provides essential information on spatial and temporal variations of water mass characteristics, the oceanic effects of ice sheet dynamics and circulation models. 相似文献