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271.
In an attempt to delineate heavy metal contamination precincts and to evaluate the extent and degree of toxic levels, besides
their possible sources, 38 water samples from Ankaleshwar Industrial Estate, south Gujarat, India were analyzed. By clutching
geochemical analyses and GIS-based colour composites areas depicting anomalously high concentration of heavy metals (Mo, Zn,
Pb, Ni, Co, Cd, etc.) in the groundwater were revealed. The multicomponent overlays in grey-scale facilitated in identifying
situates of heavy metal ‘hot spots’, and lateral protuberances of the contamination plume around defile stretch of the main
stream Amla Khadi flowing through the area. The multiple pollution plumes emerging from other parts of the area further coincide
with effluent laden streams and small channels indicating industrial establishments as major sources of groundwater contamination.
Influent nature of the streams, accelerated infiltration process, high mass influx and shallow groundwater table are the factors
conducive for easy access of heavy metals to the phreatic aquifers affecting over 20 km2 area. On the basis of P/U ratios (concentration of metals in polluted water to unpolluted water), geogenic and anthropogenic sources have been identified.
Very high levels of technogenic elements present in the ground water raise concerns about possible migration into food crops,
as the area is an important horticultural locale and is highly cultivated. 相似文献
272.
M. Draoui J. Vias B. Andreo K. Targuisti J. Stitou El Messari 《Environmental Geology》2008,54(3):455-463
This paper presents the results of a comparative study relating to the application of four vulnerability mapping methods,
GOD, AVI, DRASTIC and SINTACS, in a pilot detritic aquifer situated in NW Morocco, known as the Martil–Alila aquifer. The
principal objective of this work is to determine the most suitable such methods for this aquifer type within a Mediterranean
context, and to show the effect of the rainfall variations that are characteristic of the Mediterranean climate on the degree
of vulnerability. The methods applied distinguish five classes of vulnerability, these being irregularly divided up in space,
with the division varying according to the method in question. The vulnerability maps obtained by the different methods strongly
suggest that the eastern half of the aquifer is more vulnerable to contamination than the western half, for all hydrological
situations. The effect of climatic conditions on the degree of vulnerability is well represented by the DRASTIC, according
to which the aquifer is moderately to strongly vulnerable during humid hydrological years and weakly to moderately vulnerable
during dry ones. For the other methods, this climatic effect is limited to the area occupied by the two predominant classes
(“High” and “Low” for GOD and “High” and “Moderate” for SINTACS) while it is null for AVI. In conclusion, DRASTIC appears
the most suitable for mapping the vulnerability to contamination of Mediterranean coastal detritic aquifers such as the Martil–Alila
aquifer. 相似文献
273.
Georadiochemical evidence to weathering of mining residues of the Mansfeld mining district,Germany 总被引:1,自引:0,他引:1
Mining heaps are used as archives for the investigation of weathering processes. Aim of this work was to investigate the different
weathering behavior of heap materials derived from Kupferschiefer mining with respect to environmental hazard. For this purpose,
Kupferschiefer and slag material of two heaps of different age were examined regarding to the radionuclide distribution and
geochemical composition. By measuring of the local dose rate, performing digital autoradiography and gamma spectrometry the
radiological load of the heaps and the heap materials was determined. The geochemical characterization of the samples was
performed by XRF, ICP–OES and ICP–MS. The results show a clear higher radionuclide load of the younger slag heap. A depletion
of chalcophile and lithophile elements in the older slag was determined. Apart from a homogeneous radionuclide distribution,
considerable radionuclide enrichments in fossil fragments could be proven. The results reveal a different weathering behavior
of slag material in comparison to the Kupferschiefer depending on the chemical binding of the elements on organic and inorganic
species. Natural organic matter as well as apatite in Kupferschiefer act as retention barrier for some metals. 相似文献
274.
Investigations were carried out at three underground coal mines in India to study the response of surface structures to underground
blasting and the likelihood of damage to the structures. The structures in the vicinity of the underground blasting area were
single and multistoried residential houses. The amplitudes of vibration due to underground blasting were monitored simultaneously
on the ground surface near the foundation of the structures and on various floors of the structures. The vibrations were also
monitored near the important surface installations. It was observed that the magnitude of vibration in structures decreased
with the increase in the height of the structures. The frequency of blast vibration from underground blasting was higher than
the natural frequency of the structures. Little energy was transmitted into the structures, which caused reduction in the
vibration level in the structures. The reduction in the vibration levels was up to 45% in the houses. It indicates that the
dominant frequency of blast vibration plays an important role in persistence of vibration and its amplification or reduction
characteristics in the structures. This paper deals with the effect of the vibrations on structures/houses standing above
the blasting faces in underground workings and their potential to likely damage to the structures at different Indian geo-mining
conditions. 相似文献
275.
R. K. Prasad N. C. Mondal Pallavi Banerjee M. V. Nandakumar V. S. Singh 《Environmental Geology》2008,55(3):467-475
Remote Sensing and Geographic Information System has become one of the leading tools in the field of hydrogeological science,
which helps in assessing, monitoring and conserving groundwater resources. It allows manipulation and analysis of individual
layer of spatial data. It is used for analysing and modelling the interrelationship between the layers. This paper mainly
deals with the integrated approach of Remote Sensing and geographical information system (GIS) to delineate groundwater potential
zones in hard rock terrain. The remotely sensed data at the scale of 1:50,000 and topographical information from available
maps, have been used for the preparation of ground water prospective map by integrating geology, geomorphology, slope, drainage-density
and lineaments map of the study area. Further, the data on yield of aquifer, as observed from existing bore wells in the area,
has been used to validate the groundwater potential map. The final result depicts the favourable prospective zones in the
study area and can be helpful in better planning and management of groundwater resources especially in hard rock terrains. 相似文献
276.
277.
Håkon Austrheim Christine V. Putnis Ane K. Engvik Andrew Putnis 《Contributions to Mineralogy and Petrology》2008,156(4):517-527
Ilmenite in coronitic gabbros from the Bamble and Kongsberg sectors, southern Norway, is surrounded by zircons ranging in
diameters from a fraction of a micrometer to 10 μm across. The zircons are inert during subsequent metamorphism (amphibolite-
to pumpellyite–prehnite facies) and metasomatism (scapolitization and albitization) and can be found as trails in silicates
(phlogopite, talc, chlorite, amphibole, albite, and tourmaline) in the altered rocks. The trails link up to form polygons
outlining the former oxide grain boundary. This 3-dimensional framework of zircons is used to (a) recognize metasomatic origin
of rocks, (b) quantify the mobility of elements during mineral replacement, (c) establish the growth direction of reaction
fronts and to identify the reaction mechanism as dissolution–reprecipitation. Zircon coronas on Fe–Ti oxides have been described
from a number of terrains and appear to be common in mafic rocks (gabbros and granulites) providing a tool for a better understanding
of metasomatic and metamorphic reactions. 相似文献
278.
A.N. Krot M. Chaussidon H. Yurimoto N. Sakamoto K. Nagashima I.D. Hutcheon G.J. MacPherson 《Geochimica et cosmochimica acta》2008,72(10):2534-2555
In situ oxygen isotopic measurements of primary and secondary minerals in Type C CAIs from the Allende CV3 chondrite reveal that the pattern of relative enrichments and depletions of 16O in the primary minerals within each individual CAI are similar to the patterns observed in Types A and B CAIs from the same meteorite. Spinel is consistently the most 16O-rich (Δ17O = −25‰ to −15‰), followed by Al,Ti-dioside (Δ17O = −20‰ to −5‰) and anorthite (Δ17O = −15‰ to 0‰). Melilite is the most 16O-depleted primary mineral (Δ17O = −5‰ to −3‰). We conclude that the original melting event that formed Type C CAIs occurred in a 16O-rich (Δ17O −20‰) nebular gas and they subsequently experienced oxygen isotopic exchange in a 16O-poor reservoir. At least three of these (ABC, TS26F1 and 93) experienced remelting at the time and place where chondrules were forming, trapping and partially assimilating 16O-poor chondrule fragments. The observation that the pyroxene is 16O-rich relative to the feldspar, even though the feldspar preceded it in the igneous crystallization sequence, disproves the class of CAI isotopic exchange models in which partial melting of a 16O-rich solid in a 16O-poor gas is followed by slow crystallization in that gas. For the typical (not associated with chondrule materials) Type C CAIs as well for as the Types A and B CAIs, the exchange that produced internal isotopic heterogeneity within each CAI must have occurred largely in the solid state. The secondary phases grossular, monticellite and forsterite commonly have similar oxygen isotopic compositions to the melilite and anorthite they replace, but in one case (CAI 160) grossular is 16O-enriched (Δ17O = −10‰ to −6‰) relative to melilite (Δ17O = −5‰ to −3‰), meaning that the melilite and anorthite must have exchanged its oxygen subsequent to secondary alteration. This isotopic exchange in melilite and anorthite likely occurred on the CV parent asteroid, possibly during fluid-assisted thermal metamorphism. 相似文献
279.
Annually laminated carbonates, known as tufas, commonly develop in limestone areas and typically record seasonal patterns of oxygen- and carbon-isotope compositions. δ18O values are principally controlled by seasonal changes of water temperature, whereas δ13C values are the result of complex reactions among the gaseous, liquid, and solid sources of carbon in the system. We examined the processes that cause the seasonal patterns of δ13C in groundwater systems at three tufa-depositing sites in southwestern Japan by applying model calculations to geochemical data. Underground inorganic carbon species are exchanged with gaseous CO2, which is mainly introduced to the underground hydrological system by natural atmospheric ventilation and by diffusion of soil air. These processes control the seasonal pattern of δ13C, which is low in summer and high in winter. Among the three sites we investigated, we identified two extreme cases of the degree of carbon exchange between liquid and gaseous phases. For the case with high radiocarbon composition (Δ14C) and low pCO2, there was substantial carbon exchange because of a large contribution of atmospheric CO2 and a small water mass. For the other extreme case, which was characterized by low Δ14C and high pCO2, the contribution of atmospheric CO2 was small and the water mass was relatively large. Our results suggest that at two of the three sites water residence time within the soil profile was longer than 1 year. Our results also suggested a short residence time (less than 1 year) of water in the soil profile at the site with the smallest water mass, which is consistent with large seasonal amplitude of the springwater temperature variations. The Δ14C value of tufas is closely related to the hydrological conditions in which they are deposited. If the initial Δ14C value of a tufa-depositing system is stable, 14C-chronology can be used to date paleo-tufas. 相似文献
280.
Steven J.K. Symes Lars E. Borg Charles K. Shearer 《Geochimica et cosmochimica acta》2008,72(6):1696-1710
Samarium-neodymium isotopic analyses of unleached and acid-leached mineral fractions from the recently identified olivine-bearing shergottite Northwest Africa 1195 yield a crystallization age of 347 ± 13 Ma and an value of +40.1 ± 0.9. Maskelynite fractions do not lie on the Sm-Nd isochron and appear to contain a martian surface component with low 147Sm/144Nd and 143Nd/144Nd ratios that was added during shock. The Rb-Sr system is disturbed and does not yield an isochron. Terrestrial Sr appears to have affected all of the mineral fractions, although a maximum initial 87Sr/86Sr ratio of 0.7016 is estimated by passing a 347 Ma reference line through the maskelynite fraction that is least affected by contamination. The high initial value and the low initial 87Sr/86Sr ratio, combined with the geologically young crystallization age, indicate that Northwest Africa 1195 is derived from a source region characterized by a long-term incompatible-element depletion.The age and initial Sr and Nd isotopic compositions of Northwest Africa 1195 are very similar to those of Queen Alexandra Range 94201, indicating these samples were derived from source regions with similar Sr-Nd isotopic systematics. These similarities suggest that these two meteorites share a close petrogenetic relationship and might have been erupted from a common volcano. The meteorites Yamato 980459, Dar al Gani 476, Sayh al Uhaymir 005/008, and Dhofar 019 also have relatively old ages between 474 and 575 Ma and trace element and/or isotopic systematics that are indicative of derivation from incompatible-element-depleted sources. This suggests that the oldest group of meteorites is more closely related to one another than they are to the younger meteorites that are derived from less incompatible-element-depleted sources. Closed-system fractional crystallization of this suite of meteorites is modeled with the MELTS algorithm using the bulk composition of Yamato 980459 as a parent. These models reproduce many of the major element and mineralogical variations observed in the suite. In addition, the rare earth element systematics of these meteorites are reproduced by fractional crystallization using the proportions of phases and extents of crystallization that are calculated by MELTS. Other shergottites that demonstrate enrichments in incompatible-elements and have evolved Sr and Nd isotopic systematics have some geochemical systematics that are similar to those observed in the depleted group. Most notably, although they exhibit a very limited range of incompatible trace element and isotopic compositions, they have highly variable major element compositions. This is also consistent with evolution from a common mantle source region by variable amounts of fractional crystallization. If this scenario is correct, it suggests that the combined effects of source composition and fractional crystallization are likely to account for the major element, trace element, and isotopic diversity of all shergottites. 相似文献