Deep structure of the northeastern margin of the Parnaiba Basin, Brazil, from magnetotelluric imaging

The magnetotelluric (MT) method has been applied to the determination of the deep resistivity structure of the northeastern margin of the Parnaiba Basin. Transient electromagnetic (TEM) and MT data were collected in early 1999 along a 95 km long N–S line, extending from the coast across the projected subcrop position of a discontinuous fault found to the west of the study area that is believed to be a possible basin‐bounding fault. The MT data were processed to yield the TE‐ and TM‐mode responses and then corrected for static shift using central‐loop and single‐loop TEM data, respectively. Regularized 2D MT inversion was subsequently undertaken using a structured initial model with the near‐surface constrained by TEM inversion results. As a consistency check, we performed another set of 2D inversions using different smooth initial models. The various optimal 2D inversion models show clearly the presence of a major basement trough, over 2 km deep, located about 70 km from the coast. We interpret it as possibly marking the main basin margin and suggest that it may have implications for groundwater resource development in the area.     

Relationships between tissue concentrations of chlorinated hydrocarbons (polychlorinated biphenyls and chlorinated pesticides) and antioxidative responses of marine mussels, Perna viridis

Marine mussels, Perna viridis, were transplanted from a reference site to various polluted sites around Hong Kong. After 30 d of exposure, antioxidative responses in the gills and hepatopancreas and tissue concentrations of chlorinated hydrocarbons [polychlorinated biphenyls (PCBs) and chlorinated pesticides (CPs)] were determined for individual mussels. Glutathione S transferase (GST) and glutathione (GSH) were positively correlated with tissue PCB concentrations. Only one of the enzymatic antioxidants, glutathione peroxidase (GPx), showed significant response to tissue PCB. No significant correlation was found between tissue concentrations of chlorinated hydrocarbons and other enzymatic antioxidants (superoxide dismutase (SOD), catalase (CAT), glutathione reductase (GR) and NADPH DT-diaphorase (DT-d). Oxidative stress, measured as thiobarbituric acid reactive substances, was correlated with chlorinated pesticide concentrations in tissues. This study demonstrated a correlation between GST/GSH and chlorinated hydrocarbons. The apparent lack of correlation between trace organic pollutants and some of the enzymatic antioxidants may be due to the inhibitory effects caused by these chemicals. The above results suggest that more investigations are needed before these enzymes can be used as biomarkers.     

Mathematical modeling of PCB bioaccumulation in Perna viridis

In the present work, we built a mathematical model of polychlorinated biphenyl (PCB) bioaccumulation in Perna viridis, namely, a one-compartment model with a time dependent incorporation rate R (μg g⁻¹ lipid per ppb water per day), with positive substrate cooperativity as the underlying physical mechanism. The temporal change of the PCB concentration Q (μg g⁻¹ lipid) in the soft tissues of the mussel depends on the competition of the input rate RW and the output rate kQ, where W is the concentration of PCB in water (ppb water) and k is the elimination rate (per day). From our experimental data, k=0.181±0.017 d⁻¹. The critical concentration in water W_c for positive substrate cooperativity was found to be 2.4 ppb. Below W_c, R is a constant. For a water concentration of 0.5 ppb Aroclor 1254, R=24.0±2.4 μg g⁻¹ lipid ppb⁻¹ d⁻¹. Above W_c, positive substrate cooperativity comes into effect and R becomes a function of time and dependent on the concentration Q in a form R=γQ/(Q+δ). This is the case for a water concentration of 5 ppb Aroclor 1254, where γ=15.1 μg g⁻¹ lipid ppb⁻¹ d¹ and δ≈200 μg g⁻¹ lipid. From this model, the uptake is exponentially increasing when the PCB concentration in the mussel is small compared to 200 μg g⁻¹ lipid, and hyperbolically increasing when the concentration is large compared to 200 μg g⁻¹ lipid, which are consistent with the experimental data. The model is useful for understanding the true processes taking place during the bioaccumulation and for risk assessment with higher confidence. Future experimental data which challenge the present model are anticipated and in fact desirable for improvement and perfection of the model.     

Solar–terrestrial effects possibly stronger in biblical times

Paleomagnetic studies have shown that, moving backwards in time, the geomagnetic dipole moment increased to a peak nearly 50% greater than at present ca. 2500 years ago. Attempts to model how changes in dipole moment affect solar–terrestrial relations have hitherto invoked a scaling relation for the size of the magnetosphere based on finding where the magnetic pressure of the dipole field balances the ram pressure of the solar wind. This approach predicts that, following a solar storm, the strength of the terrestrial response represented by the electrical potential across the auroral zones in the ionosphere should vary as the 1/3 power of dipole moment. Such a weak dependence suggests that a 50% increase in dipole moment would minimally effect (14%) terrestrial manifestations of solar storms. Recent work, however, based on a feedback mechanism involving electrical currents coupling the magnetosphere and ionosphere has identified a stronger 4/3, power scaling relation applicable to storm conditions. Here we use a global MHD simulation to calculate for a 50% increased dipole moment the correspondingly increased auroral-zone potential and its extension to low latitudes.     

African monsoon variability during the previous interglacial maximum

Little is known about centennial- to millennial-scale climate variability during interglacial times, other than the Holocene. We here present high-resolution evidence from anoxic (unbioturbated) sediments in the eastern Mediterranean Sea that demonstrates a sustained ∼800-yr climate disturbance in the monsoonal latitudes during the Eemian interglacial maximum (∼125 ka BP). Results imply that before and after this event, the Intertropical Convergence Zone (ITCZ) penetrated sufficiently beyond the central Saharan watershed (∼21°N) during the summer monsoon to fuel flooding into the Mediterranean along the wider North African margin, through fossil river/wadi systems that to date have been considered only within a Holocene context. Relaxation in the ITCZ penetration during the intra-Eemian event curtailed this flux, but flow from the Nile - with its vast catchment area - was not affected. Previous work suggests a concomitant Eurasian cooling event, with intensified impact of the higher-latitude climate on the Mediterranean basin. The combined signals are very similar to those described for the Holocene cooling event around 8 ka BP. The apparent type of concurrent changes in the monsoon and higher-latitude climate may reflect a fundamental mechanism for variability in the transfer of energy (latent heat) between the tropics and higher latitudes.     

Where did rotational shortening occur in the Himalayas? - Inferences from palaeomagnetic remagnetisations

In metacarbonates of the Lesser (LH) and Tethyan (TH) Himalayas of Kumaon/Garhwal (N-India) characteristic remanent magnetisations carried by pyrrhotite (unblocking temperatures: 250-330°C) and magnetite (demagnetising spectra: 15-50 mT) have been identified. Negative fold tests indicate remanence acquisition after the main folding phase, which is of short-wavelength character and occurs during the early orogenese of the Himalayas. A thermal or thermochemical origin of magnetisation is likely and the age of remanence acquisition is indicated to be about 40 Ma by ⁴⁰K/³⁹Ar cooling and ⁴⁰Ar/³⁹Ar crystallisation ages. In the Kumaon LH a long-wavelength tilting is indicated by a distribution of the remanence directions along a small-circle in N-S direction. Steepening of the remanence directions in the TH related to ramping on the Main Central Thrust (MCT) was not observed, in contrast to other related studies. In the Alaknanda valley of LH a 38±8 Ma age of remanence acquisition is supported by comparison of observed inclinations to the apparent polar wander path of India. Clockwise rotation of 20.3±11.7° (LH/Alaknanda valley) and 11.3±8.5° (TH) with respect to the Indian plate is observed, indicating that there is no significant evidence for rotational shortening along the MCT since about 40 Ma. Our results suggest that most of rotational underthrusting and oroclinal bending has not been accommodated by the MCT, but by the main thrusts south of it. The latest Miocene/Pliocene age of the Main Boundary Thrust indicates that oroclinal bending is a late-orogenic process.     

Determination of S-wave Site Response in Anchorage, Alaska in the 1–9 Hz Frequency Band

—?Site response was estimated at 19 sites in the Anchorage basin in south-central Alaska, using 15 local earthquakes recorded with good signal-to-noise ratio by a temporary weak motion network. The receiver-function-type horizontal-to-vertical spectral ratios (HVSR) were computed at 1–9 Hz frequency band and the resulting HVSR contour maps at 1, 5 and 9 Hz are presented here. The spatial site response distribution shows considerable variation from the foothills of the Chugach Mountains in the east to the western part of Anchorage. The site response increases by a factor of 3 and 3.5 at 1 and 5 Hz, respectively, from the area of older glacial deposits in the eastern part of the city to the area occupied by the Bootlegger Cove formation, particularly in the section adjoining Knik Arm. At 9 Hz, the variation of HVSR from the east to the west is smaller, approximately by a factor of 2. Moreover, the trend of the HVSR variation at 1 and 5 Hz shows good correlation with that of the soil class obtained from surface measurements of S-wave velocity in the 0–30?m depth range and available results on ground failure susceptibility of Anchorage.     

Spatial variation of seismic motion induced by propagation of body waves

Spatial variation of earthquake ground motion is an important phenomenon that cannot be ignored in the design and safety of strategic structures. Several models have been developed to describe this variation using statistical, mathematical or physical approaches. The latter approach is not specific to an event. A recent contribution, which uses such an approach and called complete stochastic deamplification approach (CSDA), was developed [1]. The aim of this paper is to analyze the spatial variation of earthquake motion induced by the propagation of body waves using the CSDA. Coherency functions are evaluated for the cases of SH–SV–P waves propagating through stratified soil. Results obtained show that the variation of the coherency function is not the same for vertical and horizontal components and that the motion is more coherent at depth than at the free surface. In fact, we found that the rate of decrease with frequency and distance is not the same if P–SV waves propagate through stratified soil.     

Contrasting rifted margin styles south of Greenland: implications for mantle plume dynamics

We present new and reprocessed seismic reflection data from the area where the southeast and southwest Greenland margins intersected to form a triple junction south of Greenland in the early Tertiary. During breakup at 56 Ma, thick igneous crust was accreted along the entire 1300-km-long southeast Greenland margin from the Greenland Iceland Ridge to, and possibly 100 km beyond, the triple junction into the Labrador Sea. However, highly extended and thin crust 250 km to the west of the triple junction suggests that magmatically starved crustal formation occurred on the southwest Greenland margin at the same time. Thus, a transition from a volcanic to a non-volcanic margin over only 100–200 km is observed. Magmatism related to the impact of the Iceland plume below the North Atlantic around 61 Ma is known from central-west and southeast Greenland. The new seismic data also suggest the presence of a small volcanic plateau of similar age close to the triple junction. The extent of initial plume-related volcanism inferred from these observations is explained by a model of lateral flow of plume material that is guided by relief at the base of the lithosphere. Plume mantle is channelled to great distances provided that significant melting does not take place. Melting causes cooling and dehydration of the plume mantle. The associated viscosity increase acts against lateral flow and restricts plume material to its point of entry into an actively spreading rift. We further suggest that thick Archaean lithosphere blocked direct flow of plume material into the magma-starved southwest Greenland margin while the plume was free to flow into the central west and east Greenland margins. The model is consistent with a plume layer that is only moderately hotter, 100–200°C, than ambient mantle temperature, and has a thickness comparable to lithospheric thickness variations, 50–100 km. Lithospheric architecture, the timing of continental rifting and viscosity changes due to melting of the plume material are therefore critical parameters for understanding the distribution of magmatism.     

Production of selected cosmogenic radionuclides by muons: 2. Capture of negative muons

We have determined the production yields for radionuclides in Al₂O₃, SiO₂, S, Ar, K₂SO₄, CaCO₃, Fe, Ni and Cu targets, which were irradiated with slow negative muons at the Paul Scherrer Institute in Villigen (Switzerland). The fluences of the stopped negative muons were determined by measuring the muonic X-rays. The concentrations of the long-lived and short-lived radionuclides were measured with accelerator mass spectrometry (AMS) and γ-spectroscopy, respectively. Special emphasis was put on the radionuclides ¹⁰Be, ¹⁴C and ²⁶Al produced in quartz targets, ²⁶Al in Al₂O₃ and S targets, ³⁶Cl in K₂SO₄ and CaCO₃ targets, and ⁵³Mn in Fe₂O₃ targets. These targets were selected because they are also the naturally occurring target minerals for cosmic ray interactions in typical rocks. We also present results of calculations for depth-dependent production rates of radionuclides produced after cosmic ray μ⁻ capture, as well as cosmic ray-induced production rates of geologically relevant radionuclides produced by the nucleonic component, by μ⁻ capture, by fast muons and by neutron capture.